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Olefin metathesis: Reaction and Mechanism



Olefin metathesis

The Olefin metathesis (transalkylidenation) is an chemical organic reaction that causes the reallocation of alkylene fragments by the decomposition of carbon - carbon double bonds in olefins.

Online available information resources on olefin metathesis (transalkylidenation).

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Current Stories and Reports


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New catalysts promise faster, cleaner and more efficient research platform

A team of researchers have discovered a new class of catalysts for the powerful olefin metathesis reaction, illustrated here, which transforms simple molecules into complex ones. The process is critical to new research in medicine, biology and materials science [Illustration courtesy of Nature].



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Lecture Notes, Tutorials


Alkyne Metathesis
Article. RSC

Alkyne Metathesis
Background and catalyst development. MPG - Format: PDF

Alkyne Metathesis in Synthesis: Syntheses of (+)-Ferrugine and Anatoxin-a
Scientific article. Organic Chemistry Portal

Cross Metathesis
Olefin cross metathesis - Format: PDF

Cross Metathesis
A Model in Selectivity - Format: PDF

Cross Metathesis
Reactions and mechanisms. Organic Chemistry Portal

Cross Metathesis
Olefin Cross Metathesis

Grubbs Reaction
Description and mechanisms. Organic Chemistry Portal

Industrial Applications of Olefin Metathesis
Article, 2004 - Format: PDF

Olefin Metathesis
General information. The Organometallic HyperTextBook

Olefin Metathesis in Organic Synthesis
- Format: PDF

Olefin Metathesis Polymerization
An overview

Olefin Metathesis Reaction
Lecture notes - Format: PDF

Ring Closing Metathesis, RCM
Reactions and mechanisms. Organic Chemistry Portal

Ring Opening Metathesis Polymerization
ROMP. The Organometallic HyperTextBook

Ring Opening Metathesis, ROM, ROMP
Reactions and mechanisms. Organic Chemistry Portal



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Special Information


Cyclic Ether Formation
Direct Conversion of Olefinic Esters to Cyclic Enol Ethers with Tebbe-Type Reagents - Format: PDF

Development of the metathesis method in organic synthesis
Advanced information on the Nobel Prize in Chemistry 2005. Noble Foundation

Grandisol
Alkene and Alkyne Metathesis: Grandisol (Goess), 8-Epihalosilane (Kouklovsky /Vincent), (+)-Chinensiolide B (Hall)

Heterocycle Construction by Grubbs Metathesis
Scientific article. Organic Chemistry Portal

Light-induced Olefin Metathesis
Article, Beilstein Journal, 2010 - Format: PDF

Metathesis - a change-your-partners dance
Advanced information on the Nobel Prize in Chemistry 2005. Noble Foundation

Metathesis Reactions in Total Synthesis
Article: Synthethic Methods, 2005 - Format: PDF

Microwave-Assisted Olefin Metathesis
Article, 2003 - Format: PDF

Monoalkoxidepyrrolide Catalysts
… for olefin metathesis - Format: PDF

Olefin Metathesis - Big-deal Reaction
Scientific article; Chemical & Engineering News. ACS

Ruthenium Olefin Metathesis Catalysts
Article - Format: PDF

Site-Selective Protein Modification
ChemBioChem article 2009 - Format: PDF



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Historical Facts and Documents


Nobel Prize in Chemistry 2005
Yves Chauvin, Institut Français du Pétrole, Rueil-Malmaison, France; Robert H. Grubbs, California Institute of Technology (Caltech), Pasadena, CA, USA and Richard R. Schrock. Noble Foundation

Olefin Metathesis
The Early Day. Scientific article, 2002. Chemical & Engineering News



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Compounds


Epothilone A
The Olefin Metathesis Approach to Epothilone A and Ist Analogues - Format: PDF

Synthesis of (+)-4,5-Deoxyneodolabelline
Scientific article. Organic Chemistry Portal



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Data and Databases


Olefin-Metatheses in Literature
Listing of current research articles. Organic Chemistry Portal



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Dissertations


Natural Product Syntheses
Application of Olefin Cross Metathesis in Natural Product Syntheses. TU Berlin

Nonlinear Polymeric Architectures
… via olefin metathesis. Dissertation, 2008. Caltech

Optimization of Ring-Closing Metathesis
Inert Gas Sparging and Microwave Irradiation. Dissertation, 2006. University of Regensburg

Stemoamide
Total Synthesis of Stemoamide using ring-closing-metathesis - a comparison. Dissertation, 2006. University of Regensburg







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Citation:
www.internetchemistry.com/chemistry/olefin-metathesis.htm
Entries:
38
Topic:
Olefin metathesis: Reaction and Mechanism
Keywords:
Olefin, metathesis, transalkylidenation, chemical, reactions, mechanisms, organic, synthesis
Update:
26.02.2012 00:00:00 [link check]
 
26.02.2012 [site update]


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