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Green Chemistry

Current research reports and chronological list of recent articles..




The international scientific journal Green Chemistry publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research and policy relating to the endeavour are welcome.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles see Current Chemistry Research Articles. Magazines with similar content (sustainable and green chemistry):

 - ChemSusChem.

 - Environmental Chemistry.

 - Green Chemistry Letters and Reviews.



Green Chemistry - Abstracts



Ammonium hydroxide as ultimate amino source for synthesis of N-unprotected 3-tetrasubstituted aminooxindoles via catalyst-free direct amination

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00130A, Communication
Jing Yue, Xi-Tao Ma, Xiong-Li Liu, Jun-Xin Wang, Xiong-Wei Liu, Ying Zhou
The direct use of ammonium hydroxide in amination for the synthesis of primary amines is considered to be one of the major challenges in synthetic organic chemistry. Herein the first...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


Biological upgrading of 3,6-anhydro-L-galactose from agarose to a new platform chemical

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04265B, Paper
Dong Hyun Kim, Jing-Jing Liu, Jae Won Lee, Jeffrey G. Pelton, Eun Ju Yun, Sora Yu, Yong-Su Jin, Kyoung Heon Kim
This study demonstrated the novel biological upgrading (using engineered yeast cells) of 3,6-anhydro-L-galactose, the main but untapped sugar of red macroalgal biomass, to 3,6-anhydro-L-galactitol that can be converted to various valuable chemicals including isosorbide.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


A new approach to large scale production of dimethyl sulfone: A promising and strong recyclable solvent for ligand-free Cu-catalyzed C-C cross-coupling reactions

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04374H, Paper
Shen Cheng , Wei Wei, Xingyu Zhang, Hewei Yu, Mingming Huang, Milad Kazemnejadi
Dimethyl sulfone (DMSN) was easily prepared through efficient oxidation of dimethyl sulfoxide (DMSO) and used as a strong and green solvent for organic reactions. A mixture of HNO3/NaOCl was used...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


Production of chiral alcohols from racemic mixtures by integrated heterogeneous chemoenzymatic catalysis in fixed bed continuous operation

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04127C, Paper
Jose Miguel Carceller, Maria Mifsud, Maria J. Climent, Sara Iborra, Avelino Corma
Production of chiral alcohols from racemic mixtures with an integrated heterogeneous chemo-enzymatic two step relay catalyst in fixed bed continuous operation.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


In-situ processed tungsten carbide/carbon black-supported platinum electrocatalysts for enhanced electrochemical stability and activity

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03453F, Paper
Hyunwoong Na, Hanshin Choi, Ji-Won Oh, Da Bin Kim, Yong Soo Cho
High performance electrocatalysts have been intensively studied to reduce the content of expensive platinum-group metals and to secure excellent electrochemical durability. Herein, we introduce a very promising processing technique based...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.02.2020


Microalgae: A sustainable adsorbent with high potential for upconcentration of indium(III) from liquid process and waste streams

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03073E, Paper
Nina Ricci Nicomel, Lila Otero-Gonzalez , Larissa Arashiro, Marianna Garfi, Ivet Ferrer, Pascal Van Der Voort, Kim Verbeken, Tom Hennebel, Gijs Du Laing
Indium (In) is a critical raw material heavily demanded in the optical-electronics industry. With its high supply risk, sustainable technologies are needed to recover In(III) from secondary sources, such as...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.02.2020


Synthesis of renewable C-C cyclic compounds and high-density biofuel using 5-hydromethylfurfural as a reactant

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shugaung Deng
The major challenge in the synthesis of high-density biofuel is to identify biobased source of C-C cyclic compounds and C-C coupling reactions with a suitable selectivity. Herein, we selectively synthesize...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.02.2020


A simple and effective approach to fabricate lignin nanoparticles with tunable sizes based on lignin fractionation

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00377H, Paper
Mingshuai Ma, Lin Dai, Zhong Liu, Yonghao Ni
In recent years, an increasing number of studies showed that lignin nanoparticles (LNPs) are not only a new kind of green and sustainable materials but also have great potential applications...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


Environmental Assessment of the Near-net-shape Electrochemical Metallisation Process and the Kroll – Electron Beam Melting Process for Titanium Manufacture

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04036F, Paper
Aleksei Dolganov, Matthew T. Bishop, Marco Tomatis, George Zheng Chen, Di Hu
The enforcement of environmental policies in recent years has become one of the major driving forces for industrial upgrading. Therefore, this study is focused on the evaluation of the environmental...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


Acid-catalyzed Pyrolytic Synthesis of Levoglucosan through Salt-mediated Ring Locking

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03973B, Paper
Li Chen, Welman Curi Elias, Yiyuan "Ben" Yin, Zongchao (Conrad) Zhang, Michael Wong
Selectively producing chemicals from cellulosic carbohydrate pyrolysis in large quantities is challenging, especially anhydro-monosaccharides with double-ring, triple-ring, and furan/pyran structures. Formation of these sugar derivatives greatly improves when pyranose ring...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


Graphitic Carbon Embedded with Fe/Ni Nano-Catalysts Derived from Bacterial Precursor for Efficient Toluene Cracking

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03357B, Paper
Shifei Kang, Maofen He, Chao chuang Yin, Haiyang Xu, Qing Cai, Yangang Wang, Lifeng Cui
The environmentally-harmful by-product -- biomass tar -- is the major obstacle during biomass gasification, which produces synthetic gas as a clean energy source from agricultural waste or other bio-wastes. The...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


Superhydrophobic Nickel/Carbon Core-shell nanocomposites for the hydrogen transfer reactions of nitrobenzene and N-heterocycles

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04358F, Paper
shaofeng pang, Yujing Zhang, Qiong Su, Fangfang Liu, xin xie, Zhiying Duan, Feng Zhou, Ping Zhang, yanbin wang
In this work, catalytic hydrogen transfer as an effective, green, convenient and economical strategy is first used to synthesize anilines and N-heterocyclic aromatic compounds from nitrobenzene and N-heterocycles in one...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


Efficient Hydrogenation Catalytic Model Hosted in Stable Hyper-crosslinked Porous-Organic-Polymer: From Fatty Acids to Bio-based Alkanes Diesel Synthesis

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03803E, Paper
Chitra Sarkar, Subhash Chandra Shit, Duy Quang Dao, Jihyeon Lee, Ngoc Han Tran, Ramana Singuru, Kwangjin An, Nguyen Dang Nam, Quyet Van Le, Prince Nana Amaniampong, Asmaa Drif, Francois Jerome, Thanh Huyen Pham, Thi To Nga Phan, Dai-Viet Nguyen Vo, Nguyen Thanh Binh, Quang Thang Trinh, Matt Sherburne, John Mondal
In this study, Pd-based catalytic model hosted over nitrogen enriched fibrous Porous-Organic-Polymer (POP) is established to execute hydrodeoxygenation of various vegetable oils in producing potential large-scale renewable diesel. Here we...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


Ni-catalyzed reductive amination of phenols with ammonia or amines into cyclohexylamines

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC02625H, Paper
Thomas Cuypers, Thomas Morias, Simon Windels, Carlos Marquez, Cédric Van Goethem, Ivo F.J. Vankelecom, Dirk E. De Vos
Phenol and its derivatives, which naturally occur in lignocellulose, can be considered as a renewable feedstock not only for aromatic, but also for alicyclic compounds, such as primary and N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


Visible-Light Induced Disproportionation of Pyrrole Derivatives for Photocatalyst-Free Aryl Halides Reduction

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04248B, Paper
Zhijun Li, Shuuya Li, Elan Hofman, Andrew H Davis, Gyu Leem, Weiwei Zheng
As a green synthetic approach, visible light-driven photosynthesis is highly desirable in arylation of inert alkyl halides, as they are important precursors in the total synthesis of natural products and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


Dioxomolybenum complex as an efficient and cheap catalyst for the reductive depolymerization of waste plastics into value-added compounds and fuels

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
This work describes the efficient and selective reductive depolymerization of the waste plastics PET, PBT, PCL, PLA and PDO into value-added compounds and fuels, including 1,6-hexanediol, xylene and propane, catalyzed...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.02.2020


High-strength cellulose nanofibers produced via swelling pretreatment based on a choline chloride–imidazole deep eutectic solvent

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04119B, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Juho Antti Sirviö, Kalle Hyypiö, Shirin Asaadi, Karoliina Junka, Henrikki Liimatainen
A deep eutectic solvent based on choline chloride and imidazole was investigated for swelling of cellulose fibers prior to mechanical disintegration into cellulose nanofibers.
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Datum: 18.02.2020


Controlled assembly of secondary keratin structures for continuous and scalable production of tough fibers from chicken feathers

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03896E, Paper
Bingnan Mu, Faqrul Hassan, Yiqi Yang
Continuous production of tough keratin fibers via high recovery of protein secondary structures.
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Datum: 18.02.2020


A dual biomimetic process for the selective aerobic oxidative coupling of primary amines using pyrogallol as a precatalyst. Isolation of the [5+2] cycloaddition redox intermediates

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03992A, Paper
Martine Largeron, Patrick Deschamps, Karim Hammad, Maurice-Bernard Fleury
A bioinspired organocatalytic cascade reaction mimicking both purpurogallin biosynthesis and copper amine oxidases (CuAOs) activity is described, at room temperature under ambient air, for the activation of the α-C-H bond...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.02.2020


Catalytic Transformation of CO2 into C1 Chemicals Using Hydrosilanes as a Reducing Agent

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04342J, Critical Review
Yu Zhang, Tong Zhang, Shoubhik Das
Utilization of CO2 for the synthesis of fine chemicals and pharmaceuticals has attracted tremendous attention. In fact, reductive transformation of CO2 is also an interesting approach in this direction. Obviously,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.02.2020


Cleaner enzymatic production of biodiesel with easy separation procedures triggered by a biocompatible hydrophilic ionic liquid

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03796A, Paper
Anlian Zhu, Wanlu Feng, Zhiyong Li, Shuang Cheng, Qianhan Chen, Dongshuang Fan, Yuan-Yang Guo, Lingjun Li, Jianji Wang
The great challenges of modern industry and environment make it important to develop sustainable energy resources with low cost. In this work, a cleaner enzymatic procedure for biodiesel production was...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.02.2020


An overview of the biphasic dehydration of sugars to 5-hydroxymethylfurfural and furfural: a rational selection of solvents using COSMO-RS and selection guides

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04208C, Critical Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Jesús Esteban, Andreas J. Vorholt, Walter Leitner
A wide overview of the biphasic production of 5-hydroxymethylfurfural and furfural from lignocellulosic sugars is presented together with a screening of solvents following a methodology based on COSMO-RS and section guides.
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Datum: 14.02.2020


Mild and controlled lignin methylation with trimethyl phosphate: towards a precise control of lignin functionality

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03890F, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Antoine Duval, Luc Avérous
A novel protocol for a mild, controlled and selective methylation of lignin phenolic OH groups with trimethylphosphate has been developed.
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Datum: 14.02.2020


In depth interpret the structural changes of lignin and formation of diketones during acidic deep eutectic solvent pretreatment

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00006J, Paper
Si Hong, Xiao-jun Shen, Bo Pang, Zhimin Xue, Xuefei Cao, Jia-Long Wen, zhuohua sun, Su Shiung Lam, Tong-Qi Yuan, Runcang Sun
Deep eutectic solvents (DES) as a novel and green solvent can extract high-purity lignin from lignocellulose in a high yield, while the further utilization of the extracted lignin in the...
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Datum: 14.02.2020


Understanding laccase/HBT-catalyzed grass delignification at the molecular level

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04341A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roelant Hilgers, Gijs van Erven, Vincent Boerkamp, Irina Sulaeva, Antje Potthast, Mirjam A. Kabel, Jean-Paul Vincken
An in-depth study on the pathways underlying wheat straw and corn stover delignification by a laccase/HBT system. New insights were obtained by comprehensive fractionation, purification and analysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.02.2020


Covalent triazine framework/carbon nanotube hybrids enabling selective reduction of CO2 to CO at low overpotential

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00090F, Paper
Andreas Laemont, Sara Abednatanzi, Parviz Gohari Derakshandeh, Florian Verbruggen, Erika Fiset, Qing Qin, Kevin Van Daele, Maria Meledina, Johannes Schmidt, Martin Oschatz, Pascal Van Der Voort, Korneel Rabaey, Markus Antonietti, Tom Breugelmans, Karen Leus
Nitrogen-rich covalent triazine frameworks (CTFs) were grown in situ onto surface-functionalized carbon nanotubes. These novel hybrid catalysts electrochemically reduce CO2 to CO with a faradaic efficiency up to 81% at an overpotential of 380 mV.
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Datum: 13.02.2020


Insights into pressure tunable reaction rates for electrochemical reduction of CO2 in organic electrolytes

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00013B, Paper
Charles I. Shaughnessy, David Joseph Sconyers, Hyun-Jin Lee, Bala Subramaniam, James Blakemore, Kevin C. Leonard
Electrochemical CO2 reduction rates are limited in aqueous-based electrolytes by the low solubility of CO2. We recently demonstrated that organic solvent-based CO2 Expanded Electrolytes (CXEs) can solubilize multi-molar amounts of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.02.2020


A strategy to control grain boundary density and Cu+/Cu0 ratio of Cu-based catalysts for efficient electroreduction of CO2 to C2 products

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00247J, Communication
Chunjun Chen, Xiaofu Sun, Xupeng Yan, Yahui Wu, Mingyang Liu, ShuaiShuai Liu, Zhijuan Zhao, Buxing Han
Cu(OH)2/CuO nanocomposites-derived Cu2O/Cu were highly efficient for CO2 electroreduction to C2 products. The highest faradaic efficiency and current density could reach 64.5% and 26.2 mA cm-2, respectively. By changing calcination...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.02.2020


A metal-free route to alkynyl sulfones under photoinduced conditions with the insertion of sulfur dioxide

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00332H, Paper
Xinxing Gong, Min Yang, Jin-Biao Liu, Fu-Sheng He, Xiaona Fan, Jie Wu
A metal-free route to alkynyl sulfones under photoinduced conditions is accomplished, starting from 4-alkyl Hantzsch esters, sulfur dioxide, and alkynyl bromides under visible light irradiation at room temperature. This transformation...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.02.2020


Closing the loop: Life cycle assessment and optimization of a PEMFC platinum-based catalyst recycling process

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC03630J, Paper
Lucien Duclos, Raphael Chattot, Laetitia Dubau, Pierre-Xavier Thivel, Guillaume Mandil, Valérie Laforest, Marco Bolloli, Rémi Vincent, Lenka Svecova
This study is focused on the development of environmentally friendly recycling method for selective recovery in a closed loop manner of Co and Pt from Pt3Co/C catalyst used as the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.02.2020


Controllable chemoselective hydrogenation of furfural by PdAg/C bimetallic catalysts under ambient operating conditions: an interesting Ag switch

Green Chem., 2020, 22,1432-1442
DOI: 10.1039/C9GC03693H, Paper
Zhi-Lei Wu, Jian Wang, Shuo Wang, Ya-Xin Zhang, Guo-Yi Bai, Luis Ricardez-Sandoval, Gui-Chang Wang, Bin Zhao
Selectivity reversal for the hydrogenation of furfural is acheived by PdAg/C bimetallic catalysts under ambient conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.02.2020


Muconic acid isomers as platform chemicals and monomers in the biobased economy

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04161C, Critical Review
Ibrahim Khalil, Greg Quintens, Tanja Junkers, Michiel Dusselier
A complete overview of the chemical and biotechnological synthesis of muconic acid, its isomerization, and valorization into chemicals and polymers is presented.
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Datum: 07.02.2020


Applications of ionic liquids in starch chemistry: a review

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03738A, Tutorial Review
Fei Ren, Jinwei Wang, Fengwei Xie, Ke Zan, Shuo Wang, Shujun Wang
Recently, the use of ionic liquids as promising “green solvents” in starch chemistry has gained extensive interest, especially in the areas of chemical modification of starch and the development of starch-based materials.
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Datum: 07.02.2020


Cobalt catalyzed electrochemical [4 + 2] annulation for the synthesis of sultams

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00289E, Communication
Yangmin Cao, Yong Yuan, Yueping Lin, Xiaomei Jiang, Yaqing Weng, Tangwei Wang, Faxiang Bu, Li Zeng, Aiwen Lei
Cobalt catalyzed electrochemical [4 + 2] annulation of sulfonamides with alkynes is demonstrated in this work, which provided a practical and environmentally friendly way to synthesize structurally diverse sultams.
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Datum: 07.02.2020


Patterning of metal oxide thin films using a H2/He atmospheric pressure plasma jet

Green Chem., 2020, 22,1406-1413
DOI: 10.1039/D0GC00080A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. Emre Sener, Sanjayan Sathasivam, Robert Palgrave, Raul Quesada Cabrera, Daren J. Caruana
Localised and directional micro-scale reduction of metal oxide surfaces, using a hydrogen-doped helium atmospheric pressure plasma jet.
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Datum: 07.02.2020


Visible-light-induced decarboxylative acylation of quinoxalin-2(1H)-ones with α-oxo carboxylic acids under metal-, strong oxidant- and external photocatalyst-free conditions

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03899J, Paper
Long-Yong Xie, You-Shu Bai, Xiang-Qin Xu, Xia Peng, Hai-Shan Tang, Ying Huang, Ying-Wu Lin, Zhong Cao, Wei-Min He
An eco-friendly visible-light-induced decarboxylative acylation of quinoxalin-2(1H)-ones and α-oxo carboxylic acids with air as the oxidant under external-photocatalyst-free conditions was established.
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Datum: 06.02.2020


Seed- and solvent-free synthesis of ZSM-5 with tuneable Si/Al ratios for biomass hydrogenation

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03622A, Paper
Bin Zhang, Mark Douthwaite, Qiang Liu, Chao Zhang, Qifan Wu, Ruhui Shi, Peixuan Wu, Ke Liu, Zhuangqing Wang, Weiwei Lin, Haiyang Cheng, Ding Ma, Fengyu Zhao, Graham J. Hutchings
Seed- and solvent-free synthesis of MFI zeolites with tuneable Si/Al ratios (18-∞) was achieved. The key role of F was evidenced that forming 6-coordinated “F–Al–O–Si” species drove the formation of the zeolitic framework during crystallization.
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Datum: 06.02.2020


Synthesis and polymerisation of α-alkylidene cyclic carbonates from carbon dioxide, epoxides and the primary propargylic alcohol 1,4-butynediol

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04320A, Communication
Saumya Dabral, Ulrike Licht, Peter Rudolf, Gérard Bollmann, A. Stephen. K. Hashmi, Thomas Schaub
Using the bulk chemical 1,4-butynediol, readily available epoxides and carbon dioxide, a new series of unsubstituted exovinylene carbonates were synthesised.
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Datum: 06.02.2020


Continuous-flow photo-induced decarboxylative annulative access to fused imidazole derivatives via a microreactor containing immobilized ruthenium

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03496J, Communication
Praveen Reddy Adiyala, Seungwook Jang, Niraj K. Vishwakarma, Yoon-Ho Hwang, Dong-Pyo Kim
Continuous-flow visible-light-induced decarboxylative annulation using a polydimethylsiloxane microreactor containing immobilized Ru3+ has been established for the construction of fused imidazole derivatives.
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Datum: 06.02.2020


Correction: Synthesis of dibenzocycloketones by acyl radical cyclization from aromatic carboxylic acids using methylene blue as a photocatalyst

Green Chem., 2020, 22,1443-1443
DOI: 10.1039/D0GC90015J, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hongshuo Jiang, Guijie Mao, Hongfeng Wu, Qi An, Minghui Zuo, Weihao Guo, Chunzhao Xu, Zhizhong Sun, Wenyi Chu
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Datum: 06.02.2020


Soy protein and chitin sponge-like scaffolds: from natural by-products to cell delivery systems for biomedical applications

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00089B, Paper
Kevin Las Heras, Edorta Santos-Vizcaino, Tania Garrido, Francisco Borja Gutierrez, Jose Javier Aguirre, Koro de la Caba, Pedro Guerrero, Manoli Igartua, Rosa Maria Hernandez
Natural and renewable resources, such as plant proteins and marine polysaccharides, to manufacture scaffolds with suitable properties for biomedical applications.
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Datum: 06.02.2020


An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst- and oxidant-free conditions

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03797G, Communication
Dongdong He, Jiaojiao Yao, Boling Ma, Jinghao Wei, Guangguo Hao, Xun Tuo, Shengmei Guo, Zhengjiang Fu, Hu Cai
Various aryl seleno/thiocyanates have been synthesized via the electrochemical deborylative seleno/thiocyanation of arylboronic acids under ambient conditions.
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Datum: 04.02.2020


Ethyl acetate as solvent for the synthesis of poly(2-ethyl-2-oxazoline)

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03872H, Paper
Maarten Vergaelen, Bart Verbraeken, Joachim F. R. Van Guyse, Annelore Podevyn, Ali Tigrine, Victor R. de la Rosa, Bryn D. Monnery, Richard Hoogenboom
Addressing the polymerization of 2-ethyl-2-oxazoline (EtOx) in ethyl acetate to replace the current state-of-the-art solvents. The switch to ethyl acetate is important towards pharmaceutical compliance/compatibility of PEtOx, besides low environmental burden.
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Datum: 03.02.2020


Visible-light-induced selective aerobic oxidation of sp3 C–H bonds catalyzed by a heterogeneous AgI/BiVO4 catalyst

Green Chem., 2020, 22,1156-1163
DOI: 10.1039/C9GC03727F, Communication
Li-Ya Jiang, Jing-Jing Ming, Lian-Yue Wang, Yuan-Yuan Jiang, Lan-Hui Ren, Zi-Cheng Wang, Wen-Chen Cheng
An efficient oxidation of sp3 C–H bonds to esters and ketones has been developed using AgI/BiVO4 as the photocatalyst and O2 as the oxidant in water.
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Datum: 03.02.2020


Sulfonated dendritic mesoporous silica nanospheres: a metal-free Lewis acid catalyst for the upgrading of carbohydrates

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03489G, Paper
Erlen Y. C. Jorge, Carolina G. S. Lima, Thiago M. Lima, Lucas Marchini, Manoj B. Gawande, Ondřej Tomanec, Rajender S. Varma, Marcio W. Paixão
Lignocellulosic biomass is becoming a viable alternative or a complementary source for obtaining petroleum-derived products such as fuels, polymers and fine chemicals, among others.
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Datum: 03.02.2020


Carbon dots as photocatalysts for organic synthesis: metal-free methylene–oxygen-bond photocleavage

Green Chem., 2020, 22,1145-1149
DOI: 10.1039/C9GC03811F, Communication
Simone Cailotto, Matteo Negrato, Salvatore Daniele, Rafael Luque, Maurizio Selva, Emanuele Amadio, Alvise Perosa
We report for the first time that irradiation of four different citric acid-derived carbon dots (CDs), in the absence of any other redox mediators, promotes an organic reaction.
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Datum: 31.01.2020


CO2 and CH4 conversion in “real” gas mixtures in a gliding arc plasmatron: how do N2 and O2 affect the performance?

Green Chem., 2020, 22,1366-1377
DOI: 10.1039/C9GC03743H, Paper
Joachim Slaets, Maryam Aghaei, Sara Ceulemans, Senne Van Alphen, Annemie Bogaerts
Combined experiments and modelling for CO2/CH4 conversion into syngas upon adding O2 and N2 in a gliding arc plasmatron.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.01.2020


Strategies for structuring diverse emulsion systems by using wood lignocellulose-derived stabilizers

Green Chem., 2020, 22,1019-1037
DOI: 10.1039/C9GC04457D, Critical Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kirsi S. Mikkonen
Wood cellulose, lignin, and hemicelluloses are abundant bioresources that can be valorized as sustainable emulsion stabilizers. The lignocellulose-derived stabilizers may act as surface-active compounds, Pickering particles, or viscosity enhancers.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.01.2020


Visible-light-initiated regioselective sulfonylation/cyclization of 1,6-enynes under photocatalyst- and additive-free conditions

Green Chem., 2020, 22,1388-1392
DOI: 10.1039/C9GC03769A, Paper
Xiao-Xiao Meng, Qing-Qing Kang, Jun-Yao Zhang, Qiang Li, Wen-Ting Wei, Wei-Min He
Without employing a photocatalyst or additive, a strategy has been developed for the visible-light-initiated regioselective sulfonylation/cyclization of 1,6-enynes in 2-methylTHF from sulfonyl chlorides under open-air conditions at room temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.01.2020


Covalent triazine frameworks – a sustainable perspective

Green Chem., 2020, 22,1038-1071
DOI: 10.1039/C9GC03482J, Critical Review
Chidharth Krishnaraj, Himanshu Sekhar Jena, Karen Leus, Pascal Van Der Voort
Rise of porous covalent triazine frameworks (CTFs) for sustainable applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.01.2020


Synergetic combination of a mesoporous polymeric acid and a base enables highly efficient heterogeneous catalytic one-pot conversion of crude Jatropha oil into biodiesel

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04135D, Paper
Hu Pan, Yanan Liu, Qineng Xia, Heng Zhang, Li Guo, Hu Li, Lingchang Jiang, Song Yang
Highly efficient conversion of crude Jatropha oil to biodiesel was realized under mild conditions via a synergistic catalytic system consisting of acid (MICPHPW) and base (MICPOH) catalysts using a ‘one-pot, two-step’ strategy.
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Datum: 29.01.2020


A facile method for the simultaneous recovery of rare-earth elements and transition metals from Nd–Fe–B magnets

Green Chem., 2020, 22,1105-1112
DOI: 10.1039/C9GC03325D, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Xuan Xu, Saso Sturm, Zoran Samardzija, Janez Scancar, Katarina Markovic, Kristina Zuzek Rozman
A closed loop of recovering rare-earth elements and transition metals from Nd–Fe–B magnets with the total re-use of the electrolyte using a facile electrolysis-selective precipitation procedure.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.01.2020


Transition metal- and solvent-free double hydroboration of nitriles

Green Chem., 2020, 22,1125-1128
DOI: 10.1039/C9GC04260A, Communication
Deepika Bedi, Aneelman Brar, Michael Findlater
An operationally convenient, room temperature synthesis of N,N-diborylated amines via hydroboration of nitriles using a commercially available catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.01.2020


A hydrophilic heterogeneous cobalt catalyst for fluoride-free Hiyama, Suzuki, Heck and Hirao cross-coupling reactions in water

Green Chem., 2020, 22,1353-1365
DOI: 10.1039/C9GC03455B, Paper
Sara Sobhani, Hadis Hosseini Moghadam, Jørgen Skibsted, José Miguel Sansano
A hydrophilic chitosan-cobalt-Schiff base catalyst denoted as mTEG-CS-Co-Schiff-base was prepared for C–C and C–P cross coupling reactions in water.
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Datum: 29.01.2020


Tuning Ca–Al-based catalysts’ composition to isomerize or epimerize glucose and other sugars

Green Chem., 2020, 22,1393-1405
DOI: 10.1039/C9GC02823D, Paper
Maria Ventura, Juan A. Cecilia, Enrique Rodríguez-Castellón, Marcelo E. Domine
Efficient and selective glucose isomerization to fructose and epimerization to mannose were successfully done over tuneable Ca–Al-based catalysts with controlled basicity.
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Datum: 28.01.2020


Replacing methanol with azeotropic ethanol as the co-solvent for improved chiral separations with supercritical fluid chromatography (SFC)

Green Chem., 2020, 22,1249-1257
DOI: 10.1039/C9GC04207E, Paper
Daipayan Roy, M. Farooq Wahab, Mohsen Talebi, Daniel W. Armstrong
Using azeoptropic ‘190 proof’ ethanol eliminates the use of methanol in chiral super/subcritical fluid chromatography.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.01.2020


Maleic acid as a dicarboxylic acid hydrotrope for sustainable fractionation of wood at atmospheric pressure and ≤100 °C: mode and utility of lignin esterification

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04267A, Paper
Cheng Cai, Kolby Hirth, Rolland Gleisner, Hongming Lou, Xueqing Qiu, J. Y. Zhu
Maleic acid for wood fractionation at atmospheric pressure to result in carboxylated lignin with minimal condensation, light color, and to facilitate processing of fractionated solids. 2D 1H–13C HQSC and HMBC analyses confirmed lignin esterification.
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Datum: 28.01.2020


Effective separation of surfactant-stabilized crude oil-in-water emulsions by using waste brick powder-coated membranes under corrosive conditions

Green Chem., 2020, 22,1345-1352
DOI: 10.1039/C9GC04178H, Paper
Guogui Shi, Yongqian Shen, Peng Mu, Qingtao Wang, Yaoxia Yang, Siyi Ma, Jian Li
Underwater superoleophobic WBP-coated membranes were employed to effectively separate crude oil-in-water emulsions under corrosive conditions.
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Datum: 27.01.2020


Electrochemical-induced regioselective C-3 thiomethylation of imidazopyridines via a three-component cross-coupling strategy

Green Chem., 2020, 22,1129-1133
DOI: 10.1039/C9GC04068D, Communication
Jiangwei Wen, Cong Niu, Kelu Yan, Xingda Cheng, Ruike Gong, Mengqian Li, Yongqiang Guo, Jianjing Yang, Hua Wang
The electrochemical-induced regioselective C-3 thiomethylation of imidazopyridines has been initially accomplished via a three-component cross-coupling strategy using thiocyanate as the sulfur source and methanol as the methyl reagent.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.01.2020


One-step electrodeposition of NixFe3−xO4/Ni hybrid nanosheet arrays as highly active and robust electrocatalysts for the oxygen evolution reaction

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00168F, Paper
Dongjie Li, Suqin Liu, Guanying Ye, Weiwei Zhu, Kuangmin Zhao, Meng Luo, Zhen He
NixFe3−xO4/Ni hybrid nanosheet arrays have been directly fabricated on different substrates via template-free and annealing-free one-step electrodeposition, which show excellent catalytic performance for the oxygen evolution reaction.
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Datum: 27.01.2020


Nickel on nitrogen-doped carbon pellets for continuous-flow hydrogenation of biomass-derived compounds in water

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03826D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Francesco Brandi, Marius Bäumel, Valerio Molinari, Irina Shekova, Iver Lauermann, Tobias Heil, Markus Antonietti, Majd Al-Naji
A cheap, scalable and efficient nickel catalyst on nitrogen-doped carbon for the aqueous-phase hydrogenation of biomass-derived compounds in flow system.
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Datum: 27.01.2020


Enzymatic one-pot synthesis of renewable and biodegradable surfactants in supercritical carbon dioxide (scCO2)

Green Chem., 2020, 22,1308-1318
DOI: 10.1039/C9GC04011K, Paper
Mariana d'Almeida Gameiro, Amy Goddard, Vincenzo Taresco, Steven M. Howdle
We exploit enzymatic catalysis in supercritical carbon dioxide to create novel, linear and degradable amphiphilic polymers that can act as surfactants.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.01.2020


Catalyst-free selective N-formylation and N-methylation of amines using CO2 as a sustainable C1 source

Green Chem., 2020, 22,1134-1138
DOI: 10.1039/C9GC03637G, Communication
Qizhuang Zou, Guangcai Long, Tianxiang Zhao, Xingbang Hu
We herein describe catalyst-free selective N-formylation and N-methylation of amines using CO2 as a sustainable C1 source.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.01.2020


Borate chemistry inspired by cell walls converts soy protein into high-strength, antibacterial, flame-retardant adhesive

Green Chem., 2020, 22,1319-1328
DOI: 10.1039/C9GC03875B, Paper
Weidong Gu, Feng Li, Xiaorong Liu, Qiang Gao, Shanshan Gong, Jianzhang Li, Sheldon Q. Shi
Borate chemically cross-linked soy protein to prepare high-strength, antibacterial, flame-retardant bio-adhesive.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.01.2020


Site-selective 1,3-double functionalization of arenes using para-quinol, C–N, and C–C/C–P three-component coupling

Green Chem., 2020, 22,1119-1124
DOI: 10.1039/C9GC04103F, Communication
Saddam Husen, Anil Chauhan, Ravindra Kumar
A catalytic and site-selective approach has been demonstrated for dual functionalization of arenes via cross-coupling reactions of p-quinols with amines and isocyanides/phosphites.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.01.2020


Greening Fmoc/tBu solid-phase peptide synthesis

Green Chem., 2020, 22,996-1018
DOI: 10.1039/C9GC03982A, Critical Review
Othman Al Musaimi, Beatriz G. de la Torre, Fernando Albericio
Introducing the green chemistry concept in solid-phase peptide synthesis (SPPS).
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.01.2020


Waterborne isocyanate-free polyurethane epoxy hybrid coatings synthesized from sustainable fatty acid diamine

Green Chem., 2020, 22,1329-1337
DOI: 10.1039/C9GC03335A, Paper
Cheng Zhang, Haoran Wang, Qixin Zhou
This study proposed an effective method to prepare environmental-friendly waterborne epoxy modified non-isocyanate polyurethanes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.01.2020


Scrap waste automotive converters as efficient catalysts for the continuous-flow hydrogenations of biomass derived chemicals

Green Chem., 2020, 22,1414-1423
DOI: 10.1039/C9GC04091A, Paper
Camilla Maria Cova, Alessio Zuliani, Roberta Manno, Victor Sebastian, Rafael Luque
The catalytic activity of scrap ceramic-cores of automotive catalytic converters (SCATs) was investigated in the continuous-flow hydrogenation of different biomass-derived chemicals.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.01.2020


A solvent-free strategy to realize the substitution of I− for IO3− in a BiOIO3 photocatalyst with an opposite charge transfer path

Green Chem., 2020, 22,1424-1431
DOI: 10.1039/C9GC03731D, Paper
Jing Xie, Yali Cao, Jindou Hu, Yakun Tang, Dianzeng Jia
A photocatalyst was first synthesized by replacing IO3 with I in BiOIO3via a simple solvent-free method and it exhibited excellent photocatalytic performance.
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Datum: 24.01.2020


Regio/site-selective alkylation of substrates containing a cis-, 1,2- or 1,3-diol with ferric chloride and dipivaloylmethane as the catalytic system

Green Chem., 2020, 22,1139-1144
DOI: 10.1039/C9GC04126E, Communication
Jian Lv, Yu Liu, Jia-Jia Zhu, Dapeng Zou, Hai Dong
We reported the regio/site-selective alkylation of diols and polyols with FeCl3 as a key catalyst and confirmed the mechanism.
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Datum: 24.01.2020


Selective hydrodeoxygenation of lignin phenols to alcohols in the aqueous phase over a hierarchical Nb2O5-supported Ni catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03842F, Paper
Wenjing Song, Yanyan He, Sitong Lai, Weikun Lai, Xiaodong Yi, Weimin Yang, Xingmao Jiang
Lignin-derived phenols can be highly selectively converted to alcohols in the aqueous phase over hierarchical Ni/Nb2O5 assembled from Nb2O5 nanoplates.
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Datum: 24.01.2020


Colloidal Co single-atom catalyst: a facile synthesis strategy and high catalytic activity for hydrogen generation

Green Chem., 2020, 22,1269-1274
DOI: 10.1039/C9GC03477C, Paper
Junkai Wang, Zhenxia Huang, Lilin Lu, Quanli Jia, Liang Huang, Shuai Chang, Mingyang Zhang, Zuotai Zhang, Sun Li, Dongsheng He, Wenhao Wu, Shaowei Zhang, Naoki Toshima, Haijun Zhang
A facile route for on-demand hydrogen production via simply controlling the mixing process of a KBH4 solution and an aqueous solution of ISOBAM-104 stabilized Co2+ ions.
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Datum: 24.01.2020


Selective conversion of lignin to ethylbenzene

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04246F, Paper
Zhicheng Luo, Shufang Qin, Shuang Chen, Yingshuang Hui, Chen Zhao
The developed strategy enables the selective production of value-added ethylbenzene from lignin valorization.
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Datum: 22.01.2020


Recycling non-food-grade tree gum wastes into nanoporous carbon for sustainable energy harvesting

Green Chem., 2020, 22,1198-1208
DOI: 10.1039/C9GC04310A, Paper
Abhilash Venkateshaiah, Jun Young Cheong, Sung-Ho Shin, K. P. Akshaykumar, Tae Gwang Yun, Jaehyeong Bae, Stanisław Wacławek, Miroslav Černík, Seema Agarwal, Andreas Greiner, Vinod V. T. Padil, Il-Doo Kim, Rajender S. Varma
Nanoporous carbon (nC), as electricity source, is prepared from low-grade tree-gum wastes via carbonization and exfoliation.
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Datum: 22.01.2020


Gas-phase bioproduction of a high-value-added monoterpenoid (E)-geranic acid by metabolically engineered Acinetobacter sp. Tol 5

Green Chem., 2020, 22,1258-1268
DOI: 10.1039/C9GC03478A, Paper
Atsushi Usami, Masahito Ishikawa, Katsutoshi Hori
Here we report the gas-phase bioproduction of (E)-geranic acid, a high-value-added monoterpenoid, from gaseous geraniol by Acinetobacter sp. Tol 5.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.01.2020


Lipase-catalyzed ring-opening copolymerization of ω-pentadecalactone and δ-valerolactone by reactive extrusion

Green Chem., 2020, 22,662-668
DOI: 10.1039/C9GC04111G, Communication
Changcun Li, Shuaijun Pan, Weijian Xu, Yanbing Lu, Peipei Wang, Fuming Zhang, Richard Alan Gross
This work demonstrates the synthesis of poly(ω-pentadecalactone-co-δ-valeroLactone) with high molecular weight (Mn = 71.3 kDa) and low polydispersity (Đ = 1.67) within 6 hours by reactive extrusion (REX) using a lipase catalyst (Novozyme-435).
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Datum: 22.01.2020


CO2 hydrogenation to formic acid over heterogenized ruthenium catalysts using a fixed bed reactor with separation units

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03685G, Paper
Kwangho Park, Gunniya Hariyanandam Gunasekar, Seong-Hoon Kim, Hongjin Park, Samhwan Kim, Kiyoung Park, Kwang-Deog Jung, Sungho Yoon
An integrated continuous CO2 hydrogenation to formic acid process with trickle-bed reactor is developed using a heterogeneous Ru molecular catalyst.
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Datum: 22.01.2020


Generation of ironized and multivitamin-loaded liposomes using venturi-based rapid expansion of a supercritical solution (Vent-RESS)

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04018H, Paper
Farrokh Sharifi, Apratim Jash, Alireza Abbaspourrad, Syed S. H. Rizvi
Ironized multivitamin-loaded liposomes were generated via supercritical-CO2 (SC-CO2) as a green solvent without using any organic solvent.
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Datum: 22.01.2020


Photochemical evolution of hydrogen peroxide on lignins

Green Chem., 2020, 22,673-677
DOI: 10.1039/C9GC04324A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Eva Miglbauer, Maciej Gryszel, Eric Daniel Głowacki
Means of sustainable on-demand hydrogen peroxide production are sought after for numerous industrial, agricultural, and environmental applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.01.2020


Pd@COF-QA: a phase transfer composite catalyst for aqueous Suzuki–Miyaura coupling reaction

Green Chem., 2020, 22,1150-1155
DOI: 10.1039/C9GC03718G, Communication
Jian-Cheng Wang, Cong-Xue Liu, Xuan Kan, Xiao-Wei Wu, Jing-Lan Kan, Yu-Bin Dong
A COF-based phase transfer catalyst and its continuous flow-through reactor was prepared. The obtained Pd@COF-QA can highly promote the Suzuki–Miyaura coupling reaction in water under mild conditions even at gram scale level.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.01.2020


Selective hydrogenation of 5-hydroxymethylfurfural and its acetal with 1,3-propanediol to 2,5-bis(hydroxymethyl)furan using supported rhenium-promoted nickel catalysts in water

Green Chem., 2020, 22,1229-1238
DOI: 10.1039/C9GC03856F, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jan J. Wiesfeld, Minjune Kim, Kiyotaka Nakajima, Emiel J. M. Hensen
High BHMF yield is achieved by protecting the formyl group of 5-HMF and subsequently balancing its rate of deprotection during the hydrogenation reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.01.2020


Mechanistic insights into the lignin dissolution behaviors of a recyclable acid hydrotrope, deep eutectic solvent (DES), and ionic liquid (IL)

Green Chem., 2020, 22,1378-1387
DOI: 10.1039/C9GC02760B, Paper
Hairui Ji, Pingli Lv
Mechanistic insights into lignin dissolution behaviors of a recyclable acid hydrotrope (p-TsOH), deep eutectic solvent (DES, ChCl-Lac), and ionic liquid (IL, [Amim][Cl]) were carried out by combined quantum chemistry calculations and molecular dynamics simulations.
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Datum: 21.01.2020


Microwave-assisted unprotected Sonogashira reaction in water for the synthesis of polysubstituted aromatic acetylene compounds

Green Chem., 2020, 22,1338-1344
DOI: 10.1039/C9GC04051J, Paper
Yucheng Tian, Jubo Wang, Xinying Cheng, Kang Liu, Tizhi Wu, Xiaqiu Qiu, Zijian Kuang, Zhiyu Li, Jinlei Bian
A series of porous aromatic framework material units were obtained by performing microwave-assisted Sonogashira reactions in water without inert gas protection.
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Datum: 20.01.2020


Visible light-assisted reduction of CO2 into formaldehyde by heteroleptic ruthenium metal complex–TiO2 hybrids in an aqueous medium

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03549D, Paper
Alok Kumar, Rajakumar Ananthakrishnan
Reduction of CO2 was achieved by Ru(II) complex-TiO2 hybrid under visible light in an aqueous neutral medium. The major product formaldehyde was obtained with trace of CO and CH4. Further, in situ formed CH2O was reacted with an amine to arrive useful products.
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Datum: 20.01.2020


Hydrogen production from formic acid catalyzed by a phosphine free manganese complex: investigation and mechanistic insights

Green Chem., 2020, 22,913-920
DOI: 10.1039/C9GC02453K, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Alexander Léval, Anastasiya Agapova, Christoph Steinlechner, Elisabetta Alberico, Henrik Junge, Matthias Beller
Formic acid dehydrogenation (FAD) is considered as a promising process in the context of hydrogen storage.
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Datum: 20.01.2020


Design of nitrogen-doped graphitized 2D hierarchical porous carbons as efficient solid base catalysts for transesterification to biodiesel

Green Chem., 2020, 22,903-912
DOI: 10.1039/C9GC03960K, Paper
Weiping Kong, Fujian Liu, Yong Liu
2D graphitized porous carbons decorated with high contents of nitrogen sites such as pyridinic nitrogen were developed, which were used as efficient and reusable solid base catalysts for transesterification to biodiesel.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.01.2020


Recent advances in the selective catalytic hydrodeoxygenation of lignin-derived oxygenates to arenes

Green Chem., 2020, 22,1072-1098
DOI: 10.1039/C9GC02762A, Tutorial Review
Jianghao Zhang, Junming Sun, Yong Wang
We summarize the recent advances, challenges, and perspectives in developing selective catalysts for HDO of phenolics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.01.2020


Template-free synthesis of graphene-like carbons as efficient carbocatalysts for selective oxidation of alkanes

Green Chem., 2020, 22,1291-1300
DOI: 10.1039/C9GC03781K, Paper
Xiang Hu, Yuchuan Liu, Haitao Huang, Baobing Huang, Guoliang Chai, Zailai Xie
The N-doped and N/S codoped carbon nanosheets were fabricated by metal-free carbonization of nucleobase, which can be used as efficient carbocatalysts for selective oxidation of alkanes.
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Datum: 15.01.2020


Facile synthesis of “digestible”, rigid-and-flexible, bio-based building block for high-performance degradable thermosetting plastics

Green Chem., 2020, 22,1275-1290
DOI: 10.1039/C9GC04020J, Paper
Binbo Wang, Songqi Ma, Qiong Li, Hua Zhang, Junjie Liu, Rong Wang, Zhiquan Chen, Xiwei Xu, Sheng Wang, Na Lu, Yanlin Liu, Shifeng Yan, Jin Zhu
A bio-sourced, low-toxic monomer was facilely synthesized and used to build controlled degradable, strong and tough thermosetting plastics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 15.01.2020


Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters

Green Chem., 2020, 22,1301-1307
DOI: 10.1039/C9GC03957K, Paper
Ziqiang Yan, Xiaoyu Xie, Qun Song, Fulei Ma, Xinyu Sui, Ziyu Huo, Mingming Ma
Five categories of valuable N-containing compounds can be selectively synthesized by the catalytic tandem reduction of nitroarenes with in situ generated Pd nanoclusters as the catalyst.
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Datum: 15.01.2020


An unconventional sulfur-to-selenium-to-carbon radical transfer: chemo-and regioselective cyclization of yne-ynamides

Green Chem., 2020, 22,1113-1118
DOI: 10.1039/C9GC03745D, Communication
Shubham Dutta, B. Prabagar, Rajeshwer Vanjari, Vincent Gandon, Akhila K. Sahoo
An uncommon sulfur → selenium → carbon radical transfer process is employed to develop an unprecedented selenyl radical-mediated regioselective cyclization of yne-tethered-ynamides.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.01.2020


Thermal [2 + 2]-cycloaddition between silylalkynes and allenylphenols followed by the nucleophilic addition of water: metal-free and economical synthesis of arylcyclobutenals

Green Chem., 2020, 22,1220-1228
DOI: 10.1039/C9GC04184B, Paper
Shohei Ohno, Ramon Francisco Avena, Hiroshi Aoyama, Hiromichi Fujioka, Mitsuhiro Arisawa
A novel thermal [2 + 2]-cycloaddition between silylalkynes and allenylphenols to form a cyclobutachromene intermediate, followed by the nucleophilic addition of water to yield functionalized arylcyclobutenals.
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Datum: 13.01.2020


Ecotoxicological assessment of pharmaceuticals and personal care products using predictive toxicology approaches

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03265G, Critical Review
Supratik Kar, Hans Sanderson, Kunal Roy, Emilio Benfenati, Jerzy Leszczynski
The present review critically assesses the hazardous potential of pharmaceuticals and personal care products (PPCPs) in the environment and the description of the important in silico modeling approaches for assessing the toxicity of PPCPs towards diverse organisms.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.01.2020


Fast synthesis of hierarchical Al-free Ti-BEA plate-like nanocrystals from low-templated dry gel via a steam-assisted conversion method

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03869H, Paper
Yuying Luo, Yadong Zhu, Jianguo Pan, Xiaohui Chen
A hierarchical nanosized Ti-BEA zeolite prepared via a green steam-assisted conversion (SAC) method.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.01.2020


Aqueous electrosynthesis of silver indium selenide nanocrystals and their photothermal properties

Green Chem., 2020, 22,1239-1248
DOI: 10.1039/C9GC03647D, Paper
Felipe L. N. Sousa, Brenand A. S. Souza, Anderson C. Jesus, Walter M. Azevedo, Herman S. Mansur, Denilson V. Freitas, Marcelo Navarro
The eco-friendly aqueous electrosynthesis of AgIn5Se8 (AISe) nanocrystals (NCs), and their respective core/shell structure AgIn5Se8/ZnS NCs (AISe/ZnS), was carried out by using L-glutathione (GSH) as a stabilizer.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.01.2020


Smart and sustainable design of latent catalyst-containing benzoxazine-bio-resins and application studies

Green Chem., 2020, 22,1209-1219
DOI: 10.1039/C9GC03504D, Paper
Kan Zhang, Yuqi Liu, Mengchao Han, Pablo Froimowicz
A fully bio-based benzoxazine containing latent catalytic system is designed and successfully synthesized and it can be used as both an initiator and a beneficial property modifier of other thermosetting systems, especially for fire related properties.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.01.2020


Mechanistic studies of milled and Kraft lignin oxidation by radical species

Green Chem., 2020, 22,1182-1197
DOI: 10.1039/C9GC04162A, Paper
Maryam Davaritouchaee, William C. Hiscox, Evan Terrell, Rock J. Mancini, Shulin Chen
Accomplishing selective lignin degradation in a controlled manner by breaking C–O and C–C bonds is of great scientific interest although technically challenging.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.12.2019


Catalyst-free, direct electrochemical synthesis of annulated medium-sized lactams through C–C bond cleavage

Green Chem., 2020, 22,1099-1104
DOI: 10.1039/C9GC03901E, Communication
Zhongnan Xu, Zhixing Huang, Yueheng Li, Rositha Kuniyil, Chao Zhang, Lutz Ackermann, Zhixiong Ruan
Expanding ring under green electricity: The electrosynthetic approach enabled atom-economical synthesis of challenging medium-sized lactams through a unique remote amidyl migration under exceedingly mild, transition metal- and oxidant-free conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.12.2019


Pentanoic acid from γ-valerolactone and formic acid using bifunctional catalysis

Green Chem., 2020, 22,1171-1181
DOI: 10.1039/C9GC02627D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Majd Al-Naji, Joost Van Aelst, Yuhe Liao, Martin d'Hullian, Zhipeng Tian, Chenguang Wang, Roger Gläser, Bert F. Sels
The production of pentanoic acid from γ-valerolactone and the one-pot route from levulinic acid both over bifunctional catalyst with formic acid as H2 source is an example for an integrated biorefinery in the direction to an industrial application.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.11.2019


Visible light-promoted copper catalyzed regioselective acetamidation of terminal alkynes by arylamines

Green Chem., 2020, 22,1164-1170
DOI: 10.1039/C9GC03608C, Paper
V. Kishore Kumar Pampana, Arunachalam Sagadevan, Ayyakkannu Ragupathi, Kuo Chu Hwang
Herein, we describe a copper photoredox catalyzed synthesis of acetamide via regioselective C–N coupling of arylamines with terminal alkynes using molecular oxygen (O2) as an oxidant at room temperature under visible light irradiation (47 examples).
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.11.2019


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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