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Green Chemistry

Current research reports and chronological list of recent articles..




The international scientific journal Green Chemistry publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research and policy relating to the endeavour are welcome.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles see Current Chemistry Research Articles. Magazines with similar content (sustainable and green chemistry):

 - ChemSusChem.

 - Environmental Chemistry.

 - Green Chemistry Letters and Reviews.



Green Chemistry - Abstracts



Bifunctional Small Molecule Photocatalyst with Redox Center and Lewis Acid Site for One-pot Tandem Oxidation-Acetalization

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01321E, Paper
Caihui Rao, Shuai Ma, Jing-Wang Cui, Meng-Ze Jia, Xinrong Yao, Jie Zhang
By combining the double identity of redox center and Lewis acid sites of the pyridinium derivative, the first bifunctional small molecule photocatalyst has been developed for one-pot tandem oxidation-acetalization reaction....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.07.2022


What is the best scenario to utilize landfill gas?: Quantitative and qualitative approaches for technical, economic, and environmental feasibility

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01108E, Paper
Manhee Byun, Heehyang Kim, Aejin Lee, Seunghyun Cheon, Jiwon Gu, Hankwon Lim
To overcome the global increasing trend of environmentally harmful waste of landfill gas (LFG) generation derived from a huge amount of municipal solid waste, various research on utilization of LFG...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.07.2022


Graphdiyne-based photocatalysts for solar fuel production

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01684B, Tutorial Review
Chuanbiao Bie, Bei Cheng, Wing-Kei Ho, Youji Li, Wojciech Macyk, Jahan B Ghasemi, jiaguo yu
Graphdiyne is an emerging material widely applied in photocatalysis. Its excellent physicochemical properties, such as nonuniform electron distribution, uniform pore distribution, excellent electron mobility, and high chemical stability, make it...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Construction of "environmental-friendly" CuBx@PU self-supporting electrode toward efficient seawater electrolysis

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01819E, Paper
Yiran Zhang, Chengyu Fu, Shuo Weng, Haiyang Lv, Peng Li, Shengwei Deng, Weiju Hao
It is of great significance to realize green development of high-efficient and economical catalysts modified stably on the "white plastic" surface for grid-scale hydrogen production coupling plastic degradation by alkaline...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Recent advances of lignin-based carbon fibers (LCFs): precursors, fabrications, properties, and applications

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01503J, Critical Review
Shao-Chao Sun, Ying Xu, Jia-Long Wen, Tong-Qi Yuan, Runcang Sun
To meet the huge market demand for carbon fibers (CFs), great efforts have been focused on developing low-cost and sustainable CFs with comparable properties. Lignin, a polyaromatic heteropolymer in nature,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Photo-Medicated Synthesis of 1,2-Dideoxy-2-phosphinylated Carbohydrates from Glycals: The Reduction of Glycosyl Radicals to Glycosyl Anions

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01513G, Paper
Hai Li, Kai-Cheng Yu, Jia-Kun Su, Wei Ouyang, Nai-Li Fan, Xiang-Guo Hu
We have developed a photo-mediated method for the synthesis of C2- phosphinylated carbohydrates from glycals and diarylphosphine oxides. This approach avoids over-stoichiometric transition-metal promoters used in previous methods and shows...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Production of lactic acid mediated by compressed carbon dioxide on heterogeneous Ni(II) catalyst: A facile approach

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01172G, Paper
Maya Chatterjee, Abhijit Chatterjee, Hajime Kawanami
Lactic acid is one of the appealing platform molecules in organic synthesis, currently in high demand after the innovation of bio-plastics. The limitations of traditional manufacturing routes (microbial process and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


A hemicellulose-first approach: one-step conversion of sugarcane bagasse to xylooligosaccharides over activated carbon modified with tandem plasma and acid treatments

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01303G, Paper
Shahrooz Rahmati, Luqman Atanda, Michael Horn, Kasup Deshan Athukoralalage Don, Javier Alexander Jimenez Forero, Lalehvash Moghaddam, Deepak P. Dubal, Kostya Ostrikov, William Doherty
With growing awareness of a circular economy, it is necessary to utilize all lignocellulose biomass components as a resource to maintain sustainability. We have selectively targeted the one-step conversion of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Efficient hydrodeoxygenation of guaiacol to phenol over Ru/Ti-SiO2 catalysts: the significance of defect-rich TiOx species

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01714H, Paper
Xinchao Wang, Zhuangqing Wang, Leilei Zhou, Yanchun Liu, Yinze Yang, Liyan Zhang, Zongling Shang, Hui Li, Tingting Xiao, Chao Zhang, Fengyu Zhao
Selective hydrodeoxygenation of lignin-derived phenolics to value-added aromatic products such as phenol with high efficiency and low energy consumption remains an important challenge in the field of biomass conversion. Herein,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Catalyst- and Additive-Free Sunlight-Induced Autoxidation of Aldehydes to Carboxylic Acids

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01429G, Paper
Hongwei Shi, Jun Li, Tao Wang, Matthias Rudolph, Stephen Hashmi
A catalyst- and additive-free sunlight-induce strategy for autoxidation of a wide range of aldehydes to carboxylic acids is described for the first time. In this oxidation system, air as the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Highly Efficient and Robust Aerobic Co-oxidation of Olefins and Aldehydes over CoOx Dispersed within Hierarchical Silicalite-1 Zeolites

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC00625A, Paper
Chenhao Li, Ning Pu, Kaimeng Huang, Changjiu Xia, Xinxin Peng, Min Lin, Bin Zhu, Xingtian Shu
Epoxide compounds are ultra-important intermediates for manufacturing a variety of chemical products, yet their industrial preparation still suffers from some non-negligible drawbacks. Herein, novel CoOx nanoparticles dispersed within internal channels...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Carbon quantum dots anchored on 1,2,3,5-tetrakis(carbazole-9-yl)-4,6-dicyanobenzene for efficient selective photo splitting of biomass-derived sugars to lactic acid

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01465C, Paper
Xiaopan Yang, Kangning Liu, Jiliang Ma, Runcang Sun
The application of photocatalysis in biomass reforming meets the needs of contemporary society for green and sustainable development, and its comprehensive utilization is appealing but challenging. Here, a novel metal-free...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


New Electrotriggers: p-Methoxycarbonylbenzyl (pMCB) as an Electroremovable Protecting Group for Carboxylic Acids, Phosphoric Acids and Alcohols

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC00513A, Paper
Shulin Ning, Lianyou Zheng, Qiansong Gao, Lingling Shi, Yueling Liu, Chengcheng Sun, Zhuoqi Zhang, Jinbao Xiang
Precise release of bioactive molecules is highly desirable in order to optimise drug therapy. Organic electrochemistry offers a highly versatile tool for the selective cleavage of chemical bonds using electrons...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Ionically Conducting Inorganic Binders: A Paradigm Shift in Electrochemical Energy Storage

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01389D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Shivam Trivedi, Venkat Pamidi, Maximilian Fichtner, Anji Reddy Munnangi
Among the key components in batteries, binders play a vital role by interconnecting active materials and conductive additives and facilitating the coating of electrode materials on the desired substrates thus...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.06.2022


Surprisingly Fast Assembly of MOF Film for Synergetic Antibacterial Phototherapeutics

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC00226D, Paper
Jie Gao, Lingwan Hao, Rujian Jiang, Zhuo Liu, Limei Tian, Jie Zhao, Weihua Ming, Luquan Ren
Synergetic photothermal/photodynamic therapy (PTT/PDT) antibacterial surfaces offer a promising avenue for combating bacterial infections, but generally require a time-consuming and cumbersome chemical preparation procedure. Herein, a metal-organic frameworks (MOF) composite...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.06.2022


Delamination of polyamide/polyolefin multilayer films by selective glycolysis of polyurethane adhesive

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01531E, Paper
Galahad O'Rourke, Margot Houbrechts, Marthe Nees, Martijn Roosen, Steven De Meester, Dirk De Vos
Sustainable solvent mediated recycling of plastic multilayer packaging by splitting of polyurethane adhesive glue.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.06.2022


Hydrodeoxygenation of potential platforms derived from biomass to fuels and chemicals

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01289H, Critical Review
Keiichi Tomishige, Mizuho Yabushita, Ji Cao, Yoshinao Nakagawa
Biomass valorization has emerged as a promising and sustainable means of accommodating value-added chemicals. To produce such chemicals, various transformation methods of the top biomass-derived platforms nominated by the U.S....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.06.2022


Switchable Aroylation and Diaroylation of Allyl Sulfones with Aldehydes Enabled by Decatungstate Photocatalysis

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01381A, Paper
Li-Peng Qiao, Xiao-Yang Fu, Ya-Feng Si, Xiaolan Chen, Ling-Bo Qu, Bing Yu
A photocatalytic strategy for the controllable aroylation or diaroylation of allyl sulfones was established by using tetrabutylammonium decatungstate (TBADT) as hydrogen atom transfer (HAT) photocatalyst and aldehydes as radical precursors....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.06.2022


Highly regioselective surface acetylation of cellulose and shaped cellulose constructs in the gas-phase

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01141G, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tetyana Koso, Marco Beaumont, Blaise L. Tardy, Daniel Rico del Cerro, Samuel Eyley, Wim Thielemans, Orlando J. Rojas, Ilkka Kilpeläinen, Alistair W. T. King
Gas-phase acetylation of celluloses is shown to be highly regioselective for 6-OH and confinement of the reaction to the surface.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.06.2022


On-demand, in situ, generation of ammonium caroate (peroxymonosulfate) for the dihydroxylation of alkenes to vicinal diols

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00671E, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin J. Deadman, Sarah Gian, Violet Eng Yee Lee, Luis A. Adrio, Klaus Hellgardt, King Kuok (Mimi) Hii
A sustainable alkene dihydroxylation process was developed, including the on-demand generation of SO52− and a capture-release workup.
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Datum: 21.06.2022


Parallel mechanochemical optimization – Buchwald–Hartwig C–N coupling as a test case

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01460B, Paper
Quentin Lemesre, Thomas Wiesner, Rainer Wiechert, Eduardo Rodrigo, Sonja Triebel, Hervé Geneste
Reaction conditions for mechanochemical Ar-amination were optimized in parallel: in a maximum of four steps [neat, LAG (water or methanol) and AG (sand) conditions] the yield could be significantly improved. The reaction time is short, and the conversion and purity are high.
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Datum: 20.06.2022


Ecotoxicological study of bio-based deep eutectic solvents formed by glycerol derivatives in two aquatic biomodels

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01293F, Paper
Mª Pilar Garralaga, Laura Lomba, Alejandro Leal-Duaso, Sara Gracia-Barberán, Elisabet Pires, Beatriz Giner
The ecotoxicity of some deep eutectic solvents formed by glycerol derivatives have been studied in two aquatic biomodels: Aliivibrio fischeri (bacteria) and Raphidocelis subcapitata (algae). The results show that these chemicals are not toxic for aquatic media.
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Datum: 20.06.2022


Electrosynthesis of amino acids from biomass-derived α-hydroxyl acids

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01779B, Paper
Kaili Yan, Morgan L. Huddleston, Brett A. Gerdes, Yujie Sun
An electrochemical approach is reported to produce amino acids from biomass-derived α-hydroxyl acids.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.06.2022


Biobased thin-film composite membranes comprising priamine–genipin selective layer on nanofibrous biodegradable polylactic acid support for oil and solvent-resistant nanofiltration

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01476A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cong Yang, Fuat Topuz, Sang-Hee Park, Gyorgy Szekely
A robust and sustainable thin-film composite membrane, using green raw materials on a highly porous, electrospun and biodegradable support, was developed for molecular sieving.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.06.2022


Facile in situ construction of a covalent adaptable network polyester vitrimer with advanced performance in repairability, foamability and recyclability

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01320G, Paper
Pengzhi Li, Bin Lan, Xutao Zhang, Siyuan Lei, Qi Yang, Pengjian Gong, Chul B. Park, Guangxian Li
An environmentally friendly polyester vitrimer was prepared through an efficient one-pot method. The vitrimer possesses advanced recyclability,  foamability, creep resistance and self-healing performance.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.06.2022


Synthesis of isochromanones via laccase-mediated oxidative [4 + 2] cyclization of pyrocatechuic acid with styrenes

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01706G, Paper
Huan Guo, Jin Liu, Guojiao Wu, Weijun Yao, Fangrui Zhong
Isochromanone is the core structure of many active natural products.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.06.2022


Carbon Neutral Methanol from Pulp Mills Towards Full Energy Decarbonization: An Inside Perspective and Critical Review

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01528E, Critical Review
D.T. Pio, A.C.M Vilas-Boas, N.F.C Rodrigues, A. Mendes
This work provides a critical review on the potential of integrating green methanol production processes in pulp mills. It identifies the current challenges, available synergies and future trends, whilst considering...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.06.2022


Striding the threshold of photocatalytic lignin-first biorefining via a bottom-up approach: from model compounds to realistic lignin

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01409B, Critical Review
Jikun Xu, Pengfei Zhou, Chuntao Zhang, Lan Yuan, Xiao Xiao, Lin Dai, Kaifu Huo
This critical review delivers an in-depth description of advancements and challenges in the photocatalytic lignin-first biorefining via a bottom-up paradigm, ranging from models transformation mechanism to practical lignin tactics.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.06.2022


Spherical agglomeration of high melting point drugs in water at low temperature by developing a two-step oiling-out mechanism and the design strategy

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01498J, Paper
Yanbo Liu, Yiming Ma, Changyou Yu, Ye Gao, Kangli Li, Li Tong, Mingyang Chen, Junbo Gong
The current oiling-out spherical agglomeration technology overcomes the shortcomings of biohazardous solvents and complex equipment of traditional spherical granulation technologies in the pharmaceutical industry. However, it is difficult for high...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.06.2022


Copper and neocuproine catalysed synthesis of cinnamyl ether derivatives directly from secondary and tertiary cinnamyl alcohols

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01602H, Paper
Zhenjiao Yang, Yongsheng Zhang, Xingxian Lv, Yang Yang, Chunhao Jiang, Xiaoyan He, Guoliang Chen, Gang Huang, Xiuhong Lu
A new method for the O-alkylation of secondary and tertiary cinnamyl alcohols with primary alcohols by employing CuSO4·5H2O and neocuproine as catalysts was developed, and PEG-modified secondary and tertiary cinnamyl alcohols can be achieved directly.
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Datum: 16.06.2022


Organic waste valorisation towards circular and sustainable biocomposites

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC01668K, Critical Review
Erlantz Lizundia, Francesca Luzi, Debora Puglia
The development of circular production and consumption patterns to counteract current depletion of natural resources, global warming, and environmental pollution emergencies results one of the most pressing global challenges facing...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.06.2022


Amine-based pretreatments for lignocellulose fractionation and lignin valorization: a review

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01423H, Tutorial Review
Samuel Ntakirutimana, Tao Xu, He Liu, Jia-Qi Cui, Qiu-Jin Zong, Zhi-Hua Liu, Bing-Zhi Li, Ying-Jin Yuan
The increasing demand for sustainable bioproducts as alternatives to fossil-based resources requires unremitting endeavor for the advancement of lignocellulose valorization.
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Datum: 16.06.2022


Graphite oxide catalyzed one-pot synthesis of highly functionalized spirodibenzo[1,4]diazepine derivatives in aqueous ethanol medium

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00194B, Paper
Rajib Sarkar, Binoyargha Dam, Lenida Kyndiah, Fillip Kumar Sarkar, Sushmita Gajurel, Amarta Kumar Pal
We presented the synthesis of highly functionalized spirodibenzo[1,4]diazepine derivatives using graphite oxide (GO) as a metal-free carbocatalyst via a one-pot three-component strategy.
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Datum: 16.06.2022


Rapid synthesis of zeolites through g-C3N4-based photocatalysis

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00082B, Paper
Yang Liu, Xiao Xue, Yanshuai Wang, Fei Ye, Jian-Guo Dai, Guohua Chen
ROS-dominant fast and green synthesis of zeolites within 8 hours at room temperature has been realized for the first time by using photocatalytic induced ˙OH and ˙O2 to accelerate the Si–O (Al–O) bonds breaking and reforming.
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Datum: 16.06.2022


Iron-catalyzed ring-opening of cyclic carboxylic acids enabled by photoinduced ligand-to-metal charge transfer

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01738E, Paper
Jia-Lin Tu, Han Gao, Mengqi Luo, Lulu Zhao, Chao Yang, Lin Guo, Wujiong Xia
A decarboxylative ring-opening reaction of cyclic tertiary carboxylic acids via an iron-catalyzed photoinduced ligand-to-metal charge transfer (LMCT) process is herein reported.
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Datum: 16.06.2022


A convenient transformation of alkynes to α-hydroxy-α-CF3-γ-ketoester derivatives via H3PO4-catalyzed tandem hydration and aldol condensation

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01199A, Paper
Jiali Wang, Jun Yao, Chunqi Jia, Dandan Hu, Yun-Hua Chen, Jinyu Song, Jun-Qi Zhang, Hongjun Ren
A robust metal-free catalytic strategy for the rapid construction of the valuable α-hydroxy-α-CF3-γ-ketoester skeleton with cheap and easily available stock chemicals (alkynes and trifluoropyruvate) as the starting material is described.
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Datum: 15.06.2022


Tuning the d-band center of NiC2O4 with Nb2O5 to optimize the Volmer step for hydrazine oxidation-assisted hydrogen production

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01158A, Paper
Xiao Hui Chen, Hong Chuan Fu, Li Li Wu, Xiao Lin Li, Bo Yang, Ting Li, Fei Gu, Jing Lei Lei, Nian Bing Li, Hong Qun Luo
Nb2O5 can adjust the electronic structure of SNiC2O4 and improve the catalytic activity. Replacing the OER with the HzOR for hydrogen production can save 80% of energy consumption.
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Datum: 15.06.2022


Correction: Nano Au/Pd-catalysed ‘on-water’ synthesis of C3–C3′ diaryl-oxindole scaffolds via N2-selective dearomatization of indole

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC90048C, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shivanee Borpatra Gohain, Monika Basumatary, Purna K. Boruah, Manash R. Das, Ashim Jyoti Thakur
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Datum: 14.06.2022


Closed-loop chemical recycling of thermosetting polymers and their applications: a review

Green Chem., 2022, Accepted Manuscript
DOI: 10.1039/D2GC00368F, Critical Review
Yanlin Liu, Zhen Yu, Binbo Wang, Li Pengyun, Jin Zhu, Songqi Ma
Conventional thermosets are infusible and insoluble covalently cross-linked polymers which are difficult to be recycled and reused when discarded. Recent years witnessed development of closed-loop recycling of novel thermosets as...
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Datum: 14.06.2022


A ‘self-activating’ Bi3TaO7–Bi4TaO8Br photocatalyst and its use in the sustainable production of pro-fluorophoric rhodamine-110

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01574A, Paper
Maqsuma Banoo, Kaustav Chatterjee, Sanjit Mondal, C. P. Vinod, Ujjal K. Gautam
A rhodamine B photodegradation intermediate, a highly expensive rhodamine 110 profluorophore, has been extracted in a commercially sustainable way by developing a catalyst that improves its activity in every cycle, unlike other photocatalysts.
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Datum: 14.06.2022


Highly efficient one-pot conversion of saccharides to 2,5-dimethylfuran using P-UiO-66 and Ni–Co@NC noble metal-free catalysts

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01408D, Communication
Chi Van Nguyen, Jyun-Yi Yeh, Thuan Van Tran, Kevin C.-W. Wu
In this work, we demonstrate the one-pot conversion of saccharides to high yield (>80%) of 2,5-dimethyl furan (DMF) using a combination of two noble-metal-free catalysts (i.e., P-UiO-66 and Ni–Co@NC).
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Datum: 13.06.2022


Facile synthesis of Pd–Au/BNNS bimetallic catalysts for direct generation of H2O2 from H2 and O2 under environmentally friendly conditions

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00918H, Paper
Shahram Shaybanizadeh, Rafael Luque, Alireza Najafi Chermahini
Hydrogen peroxide (H2O2), as an important biocompatible oxidant, has many industrial applications including (bio) medical technologies, textiles, and water treatment.
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Datum: 10.06.2022


Progress in the catalytic reactions of CO2 and epoxides to selectively provide cyclic or polymeric carbonates

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01422J, Critical Review
Gulzar A. Bhat, Donald J. Darensbourg
This review of the metal- and organo-catalyzed coupling of CO2 and epoxides (oxiranes) to provide selectively cyclic or polymeric carbonates is intended to highlight recent achievements in this area of research.
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Datum: 10.06.2022


Eco-friendly and sustainable approach of assembling sugars into biobased carbon fibers

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01075E, Paper
Yu Yang, Daming Chen, Yuan Cheng, Boqian Sun, Guangdong Zhao, Weidong Fei, Wenbo Han, Jiecai Han, Xinghong Zhang
Sugars are used as precursors to manufacture carbon fibers, obviating the need for hazardous solvents. Through the synergy of sugars and the hydrogel network, the carbon yield was significantly improved and the structure was well retained.
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Datum: 09.06.2022


Venturi-based rapid expansion of supercritical solution (Vent-RESS): synthesis of liposomes for pH-triggered delivery of hydrophilic and lipophilic bioactives

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00877G, Paper
Apratim Jash, Amy Krueger, Syed S. H. Rizvi
Liposome synthesis by venturi-based rapid expansion of supercritical solution (Vent-RESS) and subsequent surface coating for simultaneous pH-triggered delivery of hydrophilic and lipophilic bioactives.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.06.2022


Morphology control of eco-friendly chitosan-derived carbon aerogels for efficient microwave absorption at thin thickness and thermal stealth

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01604D, Paper
Xinting Chen, Ming Zhou, Yue Zhao, Weihua Gu, Yue Wu, Shaolong Tang, Guangbin Ji
In the face of increasingly severe electromagnetic wave pollution, the research of biomass-based carbon materials due to the advantages of being green, renewable, environment-friendly, porous and light has become one of the most attractive topics.
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Datum: 09.06.2022


Sustainable photoredox chemistry of a transient ternary complex: an unconventional approach toward trifluoromethylated hydroquinones

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01691E, Paper
Da Seul Lee, Vineet Kumar Soni, Seunga Heo, Ho Seong Hwang, Youngmin You, Eun Jin Cho
Highly functional CF3–hydroquinones have been synthesized from benzoquinones and CF3SO2Na via a unique approach involving the formation of a transient ternary complex intermediate for facile photoinduced charge-transfer.
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Datum: 09.06.2022


Electrochemical enaminone C–H thiolation/C–N amination cascade for thiazole synthesis and its diastereoselective dearomatization

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01644C, Communication
Haijin Guo, Yunyun Liu, Chengping Wen, Jie-Ping Wan
The electrochemical annulation of enaminones/analogous enamines and thioureas providing 2-aminothiazoles has been realized. Modulating the electrolyte enables the diastereoselective synthesis of 4,5-dialkoxyl thiazolines by dearomatization.
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Datum: 09.06.2022


Synthesis of β-fluorocarboxylic esters via organophotoredox-catalyzed fluoroalkoxycarbonylation of alkenes in EtOH

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01609E, Communication
Xinhua Wang, Yi Chen, Ping Liang, Jian-Qiang Chen, Jie Wu
An efficient and environmentally friendly organophotoredox-catalyzed method for the synthesis of β-fluorocarboxylic esters is developed.
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Datum: 09.06.2022


Photoinduced synthesis of functionalized oxetanes via diradical-mediated ring contraction

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01362B, Communication
Dan Qi, Jinrui Bai, Haoxiang Zhang, Bin Li, Zhuoheng Song, Na Ma, Lin Guo, Lijuan Song, Wujiong Xia
A photochemical ring contraction is reported for the synthesis of oxetanes from dihydrofurans and diazo compounds under catalyst-free conditions.
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Datum: 08.06.2022


N-Doped holey graphene assembled on fibrous aluminum silicate for efficient carbocatalysis in fixed-bed systems

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01162J, Paper
Hanyu Hu, Shuaihu Du, Jiangbo Xi
A fixed-bed based catalytic system is ideal for a green organic synthesis process, benefitting from the advantages of easy product purification, simple operation, and convenient catalyst recycling.
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Datum: 08.06.2022


Pd doped carbon nitride (Pd-g-C3N4): an efficient photocatalyst for hydrogenation via an Al–H2O system and an electrocatalyst towards overall water splitting

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00801G, Paper
Priti Sharma, Debdyuti Mukherjee, Sujoy Sarkar, Daniel Mandler, Rajender S. Varma, Manoj B. Gawande, Radek Zbořil, Yoel Sasson
A straightforward and mild protocol for photochemical in situ selective hydrogenation is described via an Al–H2O system as a hydrogen donor and deploying a Pd-g-C3N4 photocatalyst under visible light and ambient conditions.
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Datum: 07.06.2022


Evaluating the mechanism of milk protein as an efficient lignin blocker for boosting the enzymatic hydrolysis of lignocellulosic substrates

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01160C, Paper
Caoxing Huang, Wenqian Lin, Yayue Zheng, Xiaoxue Zhao, Arthur Ragauskas, Xianzhi Meng
The residual lignin in pretreated biomass significantly hinders the bio-conversion of cellulose into monosaccharides.
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Datum: 07.06.2022


Direct conversion of isopropanol to C6+ branched compounds as high-octane gasoline blendstocks

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01200F, Communication
Wei Zhou, Zirui Gao, Meng Wang, Genghuang Wu, Junfeng Rong, Ding Ma
An efficient one-pot process is developed to convert isopropanol to C6+ compounds with ideal branched-chain selectivity in the absence of H2, showing advantage in producing sustainable liquid fuel with a high-octane number.
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Datum: 06.06.2022


Method to incorporate green chemistry principles in early-stage product design for sustainability: case studies with personal care products

Green Chem., 2022, 24,4969-4980
DOI: 10.1039/D2GC00842D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Jennifer K. Saxe, Lisa Hoffman, Ramez Labib
Applying green chemistry principles while combining ecological risk assessment and life cycle assessment approaches facilitates sustainable design for down-the-drain consumer products.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Systematic QSAR and iQCCR modelling of fused/non-fused aromatic hydrocarbons (FNFAHs) carcinogenicity to rodents: reducing unnecessary chemical synthesis and animal testing

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00986B, Paper
Feifan Li, Tengjiao Fan, Guohui Sun, Lijiao Zhao, Rugang Zhong, Yongzhen Peng
The prediction of new or untested FNFAHs will reduce unnecessary chemical synthesis and animal testing, and contribute to the design of safer chemicals for production activities.
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Datum: 02.06.2022


Mechanistic insights into the effect of the feed concentration on product formation during acid-catalyzed conversion of glucose in ethanol

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00300G, Paper
Lincai Peng, Chaonan Tao, Hui Yang, Junhua Zhang, Huai Liu
Increasing the glucose concentration from 20 to 200 g L−1 largely boosted the formation of WSO instead of SHU, thus downgrading the yield of EL.
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Datum: 02.06.2022


Visible-light-induced Smiles rearrangement without release of SO2: rapid access to alkyl sulfonyl derivatives

Green Chem., 2022, 24,4789-4793
DOI: 10.1039/D2GC01509A, Communication
Yunpeng Cao, Xinmou Wang, Haoran Jiao, Hongjian Song, Yuxiu Liu, Qingmin Wang
Conventional visible-light-induced Smiles rearrangements generate C, N, or O radicals and release SO2.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2022


Correction: Facile synthesis and isolation of 5-hydroxymethylfurfural from diphenyl sulfoxide

Green Chem., 2022, 24,4991-4991
DOI: 10.1039/D2GC90042D, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tongtong Zhang, Yaoping Hu, Liyuan Huai, Zhijin Gao, Jian Zhang
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2022


Catalyst- and oxidant-free electrooxidative site-selective [3/4 + 2] annulation to fused polycyclic heteroaromatics

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01248K, Paper
Wenjing Guan, Ke Ying, Chengcheng Yuan, Jinlin Hang, Chengkou Liu, Xiangxing Huang, Zheng Fang, Kai Guo
A catalyst- and oxidant-free electrooxidative site-selective [3/4 + 2] annulation through π-extension to fused polycyclic heteroaromatics has been developed.
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Datum: 01.06.2022


Integration of lignin microcapsulated pesticide production into lignocellulose biorefineries through FeCl3-mediated deep eutectic solvent pretreatment

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01255C, Paper
Feiyue Shen, Shiyu Wu, Mei Huang, Li Zhao, Jinsong He, Yanzong Zhang, Shihuai Deng, Jinguang Hu, Dong Tian, Fei Shen
Schematic diagram of integrating lignin-based microcapsulated pesticide production into a lignocellulose biorefinery is presented.
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Datum: 01.06.2022


Near quantitative conversion of xylose into bisfuran

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00640E, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rui Zhang, Aleksi Eronen, Petra Vasko, Xiangze Du, Joseph Install, Timo Repo
Xylose is converted to a new type of bisfuranic compound in nearly quantitative yield with acetylacetone, through a Zr-catalysed Garcia Gonzalez reaction-based strategy by losing five molecules of water.
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Datum: 31.05.2022


Visible-light-driven multicomponent reactions to access S-alkyl phosphorothioates using elemental sulfur as the sulfur source

Green Chem., 2022, 24,4915-4920
DOI: 10.1039/D2GC00903J, Paper
Chengming Qu, Ruisheng Liu, Zhiwei Wang, Yufen Lv, Huilan Yue, Wei Wei
A convenient and eco-friendly visible-light promoted multicomponent protocol has been developed for the synthesis of S-alkyl phosphorothioates by using elemental sulfur as the cheap and odorless sulfur source.
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Datum: 31.05.2022


Efficient Bi-enzymatic synthesis of aldonic acids

Green Chem., 2022, 24,4902-4908
DOI: 10.1039/D2GC00823H, Paper
Lidija Tetianec, Irina Bratkovskaja, Vida Časaitė, Vidutė Gurevičienė, Julija Razumienė, Jonita Stankevičiūtė, Rolandas Meškys, Marius Dagys, Audrius Laurynėnas
Aldonic acids have already found many applications in food, pharmaceutical, and cosmetics industries and there are many new ones likely to come.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2022


A second life for fruit and vegetable waste: a review on bioplastic films and coatings for potential food protection applications

Green Chem., 2022, 24,4703-4727
DOI: 10.1039/D1GC03904K, Tutorial Review
Danila Merino, Ana Isabel Quilez-Molina, Giovanni Perotto, Andrea Bassani, Giorgia Spigno, Athanassia Athanassiou
Circular economy approach for various agrowaste-based bioplastic and biocomposite systems with potential applications in the protection of food products and extension of their shelf life.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.05.2022


Singlet oxygen-promoted one-pot synthesis of highly ordered mesoporous silica materials via the radical route

Green Chem., 2022, 24,4778-4782
DOI: 10.1039/D2GC00869F, Communication
Tingting Lu, Wenfu Yan, Guodong Feng, Xiaolin Luo, Yueqiao Hu, Jiale Guo, Zhan Yu, Zhen Zhao, Shujiang Ding
Compared with ˙OH in an acid-free synthesis system, 1O2 plays a more important role in the hydrolysis of TEOS to meet the targeted assembly rate for templates, which is crucial for the one-pot synthesis of mesoporous silica materials.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.05.2022


Mobilization of platinum and palladium from exhausted catalytic converters using bio-cyanide and an ionic-liquid as mass transport carriers

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00874B, Paper
Sadia Ilyas, Rajiv Ranjan Srivastava, Hyunjung Kim
An approach to precious metals’ reclamation from exhausted catalytic converters using an integrative bio-solvo-chemical strategy is demonstrated.
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Datum: 26.05.2022


A jackpot C–H activation protocol using simple ruthenium catalyst in deep eutectic solvents

Green Chem., 2022, 24,4941-4951
DOI: 10.1039/D2GC01177H, Paper
Nerea González-Gallardo, Beatriz Saavedra, Gabriela Guillena, Diego J. Ramón
Deep eutectic solvents (DESs) have been used for the first time as a sustainable medium in a ruthenium-catalyzed C–H activation reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.05.2022


Electrochemical oxidation of phenols in flow: a versatile and scalable access to para-benzoquinones

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC01296K, Paper
Fiona Sprang, John D. Herszman, Siegfried R. Waldvogel
An electrochemical flow protocol for the continuous synthesis of para-benzoquinones from abundant phenols is reported.
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Datum: 26.05.2022


One-pot chemoenzymatic synthesis of glycolic acid from formaldehyde

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00688J, Communication
Tianzhen Li, Zijian Tan, Zijing Tang, Pi Liu, Haifeng Liu, Leilei Zhu, Yanhe Ma
Enzymatic carboligation coupled with selective oxidation converts formaldehyde to glycolic acid, a monomer of biodegradable polymers.
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Datum: 26.05.2022


A solar tracker integrated microreactor for real-time sunlight induced ketene formation and API synthesis

Green Chem., 2022, 24,4794-4799
DOI: 10.1039/D2GC00649A, Communication
Abhilash Rana, Bhanwar Kumar Malviya, Deepak Kumar Jaiswal, P. Srihari, Ajay K. Singh
Catalyst free, newly fabricated solar panel reactor for the fluctuating light condition, 20 new entry, gram scale synthesis, safe and green process, sun-light is energy source.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.05.2022


Desymmetric hydrolysis of prochiral imide for S-pregabalin synthesis by rationally designed D-hydantoinase

Green Chem., 2022, 24,4748-4753
DOI: 10.1039/D2GC00728B, Communication
Feixia Liu, Jie Ren, Lu Guo, Yang Liu, De-Feng Li, Bo Yu
A one-step enzymatic desymmetrization process was developed to produce the direct chiral precursor for S-pregabalin synthesis with high yield and high eep value.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.05.2022


Electrochemical radical–radical cross-coupling: direct access to β-amino nitriles from unactivated imines and alkyl nitriles

Green Chem., 2022, 24,4928-4934
DOI: 10.1039/D2GC00457G, Paper
Wei-Mei Zeng, Zhi-Lv Wang, Yan-Hong He, Zhi Guan
The direct access to β-amino nitriles from unactivated imines and alkyl nitriles by electrochemical radical–radical cross-coupling was described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.05.2022


Catalytic conversion of high S-lignin to a sustainable tri-epoxide polymer precursor

Green Chem., 2022, 24,4958-4968
DOI: 10.1039/D2GC01278B, Paper
Baoyuan Liu, Melissa Sanchez, Julianne Truong, Peter C. Ford, Mahdi M. Abu-Omar
More than 40 million tons of thermosetting plastics are produced annually and 70% of those are epoxy polymers. Propylpyrogallol made from genetically modified high-S lignin provides a pathway for making renewable thermoset plastics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.05.2022


Electrochemical triamination of alkynes: controllable synthesis of functionalized indolines and indoles

Green Chem., 2022, 24,4754-4760
DOI: 10.1039/D2GC01129H, Communication
Xiangtai Meng, Hehua Xu, Rui Liu, Yu Zheng, Shenlin Huang
The electrochemical triamination of alkynes has been developed, affording a variety of 2,3-diimino indolines and 2,3-diamino indoles.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.05.2022


Rose bengal photocatalyzed Knoevenagel condensation of aldehydes and ketones in aqueous medium

Green Chem., 2022, 24,4952-4957
DOI: 10.1039/D2GC01402E, Paper
Anupam Das, K. R. Justin Thomas
Organic photocatalytic knoevenagel condensation: Rose bengal photosensitized Knoevenagel condensation protocol for both aldehyde and ketones are described in aqueous medium.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2022


A wholly biological method for galactaric acid production from pectin by the combination of enzymatic hydrolysis and resting-cell catalysis

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00821A, Paper
Xia Hua, ChenHui Zhang, Jian Han, Yong Xu
An eco-friendly wholly biological method for galactaric acid preparation from pectin with three steps including enzymolysis, purification and catalysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2022


Water enabled, nickel-catalyzed highly chemoselective C-allylation of (NH)-indoles employing alcohols

Green Chem., 2022, 24,4921-4927
DOI: 10.1039/D2GC00921H, Paper
Gargi Nikhil Vaidya, Shyam Kumar Lokhande, Sangita Dattatray Shinde, Dinesh Parshuram Satpute, Garvita Narang, Dinesh Kumar
The ‘in-water’ nickel-catalyzed chemoselective C3-allylation of (NH)-indoles employing allylic alcohols under mild conditions is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2022


Biocatalytic CO2 fixation initiates selective oxidative cracking of 1-naphthol under ambient conditions

Green Chem., 2022, 24,4766-4771
DOI: 10.1039/D2GC01226J, Communication
Pengju Ren, Zijian Tan, Yingying Zhou, Hongzhi Tang, Ping Xu, Haifeng Liu, Leilei Zhu
CO2 fixation initiates cracking: the enzymatic ortho-carboxylation activates the singly hydroxylated aromatic ring of naphthalene for the following selective cracking catalyzed by dioxygenase in a cofactor-free one-pot cascade reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2022


Allylations of aryl/heteroaryl ketones: neat, clean, and sustainable. Applications to targets in the pharma- and nutraceutical industries

Green Chem., 2022, 24,4909-4914
DOI: 10.1039/D2GC00776B, Paper
Xiaohan Li, Alex B. Wood, Nicholas R. Lee, Fabrice Gallou, Bruce H. Lipshutz
Aromatic and heteroaromatic ketones bearing an α-methine proton can be deprotonated and mono-allylated in minutes in the complete absence of an organic solvent to arrive at the corresponding products in high isolated yields.
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Datum: 23.05.2022


Hydrogen bond mediated conversion of benzenenitriles and arylacetonitriles to amides: an “on/in-water” reaction strategy

Green Chem., 2022, 24,4981-4990
DOI: 10.1039/D2GC01341J, Paper
Shubhranshu Shekhar Choudhury, Shivam Mahapatra, Himansu S. Biswal
H-bond mediated catalysis by choline hydroxide (ChOH): reduction in activation energy via H-bonding makes ChOH one of the most efficient sustainable catalysts compared to other reported catalysts such as H2SO4 or Ru(OH)x/Al2O3.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2022


Separation of nickel from cobalt and manganese in lithium ion batteries using deep eutectic solvents

Green Chem., 2022, 24,4877-4886
DOI: 10.1039/D2GC00606E, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dana L. Thompson, Ioanna M. Pateli, Chunhong Lei, Abbey Jarvis, Andrew P. Abbott, Jennifer M. Hartley
Cobalt and manganese were selectively leached from LiNMC using an oxalic acid : choline chloride deep eutectic solvent, resulting in a nickel-enriched solid residue.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2022


Scalable selective electrochemical oxidation of sulfides to sulfoxides

Green Chem., 2022, 24,4772-4777
DOI: 10.1039/D1GC04832E, Communication
Zi-Hao Fu, Hao-Dong Tian, Shao-Fei Ni, James S. Wright, Ming Li, Li-Rong Wen, Lin-Bao Zhang
An electrochemical protocol for the selective oxidation of sulfides to sulfoxides has been developed in which NaCl plays a dual role: (1) as an electrolyte for the electrochemical transformations and (2) as a redox mediator to avoid oxidation of sensitive functional groups.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.05.2022


Electrochemical cascade synthesis of α-thio-substituted masked aldehydes

Green Chem., 2022, 24,4783-4788
DOI: 10.1039/D2GC00845A, Communication
Deepak Sharma, Yaseen Hussain, Manisha Sharma, Pankaj Chauhan
An unprecedented 3-component cascade synthesis of β,β-dialkoxy sulfides under mild electrochemical conditions has been achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.05.2022


Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines

Green Chem., 2022, 24,4742-4747
DOI: 10.1039/D2GC01276F, Communication
Shiliu Chen, Qinqin Yan, Jie Fan, Yongjun Gao, Xiulong Yang, Lijun Li, Zhongquan Liu, Zejiang Li
Photoinduced tandem cyclization of alkynes with NH4SCN was developed for the synthesis of various SCN-containing seven-membered N-heterocycles.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.05.2022


Organic redox polymers as electrochemical energy materials

Green Chem., 2022, 24,4650-4679
DOI: 10.1039/D2GC00981A, Critical Review
Hiroyuki Nishide
The review provides basic insight into organic redox polymers: efficient charge propagation and storage among the highly populated redox active/bistable sites, as well as their functions in environmentally-friendly applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.05.2022


Highly selective one-pot production of 2,5-furandimethanol from saccharides

Green Chem., 2022, 24,4935-4940
DOI: 10.1039/D2GC00500J, Paper
Ling Xu, Xilei Lyu, Yuxi Jiang, Xiwen Wei, Renfeng Nie, Xiuyang Lu
A cascade catalytic system (NiCl2/FA/Co-NC) can fulfil the one-pot production of FDM from glucose and di/polysaccharides without the separation of unstable intermediates under mild conditions, showing great potential for the industrial applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.05.2022


Supramolecular deep eutectic solvents and their applications

Green Chem., 2022, Advance Article
DOI: 10.1039/D2GC00906D, Tutorial Review
Patrycja Janicka, Massoud Kaykhaii, Justyna Płotka-Wasylka, Jacek Gębicki
Supramolecular Deep Eutectic Solvent (SUPRADES) – another milestone towards Green Chemistry.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.05.2022


Synthesis of two-dimensional ultrathin photocatalytic materials towards a more sustainable environment

Green Chem., 2022, 24,4728-4741
DOI: 10.1039/D2GC00608A, Tutorial Review
Chengxiao Zhao, Chenhui Han, Xiaofei Yang, Jingsan Xu
The latest progress in 2D ultrathin nanomaterials used for photocatalysis has been summarized from a sustainable synthesis perspective. Various synthetic strategies and approaches have been discussed and compared.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.05.2022


In situ Fmoc removal – a sustainable solid-phase peptide synthesis approach

Green Chem., 2022, 24,4887-4896
DOI: 10.1039/D2GC00963C, Paper
Ashish Kumar, Anamika Sharma, Beatriz G. de la Torre, Fernando Albericio
In-situ Fmoc removal leading to sustainable Solid Phase Peptide Synthesis (SPPS).
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.05.2022


Accelerated synthesis of dendrimers by thermal azide–alkyne cycloaddition with internal alkynes

Green Chem., 2022, 24,4897-4901
DOI: 10.1039/D2GC00473A, Paper
Sandra P. Amaral, Juan Correa, Eduardo Fernandez-Megia
Optimized reaction conditions and a strict alignment to green chemistry principles allow the accelerated preparation of a G5 dendrimer in less than 12 h by combining the thermal azide–alkyne cycloaddition and azide substitution reactions.
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Datum: 13.05.2022


Techno-economic performances and life cycle greenhouse gas emissions of various ammonia production pathways including conventional, carbon-capturing, nuclear-powered, and renewable production

Green Chem., 2022, 24,4830-4844
DOI: 10.1039/D2GC00843B, Paper
Kyuha Lee, Xinyu Liu, Pradeep Vyawahare, Pingping Sun, Amgad Elgowainy, Michael Wang
The techno-economic performances and life cycle greenhouse gas emissions of conventional NG-based, carbon-capturing, and nuclear-powered or renewable ammonia production are evaluated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.05.2022


Oxidative cleavage of polysaccharides by a termite-derived superoxide dismutase boosts the degradation of biomass by glycoside hydrolases

Green Chem., 2022, 24,4845-4858
DOI: 10.1039/D1GC04519A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
João Paulo L. Franco Cairo, Fernanda Mandelli, Robson Tramontina, David Cannella, Alessandro Paradisi, Luisa Ciano, Marcel R. Ferreira, Marcelo V. Liberato, Lívia B. Brenelli, Thiago A. Gonçalves, Gisele N. Rodrigues, Thabata M. Alvarez, Luciana S. Mofatto, Marcelo F. Carazzolle, José G. C. Pradella, Adriana F. Paes Leme, Ana M. Costa-Leonardo, Mário Oliveira-Neto, André Damasio, Gideon J. Davies, Claus Felby, Paul H. Walton, Fabio M. Squina
A Cu/Zn superoxide dismutase isolated from termite gut can oxidise glucose polymers, boosting the activity of glycoside hydrolases.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.05.2022


Mechanochemical Fischer indolisation: an eco-friendly design for a timeless reaction

Green Chem., 2022, 24,4859-4869
DOI: 10.1039/D2GC00724J, Paper
Andrea Porcheddu, Rita Mocci, Margherita Brindisi, Federico Cuccu, Claudia Fattuoni, Francesco Delogu, Evelina Colacino, Maria Valeria D'Auria
We developed an environmentally friendly mechanochemical protocol to induce an effective Fischer indolisation to synthesize indoles and indolines taking advantage of oxalic acid and dimethylurea.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.05.2022


Nitrogen-doped nickel-molybdenum oxide as a highly efficient electrocatalyst for benzyl alcohol oxidation

Green Chem., 2022, 24,4870-4876
DOI: 10.1039/D2GC00989G, Paper
Jiang Wan, Xiao Mu, Yu Jin, Jiukang Zhu, Yucong Xiong, Tianyu Li, Rong Li
Replacing the sluggish oxygen evolution reaction (OER) with electrocatalytic alcohol oxidation to construct hybrid water electrolysis systems is more economically attractive than conventional water splitting.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.05.2022


Pyrolytic lignin: a promising biorefinery feedstock for the production of fuels and valuable chemicals

Green Chem., 2022, 24,4680-4702
DOI: 10.1039/D2GC00302C, Tutorial Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. B. Figueirêdo, I. Hita, P. J. Deuss, R. H. Venderbosch, H. J. Heeres
Pyrolysis oil from lignocellulosic biomass can be fractionated into a lignin and sugar fraction. We here provide a review on the structure, properties, depolymerisation strategies and applications for pyrolytic lignin in the framework of a biorefinery.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.05.2022


A highly efficient and stable solar energy-driven device using lignocellulosic biomass Juncus effusus for the recovery of ethanol–water mixture

Green Chem., 2022, 24,4812-4823
DOI: 10.1039/D2GC00509C, Paper
Zhuan Fu, Sijie Zhou, Liangjun Xia, Chunhua Zhang, Na Zhu, Junyao Gong, Xiaofeng Wang, Xin Liu, Li Li, Weilin Xu
A highly efficient and stable solar energy-driven device was fabricated using lignocellulosic biomass Juncus effusus for the recovery of ethanol–water mixture.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.05.2022


Ultrasonic-assisted oxidation of cellulose to oxalic acid over gold nanoparticles supported on iron-oxide

Green Chem., 2022, 24,4800-4811
DOI: 10.1039/D2GC00433J, Paper
Prince Nana Amaniampong, Quang Thang Trinh, Teseer Bahry, Jia Zhang, François Jérôme
We demonstrate a catalytic base-free strategy for the selective oxidation of microcrystalline cellulose to oxalic acid (OA) by combining low frequency ultrasound as an unconventional activation technique and Au/Fe2O3 as a catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.04.2022


Significantly improved radiochemical yields in gaseous tritium reactions by iridium(I)-catalyzed hydrogen isotope exchange

Green Chem., 2022, 24,4824-4829
DOI: 10.1039/D2GC00534D, Paper
Patrick Morawietz, Remo Weck, Andrew A. Scholte, Jens Atzrodt, Stefan Güssregen, Volker Derdau
Hydrogen isotope exchange reactions with iridium(I) catalyst [(COD)Ir(IMes)(PPh3)]X 2 with significantly increased (up to 7 fold) radiochemical yields (RCY) in tritium gas reactions are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.04.2022


Alumina-mediated soft propargylic C–H activation in unactivated alkynes

Green Chem., 2022, 24,4761-4765
DOI: 10.1039/D2GC00555G, Communication
Mikhail Feofanov, Dmitry I. Sharapa, Vladimir Akhmetov
Pre-treated γ-alumina features reactive centers mimicking electronic interactions of propargyls with transition-metal-based catalysts. The combination of soft π-Lewis acidity and Brønsted basicity allows C-H propargyl activation under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.03.2022


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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