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Green Chemistry

Current research reports and chronological list of recent articles..




The international scientific journal Green Chemistry publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research and policy relating to the endeavour are welcome.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles see Current Chemistry Research Articles. Magazines with similar content (sustainable and green chemistry):

 - ChemSusChem.

 - Environmental Chemistry.

 - Green Chemistry Letters and Reviews.



Green Chemistry - Abstracts



A sustainable chemical process to recycle end-of-life silicon solar cells

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02263F, Paper
Rong Deng, Pablo Ribeiro Dias, Marina Monteiro Lunardi, Jingjia Ji
We developed a sustainable process for a fast, efficient, and environmentally friendly recovery of high purity silver and silicon from waste solar cells.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


A Review on Sustainable Synthetic Approaches of Photoluminescent Quantum Dots

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC02964A, Tutorial Review
Weiqiang Yang, Xinghua Li, Liling Fei, Weizhen Liu, Xiuling Liu, Haiyang Xu, Yichun Liu
Photoluminescent quantum dots (QDs) with unique structures and excellent optical attributes have received much interest owing to their extensive applications. In this review, various classes of QDs with different compositions...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Electrocatalytic hydrogenation of lignin monomer to methoxy-cyclohexanes with a high faradaic efficiency

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03523A, Communication
Miao Wang, Tao Peng, Chenxin Yang, Baiyao Liang, Henan Chen , Mohan Kumar, Yun Zhang, Wei Zhao
Developing efficient renewable electrocatalytic processes for chemical manufacture is of commercial interest, especially from the biomass-derived feedstock. Selective electrocatalytic hydrogenation (ECH) of biomass-derived lignin monomers to high-value oxygen-functional compounds is...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Recent advances in polymer membranes employing non-toxic solvents and materials

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03318B, Tutorial Review
Dong Zou, Suzana P. Nunes, Ivo F. J. Vankelecom, Alberto Figoli, Young Moo Lee
Critical review for the recent developments of polymer membranes using non-toxic solvents and materials based on the green chemistry principle.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Catalytic upcycling of PVC waste-derived phthalate esters into safe, hydrogenated plasticizers

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03864H, Paper
Simon Windels, Thomas Diefenhardt, Noopur Jain, Carlos Marquez, Sara Bals, Martin Schlummer, Dirk E. De Vos
Recycling of end-of-life polyvinyl chloride (PVC) calls for solutions to deal with the vast amounts of harmful phthalate plasticizers that have historically been incorporated in PVC. Here, we report on...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


One-pot ethanol production under optimized pretreatment conditions using agave bagasse at high solids loading with low-cost biocompatible protic ionic liquid

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03774A, Paper
Jose A. Perez-Pimienta, Gabriella Papa, Jian Sun, Vitalie Stavila, Arturo Sanchez, John Gladden, Blake Simmons
Agave bagasse (AG) is used as potential bioenergy feedstock due to its high biomass productivity, even in semiarid lands. In particular, Ionic liquid (IL) pretreatment using aprotic ILs (AILs) has...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


ORGANOPHOSPHORUS CHEMICAL SECURITY FROM A PEACEFUL PERSPECTIVE: SUSTAINABLE PRACTICES IN SYNTHESIS, DECONTAMINATION AND DETECTION

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC02705K, Critical Review
Valmir B Silva, Yane Santos, Renata Hellinger, Sergui Mansour, Antonin Delaune, Julien LEGROS, Sergey Zinoviev, Evandro Nogueira, Elisa S Orth
Organophosphorus compounds play an important role in the modern chemical industry and have a broad range of applications as flame retardants, agrochemicals and chemical warfare. Unfortunately, they still present a...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Correction: Flow-through solvolysis enables production of native-like lignin from biomass

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC90119B, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David G. Brandner, Jacob S. Kruger, Nicholas E. Thornburg, Gregory G. Facas, Jacob K. Kenny, Reagan J. Dreiling, Ana Rita C. Morais, Tom Renders, Nicholas S. Cleveland, Renee M. Happs, Rui Katahira, Todd B. Vinzant, Daniel G. Wilcox, Yuriy Román-Leshkov, Gregg T. Beckham
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Synthesis of 1-azido-3-heteroaryl bicyclo[1.1.1]pentanes via azidoheteroarylation of [1.1.1]propellane

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03126K, Paper
Hang Han, Bingbin Zhu, Xiaofan Du, Yu Zhu, Chuanming Yu, Xinpeng Jiang
A novel synthesis of 1-azido-3-heteroaryl bicyclo[1.1.1]pentanes has been achieved via azidoheteroarylation of [1.1.1]propellane under mild and metal-free conditions. It provides a highly efficient route to construct azide-containing BCPs.
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Datum: 30.11.2021


An electrochemical method for deborylative selenylation of arylboronic acids under metal- and oxidant-free conditions

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC02962B, Communication
Zhengjiang Fu, Jian Yin, Dongdong He, Xuezheng Yi, Sheng Mei Guo, Hu Cai
An efficient protocol to synthesize aryl selenoethers through deborylative selenylation of widely available arylboronic acids has been established under electrochemical conditions in the absence of metal catalyst and external oxidant....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Design strategies of phosphorus-containing catalysts for photocatalytic, photoelectrochemical and electrocatalytic water splitting

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03768D, Perspective
Lei Chen, Jin-Tao Ren, Zhong-Yong Yuan
Photocatalytic, photoelectrochemical and electrocatalytic water splitting provides advanced approaches to produce green hydrogen as sustainable and renewable energy carrier. The development of highly efficient catalysts is the key to achieve...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Production of levulinic acid and alkyl levulinates: A process insight

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC02457D, Critical Review
Daniele Di menno Di Bucchianico, Yanjun Wang, Jean-Christophe Buvat, Yong Pan, Valeria Casson Moreno, Sebastien Leveneur
The use of lignocellulosic biomass in the chemical industry has increased due to its non-competition with the alimentary sector. Several platform molecules can be produced from this biomass. Among them,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Life cycle assessment of multistep benzoxazoles synthesis: from batch to waste-minimised continuous flow systems

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03202J, Paper
Jose Luis Osorio Osorio Tejada, Francesco Ferlin, Luigi Vaccaro, Volker Hessel
In this contribution we have focused on the progress of synthetic methods for the preparation of 2-aryl benzoxazoles as widely interesting materials with increasing relevance in pharmaceutical industry as well...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Combining acid-based deep eutectic solvents and microwave irradiation for improved chestnut shell waste valorization

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03450B, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
José González-Rivera, Angelica Mero, Elena Husanu, Andrea Mezzetta, Carlo Ferrari, Felicia D'Andrea, Emilia Bramanti, Christian S. Pomelli, Lorenzo Guazzelli
Key features of the deep eutectic solvent-microwave assisted simultaneous extraction of polyphenols and delignification pretreatment of chestnut shell waste are presented.
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Datum: 26.11.2021


Manganese oxide as an alternative to vanadium-based catalysts for effective conversion of glucose to formic acid in water

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03637H, Paper
Jialu Li, Richard Lee Smith Jr., Siyu Xu, De Li, Jirui Yang, Keqiang Zhang, Feng Shen
MnOx catalysts were synthesized under hydrothermal conditions for converting glucose to formic acid (FA) in water with the objective to develop vanadium-free reaction systems. An FA yield of 81.1% was...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.11.2021


Free-standing Lamellar 3D Architectures Assembled from Chitosan as Reusable Titanium-immobilized Affinity Membrane for Efficiently Capturing Phosphopeptides

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03290A, Paper
Lei Pan, Shujuan Ma, Ruizhi Tang, Wenrui Wu, Junjie Ou, Cong Li, Yehua Shen
Protein phosphorylation is involved in many biological processes and associated with some diseases. However, because of the low abundance and large dynamic changes of phosphopeptides in biological samples, it is...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.11.2021


A CO2-mediated base catalysis approach for the hydration of triple bonds in ionic liquids

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03865F, Communication
Minhao Tang, Fengtao Zhang, Yanfei Zhao, Yuepeng Wang, Zhengang Ke, Ruipeng Li, Wei Zeng, Buxing Han, Zhimin Liu
CO2 mediates ILs to serve as base catalysts for the activation of triple bonds, which achieves hydration of nitriles and CC containing compounds to carbonyl compounds under metal-free conditions.
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Datum: 24.11.2021


Methanol as C1 Source: Redox Coupling of Nitrobenzenes and Alcohols for the Synthesis of Benzimidazoles

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03907E, Communication
Hengzhao Li, Yuntong Zhang, Zihan Yan, Zemin Lai, Ruoyan Yang, Mengqi Peng, Yanhao Sun, Jie An
We present an operationally simple redox coupling for the synthesis of N-1 substituted benzimidazole using feedstock building block 2-nitroaniline derivatives as the precursors and methanol as the C1 source. Higher...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.11.2021


Lignin monomer conversion into biolubricant base oils

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03350F, Paper
Elvis Osamudiamhen Ebikade, Sunitha Sadula, Sibao Liu, Dionisios G. Vlachos
Branched benzene lubricant and branched cyclic lubricant base oils were synthesized from lignin-derived monomers and aldehyde by hydroxyalkylation/alkylation and hydrodeoxygenation in high yields.
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Datum: 23.11.2021


In situ synthesis of pyridinium-based ionic porous organic polymers with hydroxide anions and pyridinyl radicals for halogen-free catalytic fixation of atmospheric CO2

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03465K, Communication
Ke Liu, Zixuan Xu, He Huang, Yadong Zhang, Yan Liu, Zhiheng Qiu, Minman Tong, Zhouyang Long, Guojian Chen
Pyridinium-based ionic porous organic polymers (Py-iPOPs) were constructed from newly-designed acetonitrile-functionalized ionic liquids and multi-carbaldehyde monomers by the base-catalyzed Knoevenagel condensation. The obtained Py-iPOPs having in situ formed hydroxide anions...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.11.2021


Bio-based photo-reversible self-healing polymer designed from lignin

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02957F, Paper
Pallabi Sinha Roy, Matthieu M. Mention, Matthew A. P. Turner, Fanny Brunissen, Vasilios G. Stavros, Gil Garnier, Florent Allais, Kei Saito
Through structure–activity relationship study and density functional theory, this research designs novel lignin-based photo-responsive crosslinkable polymer with engineerable self-healing properties by utilizing a green photo-polymerization method.
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Datum: 22.11.2021


Ionic liquids or eutectic solvents? Identifying the best solvents for the extraction of astaxanthin and β-carotene from Phaffia rhodozyma yeast and preparation of biodegradable films

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03521E, Communication
Cassamo Mussagy, Valéria Ebinuma-Santos, Rondinelli Herculano, Joao A. P. Coutinho, Jorge F B Pereira, Adalberto Pessoa Jr
In order to replace conventional organic solvents by more benign equivalents such as ionic liquids or eutetic solvents, in this work we attempt to develop a simple and ecofriendly process...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.11.2021


Debondable adhesives and their use in recycling

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03306A, Critical Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kira R Mulcahy, Alexander F. R. Kilpatrick, Gavin Harper, Allan Walton, Andrew P Abbott
Structural adhesives are commonly used to join dissimilar materials and are of particular interest in complex technological devices used in automotive, telecommunications, photonic devices, aerospace and sustainable power production and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.11.2021


Z-Scheme nanocomposite with high redox ability for efficient cleavage of lignin C–C bonds under simulated solar light

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03455C, Paper
Xuejiao Wu, Jinchi Lin, Huizhen Zhang, Shunji Xie, Qinghong Zhang, Bert F. Sels, Ye Wang
Ag3PO4–PCN nanocomposite effectively cleaves C–C bonds of β-1 lignin models under simulated solar light mainly through an electron–hole coupled mechanism. The strong redox capability of the Z-scheme photocatalyst is the key to high efficiency.
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Datum: 22.11.2021


Porous Thienyl Cyclodextrin Polymer Synthesized in Homogeneous Ionic Liquid Catalyst System for Rapid Removal of Pharmaceuticals and Personal Care Products (PPCPs)

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03141D, Paper
Yizhou Tu, Huimin Wang, Pingping Yang, Guizhou Xu, Xuejiao Hu, Aimin Li, Xianchuan Xie
Pharmaceuticals and personal care products (PPCPs) are widely distributed in aquatic environments due to their large consumption and low biodegradability, causing ecological risks. In this study, porous thienyl cyclodextrin polymer...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.11.2021


Glyoxylate Carboligase-based Whole-Cell Biotransformation of Formaldehyde into Ethylene Glycol via Glycolaldehyde

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03549E, Paper
Hye-Jin Jo, Jun-Hong Kim, Ye-Na Kim, Pil-Won Seo, Chae-Yun Kim, Ji-Won Kim, Han-na Yu, Huijin Cheon, Eun Yeol Lee, Jeong-Sun Kim, Jin-Byung Park
A novel biocatalytic system for the synthesis of the industrially relevant C2 chemicals (e.g., ethylene glycol (3)) from formaldehyde (1) was established. The biocatalytic system consisted of a newly discovered...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.11.2021


A carbon dioxide-promoted three-component Strecker reaction

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03161A, Paper
Ruslan V. Fauziev, Roman E. Ivanov, Ilya V. Kuchurov, Sergei G. Zlotin
A three-component Strecker reaction of aldehydes, amines and KCN has been performed for the first time in supercritical carbon dioxide which acts both as an environmentally benign reaction medium and as a reaction promoter.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.11.2021


Ultra-refining for the production of long-term highly pH-stable lignin nanoparticles in high yield with high uniformity

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC03525H, Paper
Braz de Souza Marotti, Valdeir Arantes
In a bioeconomy, the valorization of lignin beyond its use to generate energy in renewable biomass-based industries is highly attractive and economically critical. However, most of its proposed applications are...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.11.2021


Biogenic colourants in the textile industry – a promising and sustainable alternative to synthetic dyes

Green Chem., 2021, Accepted Manuscript
DOI: 10.1039/D1GC02968A, Critical Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Richard Fried, Ilinca Oprea, Karin Fleck, Florian Rudroff
The textile and dyeing industry have shown dramatic growth alongside synthetic chemistry in the last century. With operations and economic importance, challenges also increase, including environmental pollution, work safety, and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.11.2021


Combined ionic liquid and supercritical carbon dioxide based dynamic extraction of six cannabinoids from Cannabis sativa L.

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03516A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Christoph Kornpointner, Aitor Sainz Martinez, Michael Schnürch, Heidi Halbwirth, Katharina Bica-Schröder
A newly developed ionic liquid (IL) based supercritical CO2 extraction technique allows the solvent-free acquisition of cannabinoids from industrial hemp.
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Datum: 18.11.2021


Chrome-free tanning agent based on epoxy-modified dialdehyde starch towards sustainable leather making

Green Chem., 2021, 23,9693-9703
DOI: 10.1039/D1GC03472C, Paper
Dongyu Hao, Xuechuan Wang, Xinhua Liu, Rongrong Su, Zhengjun Duan, Xugang Dang
As a biomass tanning agent, epoxy-modified dialdehyde starch can significantly improve the comprehensive properties of finished leather, and is expected to be a novel sustainable chrome-free tanning agent replace traditional tanning agent.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.11.2021


Enabled cellulose nanopaper with outstanding water stability and wet strength via activated residual lignin as a reinforcement

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03906G, Paper
Jinlong Wang, Wei Chen, Tengteng Dong, Haiqi Wang, Shurun Si, Xusheng Li
A RL-CNP with excellent wet strength and water stability was developed by using activated residual lignin as a reinforcement.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.11.2021


An ATP–Cu(II) catalyst efficiently catalyzes enantioselective Michael reactions in water

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03259C, Communication
Xingchen Dong, Zijian Yuan, Yao Qu, Yuxin Gao, Xue Pei, Qianqian Qi, Yujuan Pei, Jiaqi Li, Yashao Chen, Changhao Wang
A biocompatible, cheap and practical biohybrid catalyst was designed using ATP and Cu2+ ions that efficiently catalyzes Michael reactions to produce valuable chiral Michael adducts.
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Datum: 15.11.2021


Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03700E, Critical Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
James H. Carter, Takudzwa Bere, Jack R. Pitchers, Daniel G. Hewes, Bart D. Vandegehuchte, Christopher J. Kiely, Stuart H. Taylor, Graham J. Hutchings
This critical review evaluates the state-of-the-art in propane dehydrogenation catalysis using oxidative and non-oxidative methods, with an emphasis on the sustainability and suitability for process commercialisation.
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Datum: 15.11.2021


A stand-alone cobalt bis(dicarbollide) photoredox catalyst epoxidates alkenes in water at extremely low catalyst load

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03119H, Paper
Isabel Guerrero, Clara Viñas, Isabel Romero, Francesc Teixidor
Cobaltabis(dicarbollide), Na[3,3′-Co(η5-1,2-C2B9H11)2] Na[1]), is an efficient photoredox catalyst for the epoxidation of alkenes in water, at low catalyst loading and requiring short reaction times (15–30 min).
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Datum: 12.11.2021


One-pot production of diethyl maleate via catalytic conversion of raw lignocellulosic biomass

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03114G, Paper
Zhenping Cai, Rujia Chen, Hao Zhang, Fukun Li, Jinxing Long, Lilong Jiang, Xuehui Li
Selective conversion of raw biomass to diethyl maleate was conducted by polyoxometalate ionic liquid [BSmim]CuPW12O40, where up to 329.6 mg g−1 DEM yield, 70.3 % selectivity, and 20.8% carbon yield were obtained at 170 °C for 4 h and 1 MPa O2.
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Datum: 12.11.2021


Choosing the right strategy: cryogrinding vs. ball milling – comparing apples to apples

Green Chem., 2021, 23,9646-9657
DOI: 10.1039/D1GC03128G, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Julia L. Shamshina, Robin S. Stein, Noureddine Abidi
Despite many reports on ball milling (BM) of chitin, the effect of cryomilling of chitin has not yet been reported, even though it is a solventless and environmentally-friendly method for the processing of chitin polymer.
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Datum: 11.11.2021


Comprehensive assessment of CO2 methanation: which H2 production pathway is practicable for green methane production in terms of technical, economic, and environmental aspects?

Green Chem., 2021, 23,9502-9514
DOI: 10.1039/D1GC02755G, Paper
Changgwon Choe, Boreum Lee, Ayeon Kim, Seunghyun Cheon, Hankwon Lim
The analytic hierarchy process was performed to determine the best alternative for green methane production based on the results of technical assessment, economic analysis, and life cycle assessment.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.11.2021


Research progress on the preparation and application of biomass derived methyl levulinate

Green Chem., 2021, 23,9254-9282
DOI: 10.1039/D1GC03474J, Tutorial Review
Gang Wu, Chen Shen, Shasha Liu, Yong Huang, Shu Zhang, Hong Zhang
The research works on preparation and application of biomass derived methyl levulinate were summarized. The problems, corresponding solutions, and future research directions in this field were proposed.
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Datum: 11.11.2021


Iodine-catalyzed, highly atom-economic synthesis of 9-sulfenylphenanthrenes and polycyclic heteroaromatics in water

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03305K, Paper
Nilanjana Mukherjee, Tanmay Chatterjee
An iodine-catalyzed, highly atom-economic and scalable synthetic method has been developed for the oxidative annulation of 2-alkynyl biaryls with disulfides in water to access a wide variety of 9-sulfenylphenanthrenes and polycyclic heteroaromatics.
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Datum: 11.11.2021


Comparative sustainability assessment of a hydrogen supply network for hydrogen refueling stations in Korea – a techno-economic and lifecycle assessment perspective

Green Chem., 2021, 23,9625-9639
DOI: 10.1039/D1GC03006J, Paper
Malik Sajawal Akhtar, Rofice Dickson, Haider Niaz, Dong Won Hwang, J. Jay Liu
Economical and environmental sustainability of hydrogen supply routes is evaluated for hydrogen refueling stations.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.11.2021


Recommendations for replacing PET on packaging, fiber, and film materials with biobased counterparts

Green Chem., 2021, 23,8795-8820
DOI: 10.1039/D1GC02082J, Tutorial Review
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Andreia F. Sousa, Rafael Patrício, Zoi Terzopoulou, Dimitrios N. Bikiaris, Tobias Stern, Julia Wenger, Katja Loos, Nadia Lotti, Valentina Siracusa, Anna Szymczyk, Sandra Paszkiewicz, Konstantinos S. Triantafyllidis, Alexandra Zamboulis, Marija S. Nikolic, Pavle Spasojevic, Shanmugam Thiyagarajan, Daan S. van Es, Nathanael Guigo
What are the most promising biobased PET replacements? Are they economically feasible? Are they sustainable? Industrially feasible? In the future, PET will certainly be replaced by more than one option, e.g., PEF, PTF, bio-PET, and PLA.
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Datum: 10.11.2021


Direct synthesis of N-aryl/alkyl 3-carbonylpyrroles from the Morita–Baylis–Hillman acetate of 2,2-dimethoxyacetaldehyde and a primary amine

Green Chem., 2021, 23,9465-9469
DOI: 10.1039/D1GC03635A, Communication
Luxia Guo, Jiaqi Li, Luigi Vaccaro, Minghao Li, Yanlong Gu
A kalinite catalyzed direct synthesis of N-substituted 3-carbonylpyrroles from the Morita–Baylis–Hillman acetate of 2,2-dimethoxyacetaldehyde and a primary amine in ethanol was developed.
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Datum: 10.11.2021


Computer-aided solvent screening for the fractionation of wet microalgae biomass

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03471E, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laura König-Mattern, Steffen Linke, Liisa Rihko-Struckmann, Kai Sundmacher
Computational solvent selection enables the screening of more than 8000 solvent candidates for the fractionation of wet microalgal cells.
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Datum: 10.11.2021


Surface active ionic liquid assisted metal-free electrocatalytic-carboxylation in aqueous phase: a sustainable approach for CO2 utilization paired with electro-detoxification of halocarbons

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03412J, Paper
Sarwar Ahmad Pandit, Sajad Ahmad Bhat, Mudasir Ahmad Rather, Feroz Ahmad Sofi, Pravin P. Ingole, Zahid Manzoor Bhat, Musthafa Ottakam Thotiyl, Khursheed Ahmad Bhat, Shakeel U. Rehman, Mohsin Ahmad Bhat
Electrocarboxylation of halocarbons in aqueous micellar solutions of Imidazolium based surface active ionic liquids offers a promising green strategy for capture, fixation and utilization of CO2 for the synthesis of high-added value compounds.
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Datum: 09.11.2021


From green to blue economy: Marine biorefineries for a sustainable ocean-based economy

Green Chem., 2021, 23,9377-9400
DOI: 10.1039/D1GC03191K, Perspective
Nathalia Vieira Veríssimo, Cassamo Ussemane Mussagy, Ariane Alves Oshiro, Carlos Miguel Nóbrega Mendonça, Valéria de Carvalho Santos-Ebinuma, Adalberto Pessoa, Ricardo Pinheiro de Souza Oliveira, Jorge Fernando Brandão Pereira
Biorefinery is the ideal model to help marine industries to apply green and blue economy principles towards a more sustainable, profitable, and conscious ocean economy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.11.2021


From symmetrical tetrasulfides to trisulfide dioxides via photocatalysis

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03242A, Communication
Kai Gong, Yilin Zhou, Xuefeng Jiang
A photocatalytic strategy for accessing trisulfides dioxides has been established. Flow-setup synthesis was achieved on the gram scale, indicating industrial potential.
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Datum: 08.11.2021


Visible-light-driven prompt and quantitative production of lactic acid from biomass sugars over a N-TiO2 photothermal catalyst

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03057D, Paper
Yingying Cao, Dandan Chen, Ye Meng, Shunmugavel Saravanamurugan, Hu Li
Biomass sugars can be quantitatively upgraded to lactic acid in water over a visible-light-activated N-TiO2 photothermal catalyst under mild conditions (60 °C, 0.5–2 h).
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Datum: 08.11.2021


Immobilization of molecular catalysts on solid supports via atomic layer deposition for chemical synthesis in sustainable solvents

Green Chem., 2021, 23,9523-9533
DOI: 10.1039/D1GC02024B, Paper
Pooja J. Ayare, Shawn A. Gregory, Ryan J. Key, Andrew E. Short, Jake G. Tillou, James D. Sitter, Typher Yom, Dustin W. Goodlett, Dong-Chan Lee, Faisal M. Alamgir, Mark D. Losego, Aaron K. Vannucci
Atomic layer deposition immobilizes molecular catalysts on solid supports, which prevents molecular deactivation pathways and leads to longer catalyst lifetimes in high aqueous content solvents.
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Datum: 08.11.2021


Capturing ethylene glycol with dimethyl carbonate towards depolymerisation of polyethylene terephthalate at ambient temperature

Green Chem., 2021, 23,9412-9416
DOI: 10.1039/D1GC02298A, Communication
Shinji Tanaka, Junichi Sato, Yumiko Nakajima
A strategy of capturing ethylene glycol with dimethyl carbonate in the catalytic methanolysis of polyethylene terephthalate enabled depolymerization at ambient temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.11.2021


OrganoSoxhlet: circular fractionation to produce pulp for textiles using CO2 as acid source

Green Chem., 2021, 23,9401-9405
DOI: 10.1039/D1GC03079E, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Davide Di Francesco, Kiran Reddy Baddigam, Suthawan Muangmeesri, Joseph S. M. Samec
Organosolv pulping performed in a high-pressure Soxhlet extractor using carbon dioxide as a mild and recyclable acid is described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.11.2021


A continuous flow chemistry approach for the ultrafast and low-cost synthesis of MOF-808

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02824C, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Sujay Bagi, Shuai Yuan, Sergio Rojas-Buzo, Yang Shao-Horn, Yuriy Román-Leshkov
The continous flow reactor can synthesize MOF-808—an industrially relevant MOF—in 5 minutes compared to 48 hours in Batch, while maintaining crystallinity and porosity of the final product.
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Datum: 05.11.2021


Metal-free visible-light-promoted C(sp3)–H functionalization of aliphatic cyclic ethers using trace O2

Green Chem., 2021, 23,9454-9459
DOI: 10.1039/D1GC03482K, Communication
Ben Niu, Bryan G. Blackburn, Krishnakumar Sachidanandan, Maria Victoria Cooke, Sébastien Laulhé
Presented is a light-promoted C–C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst.
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Datum: 05.11.2021


Visible-light-induced intermolecular aminoselenation of alkenes

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03195C, Paper
Gong-Qing Liu, Chen-Fan Zhou, Yun-Qian Zhang, Wei Yi, Peng-Fei Wang, Ji Liu, Yong Ling
A visible-light-induced intermolecular aminoselenation of alkenes is disclosed, wherein 1,2-bis(selenide) is involved as the key intermediate.
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Datum: 05.11.2021


Engineering cellulose into water soluble poly(protic ionic liquid) electrolytes in the DBU/CO2/DMSO solvent system as an organocatalyst for the Knoevenagel condensation reaction

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03148A, Paper
Yuqing Shen, Chaoping Yuan, Xianyi Zhu, Qin Chen, Shenjun Lu, Haibo Xie
Linear water soluble cellulosic poly(protic ionic liquid) electrolytes were facilely and atom economically prepared after dissolution of cellulose in a DBU/CO2/DMSO solvent system, and can be used as an efficient catalyst for the Knoevenagel condensation reaction in water.
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Datum: 05.11.2021


Semi-aromatic biobased polyesters derived from lignin and cyclic carbonates

Green Chem., 2021, 23,9658-9668
DOI: 10.1039/D1GC03135J, Paper
DeMichael Winfield, John Ring, Jessica Horn, Evan M. White, Jason Locklin
Synthesis, characterization, and compostability of several biobased polyesters with a wide array of thermoplastic and elastic properties are described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 05.11.2021


I2-induced cascade cyclization and dearomatization of indoles for the highly efficient synthesis of iodinated and vinylic spiroindolenines

Green Chem., 2021, 23,9165-9171
DOI: 10.1039/D1GC02713A, Paper
Xiaohui Wei, Xuewu Liang, Yazhou Li, Qi Liu, Xuyi Liu, Yu Zhou, Hong Liu
The spiroindolenine framework is a privileged heterocyclic motif and is widely present in numerous indole alkaloids.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.11.2021


Efficient conversion of spent mushroom substrate into a high value-added anticancer drug pentostatin with engineered Cordyceps militaris

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03594K, Paper
Gen Zou, Bo Li, Ying Wang, Xin Yin, Ming Gong, Junjun Shang, Yongjun Wei, Xiaoling Li, Dapeng Bao
An engineered Cordyceps militaris cell factory enables sustainable disposal of spent mushroom substrate while synthesizing valuable anticancer drug.
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Datum: 04.11.2021


Tuning the selectivity of electrochemical levulinic acid reduction to 4-hydroxyvaleric acid: a monomer for biocompatible and biodegradable plastics

Green Chem., 2021, 23,9154-9164
DOI: 10.1039/D1GC02826J, Paper
Francisco W. S. Lucas, Yuval Fishler, Adam Holewinski
Levulinic acid (LA) is a biomass-derived feedstock; herein, we present an efficient electrochemical method for converting LA into 4-hydroxyvaleric acid, a valuable monomer for bio-polyesters, as well as γ-valerolactone (a green fuel/solvent).
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.11.2021


Semi-heterogeneous photocatalytic fluoroalkylation-distal functionalization of unactivated alkenes with RFSO2Na under air atmosphere

Green Chem., 2021, 23,9577-9582
DOI: 10.1039/D1GC03665C, Paper
Yali He, Xiao Dan, Yurong Tang, Qian Yang, Wentao Wang, Yunfei Cai
An efficient and eco-friendly heterogeneous photocatalytic protocol for the synthesis of fluoroalkyl-containing compounds via the fluoroalkylation-distal functionalization of alkenes with RFSO2Na under air atomosphere is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.11.2021


One-pot biocatalytic synthesis of nylon monomers from cyclohexanol using Escherichia coli-based concurrent cascade consortia

Green Chem., 2021, 23,9447-9453
DOI: 10.1039/D1GC03056F, Communication
Sharad Sarak, Taresh P. Khobragade, Hyunwoo Jeon, Amol D. Pagar, Pritam Giri, Somin Lee, Hyungdon Yun
We developed a multienzyme biocatalytic cascade with high atom efficiency and a self-sufficient redox network for the synthesis of nylon monomers without adding auxiliary enzymes to recycle cofactors.
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Datum: 04.11.2021


Decoding lignin valorization pathways in the extremophilic Bacillus ligniniphilus L1 for vanillin biosynthesis

Green Chem., 2021, 23,9554-9570
DOI: 10.1039/D1GC02692E, Paper
Daochen Zhu, Lingxia Xu, Sivasamy Sethupathy, Haibing Si, Fiaz Ahmad, Rongxian Zhang, Weimin Zhang, Bin Yang, Jianzhong Sun
An efficient bioconversion procedure for the accumulation of vanillin from lignin by pathway engineering and milking fermentation has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.11.2021


Water-removable ynamide coupling reagent for racemization-free syntheses of peptides, amides, and esters

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03498G, Paper
Tao Liu, Xue Zhang, Zejun Peng, Junfeng Zhao
A water-removable ynamide coupling reagent for racemization-free construction of amide and ester bonds was reported. No column chromatography purification was involved because acidic aqueous work-up removed the byproduct completely.
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Datum: 03.11.2021


Towards cost-competitive middle distillate fuels from ethanol within a market-flexible biorefinery concept

Green Chem., 2021, 23,9534-9548
DOI: 10.1039/D1GC02854E, Paper
Junyan Zhang, Eunji Yoo, Brian H. Davison, Dongxia Liu, Joshua A. Schaidle, Ling Tao, Zhenglong Li
Cost-competitive middle distillate production from ethanol can be achieved via a pathway that relies on one-step ethanol to butene-rich olefins. 1,3-Butadiene can be flexibly produced by varying the reaction atmosphere from hydrogen to inert.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.11.2021


Enzymatic degradation of synthetic polyisoprenes via surfactant-free polymer emulsification

Green Chem., 2021, 23,9433-9438
DOI: 10.1039/D1GC03515K, Communication
Vico K. B. Adjedje, Eugen Schell, Yannick L. Wolf, Annegret Laub, Martin J. Weissenborn, Wolfgang H. Binder
A bioinspired emulsification strategy resulted in substantially increased enzymatic activities in the degradation of synthetic polyisoprene with the latex clearing protein LcpK30, even with cis : trans ratios of 56 : 27.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.11.2021


Production of chemicals from marine biomass catalysed by acidic ionic liquids

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03249F, Tutorial Review
Li Liu
Conversions of chitosan, chitin, and crustacean shells to high value-added chemicals using acidic ionic liquids (ILs) as catalysts have been reviewed, demonstrating the structural effect of marine biomass on their conversion.
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Datum: 02.11.2021


Acidic metal–organic framework empowered precise hydrodeoxygenation of bio-based furan compounds and cyclic ethers for sustainable fuels

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC03055H, Paper
Dong-Huang Liu, Hai-Long He, Jun-Jie Wang, Si-Yu Zhou, Tengwu Zeng, Xiang-Yu Gao, Yao Xiao, Xianfeng Yi, Anmin Zheng, Yue-Biao Zhang, Zhi Li
Mechanical mixture of Pd/C and a metal–organic framework-based nanoporous solid acid enables the precise hydrodeoxygenation of bio-based furan compounds and cyclic ethers towards sustainable, low carbon-footprint, and low pollution aviation fuels.
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Datum: 02.11.2021


Photo-induced direct alkynylation of methane and other light alkanes by iron catalysis

Green Chem., 2021, 23,9406-9411
DOI: 10.1039/D1GC03388C, Communication
Yunhe Jin, Lifang Wang, Qingqing Zhang, Yongqiang Zhang, Qian Liao, Chunying Duan
An iron-catalysed photoredox alkynylation of methane, ethane, and other light alkanes is developed as a concise and efficient approach to valuable internal alkyne synthesis.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.11.2021


Natural eutectic solvents for sustainable recycling of poly(ethyleneterephthalate): closing the circle

Green Chem., 2021, 23,9460-9464
DOI: 10.1039/D1GC02403E, Communication
Samuel C. Pestana, João N. Machado, R. Domingos Pinto, Bernardo D. Ribeiro, Isabel M. Marrucho
Aiming at providing a new solution for processing and recycling PET, the full solubilization of PET from water bottles in natural eutectic solvents was achieved as well as its full recovery, retaining PET properties and recycling the eutectic solvent.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.11.2021


Iron(II)-catalyzed intermolecular aziridination of alkenes employing hydroxylamine derivatives as clean nitrene sources

Green Chem., 2021, 23,9428-9432
DOI: 10.1039/D1GC03495B, Communication
Georgina Kirby, Laurence Grimaud, Maxime R. Vitale, Guillaume Prestat, Farouk Berhal
The iron-catalyzed intermolecular aziridination of alkenes with hydroxylamine derivatives is described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.11.2021


Catalysts derived from Earth-abundant natural biomass enable efficient photocatalytic CO2 conversion for achieving a closed-loop carbon cycle

Green Chem., 2021, 23,9683-9692
DOI: 10.1039/D1GC03701C, Paper
Qi-Su Huang, Wei Wei, Bing-Jie Ni
A one-pot, facile, sulfuric-acid-assisted carbonization method was developed to fabricate a series of biomass-derived metal-free carbonaceous photocatalysts for high performance CO2 conversion, which satisfied a closed-loop carbon cycle.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.11.2021


Efficacy, economics, and sustainability of bio-based insecticides from thermochemical biorefineries

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02956H, Paper
A. Nolan Wilson, Matthew J. Grieshop, Joseph Roback, Stefano Dell'Orco, Juan Huang, Jacquelyn A. Perkins, Scott Nicholson, David Chiaramonti, Mark R. Nimlos, Earl Christensen, Kristiina Iisa, Kylee Harris, Abhijit Dutta, John R. Dorgan, Joshua A. Schaidle
The efficacy, economics, and sustainability of a bio-based insecticide produced from the catalytic fast pyrolysis of biomass is reported. This synergistic approach to fuels and agrochemical production can improve both energy and food sectors.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.10.2021


A heterogeneous catalytic strategy for facile production of benzimidazoles and quinoxalines from primary amines using the Al-MCM-41 catalyst

Green Chem., 2021, 23,9439-9446
DOI: 10.1039/D1GC02627E, Communication
Amrutham Vasu, Mameda Naresh, Gajula Krishna Sai, Yennamaneni Divya Rohini, Boosa Murali, Madasu Ramulamma, Addipilli Ramunaidu, Nama Narender
This study reports a straightforward heterogeneous catalytic (Al-MCM-41) approach to synthesize nitrogen heterocycle moieties from primary amines under solvent-free conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.10.2021


Active role of lignin in anchoring wood-based stabilizers to the emulsion interface

Green Chem., 2021, 23,9084-9098
DOI: 10.1039/D1GC02891J, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Danila M. de Carvalho, Maarit H. Lahtinen, Mamata Bhattarai, Martin Lawoko, Kirsi S. Mikkonen
Lignin moieties anchoring and delivering wood-based stabilizers to the interface improve the physical stabilization of emulsions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.10.2021


Electrochemical strategies for N-cyanation of secondary amines and α C-cyanation of tertiary amines under transition metal-free conditions

Green Chem., 2021, 23,9422-9427
DOI: 10.1039/D1GC02529E, Communication
Zhengjiang Fu, Yaping Fu, Jian Yin, Guangguo Hao, Xuezheng Yi, Tingting Zhong, Shengmei Guo, Hu Cai
Electrochemical N-cyanation of secondary amines and α C-cyanation of tertiary amines have been established under transition metal-free conditions, which provide cyanamides and nitriles with good functional group tolerance from simple systems.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.10.2021


The critical role of anions in the porous biochar structure and potassium release during the potassium-assisted pyrolysis process

Green Chem., 2021, 23,9589-9599
DOI: 10.1039/D1GC03072H, Paper
Mingwei Xia, Wei Chen, Jing Wu, Yingquan Chen, Haiping Yang, Xu Chen, Danchen Zhu, Hanping Chen
Anions of potassium additives have a great influence on the structure of porous biochar and potassium release during the biomass pyrolysis process.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


Plastics to fertilizers: chemical recycling of a bio-based polycarbonate as a fertilizer source

Green Chem., 2021, 23,9030-9037
DOI: 10.1039/D1GC02327F, Paper
Takumi Abe, Rikito Takashima, Takehiro Kamiya, Choon Pin Foong, Keiji Numata, Daisuke Aoki, Hideyuki Otsuka
A polymer is used as a source of fertilizer. To demonstrate the viability of this concept, the chemical recycling of poly(isosorbide carbonate) (PIC) is presented as a model for the next generation of plastic-recycling systems.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


Correction: Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions

Green Chem., 2021, 23,9179-9179
DOI: 10.1039/D1GC90109E, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xianglei Meng, Zhaoyang Ju, Suojiang Zhang, Xiaodong Liang, Nicolas von Solms, Xiaochun Zhang, Xiangping Zhang
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


A review of hydrodeoxygenation of bio-oil: model compounds, catalysts, and equipment

Green Chem., 2021, 23,9348-9376
DOI: 10.1039/D1GC03183J, Tutorial Review
Lu Qu, Xia Jiang, Zihao Zhang, Xiang-gang Zhang, Guo-yong Song, Hua-lin Wang, Yuan-ping Yuan, Yu-long Chang
Bio-oils are an important part of the future energy composition.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


Constructing a bacterial cellulose-based bacterial sensor platform by enhancing cell affinity via a surface-exposed carbohydrate binding module

Green Chem., 2021, 23,9600-9609
DOI: 10.1039/D1GC03097C, Paper
Lingfeng Long, Yun Hu, Le Xie, Fubao Sun, Zhenghong Xu, Jinguang Hu
This study sheds light on designing an environmentally friendly biosensing platform with sustainable cellulose materials.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


Instantaneous hydrolysis of PET bottles: an efficient pathway for the chemical recycling of condensation polymers

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02896K, Paper
Jose Jonathan Rubio Arias, Wim Thielemans
An instantaneous and straightforward way to chemically recycle PET has been developed, which involves inexpensive reagents and provides a fertilizer as byproduct.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


Co-dissolution of cellulose and silk fibroin in levulinic acid-derived protic ionic liquids for composited membrane and fiber preparation

Green Chem., 2021, 23,9669-9682
DOI: 10.1039/D1GC02837E, Paper
Wang Yue, Lihua Zhang, Lulu Deng, Yuanlong Guo, Qinqin Xu, Wei Peng, Peng Chen, Haibo Xie, Guanglong Zou, Songmiao Liang
Biobased PILs were identified to have good solubility to cellulose and silk fibroin, providing a sustainable dissolution processing platform for the preparation of cellulose/silk fibroin composited membranes and fibers.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


One-pot production of oxygenated monomers and selectively oxidized lignin from biomass based on plasma electrolysis

Green Chem., 2021, 23,9109-9125
DOI: 10.1039/D1GC03315H, Paper
Lusi A, Harish Radhakrishnan, Hui Hu, Xianglan Bai
One-pot conversion of biomass is performed to produce carbohydrate-derived oxygenated monomers and a selectively oxidized lignin using a single-step process.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


Bifunctionalization of unsaturated bonds via carboxylative cyclization with CO2: a sustainable access to heterocyclic compounds

Green Chem., 2021, 23,9334-9347
DOI: 10.1039/D1GC02783B, Tutorial Review
Shuai-Fang Cai, Hong-Ru Li, Liang-Nian He
This review provides the state of the art of bifunctionalization of unsaturated bonds in carboxylative cyclization with CO2 and sheds light on its future development.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


Concise synthesis of N-phosphorylated amides through three-component reactions

Green Chem., 2021, 23,9417-9421
DOI: 10.1039/D1GC03065E, Communication
Yuan-Yuan Zhu, Tao Zhang, Linlin Zhou, Shang-Dong Yang
A one-pot synthesis of N-phosphorylated amides was achieved by a three-component reaction with carboxylic acids, phosphorus chlorides and azides under mild reaction conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.10.2021


Organic syntheses greenness assessment with multicriteria decision analysis

Green Chem., 2021, 23,9583-9588
DOI: 10.1039/D1GC03108B, Paper
Marek Tobiszewski, Witold Przychodzeń, Marta Bystrzanowska, Maria J. Milewska
Greenness metrics for comparative, comprehensive and simple assessment of organic syntheses processes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.10.2021


Plastic waste to drug intermediate: targeted cleavage of C–O bonds in polyphenylene oxide to 3,5-dimethyl phenol

Green Chem., 2021, 23,9640-9645
DOI: 10.1039/D1GC02767K, Paper
Bo Feng, Yaxuan Jing, Yong Guo, Xiaohui Liu, Yanqin Wang
Starting from polyphenylene oxide plastic, the selective production of 3,5-dimethyl phenol as an important pharmaceutical intermediate was achieved over Ru/Nb2O5, which is the first example of integrating waste plastic into the drug supply chain.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.10.2021


Metal-free, visible-light driven C–H ketoalkylation of glycine derivatives and peptides

Green Chem., 2021, 23,9549-9553
DOI: 10.1039/D1GC03230E, Paper
Hong Xin, Zi-Hang Yuan, Mingyu Yang, Ming-Hua Wang, Xin-Hua Duan, Li-Na Guo
A metal free, visible-light driven C–H ketoalkylation of glycine derivatives and peptides with cycloalkyl hydroperoxides is presented. This protocol provides diverse unnatural amino acids bearing a distal carbonyl group in moderate to good yields.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.10.2021


Divergent Ritter-type amination via photoredox catalytic four-component radical-polar crossover reactions

Green Chem., 2021, 23,9571-9576
DOI: 10.1039/D1GC03048E, Paper
Sheng-Qiang Guo, Hui-Qing Yang, Ai-Lian Wang, Yu-Zhen Jiang, Guo-Qiang Xu, Yong-Chun Luo, Zhao-Xu Chen, Peng-Fei Xu
Divergent Ritter-type amination via photoredox catalytic four-component radical-polar crossover reactions with high atom-, step- and redox economy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.10.2021


Graphitic carbon nitride (g-C3N4) as a sustainable heterogeneous photocatalyst for metal free and oxygen-tolerant photo-atom transfer radical polymerization (photo-ATRP)

Green Chem., 2021, 23,9617-9624
DOI: 10.1039/D1GC03604A, Paper
Lin Zhou, Ziqi Zhang, Mengmeng Li, Qi Wang, Jiani Gao, Kebin Li, Lin Lei
Graphitic carbon nitride (g-C3N4) is used as a sustainable heterogeneous photocatalyst, which can effectively catalyze photo-atom transfer radical polymerization (photo-ATRP) without any additives.
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Datum: 25.10.2021


Boosting the methanolysis of polycarbonate by the synergy between ultrasound irradiation and task specific ionic liquids

Green Chem., 2021, Advance Article
DOI: 10.1039/D1GC02239C, Paper
Francesca D'Anna, Maria Sbacchi, Giulia Infurna, Nadka Tz. Dintcheva, Salvatore Marullo
Combined use of task specific ionic liquids and ultrasound irradiation gives a suitable protocol to perform methanolysis of polycarbonate in a sustainable way.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.10.2021


Recent advances in the incorporation of CO2 for C–H and C–C bond functionalization

Green Chem., 2021, 23,9283-9317
DOI: 10.1039/D1GC02737A, Tutorial Review
Sandeep Pimparkar, Aishwarya K. Dalvi, Adithyaraj Koodan, Siddhartha Maiti, Shaeel Ahmed Al-Thabaiti, Mohamed Mokhtar, Arnab Dutta, Yong Rok Lee, Debabrata Maiti
Functionalization with CO2: This tutorial review is focused on various approaches developed so far for functionalization of unsaturated C–C & C–H bonds using CO2 to achieve carboxylation, lactonization & lactamization by metal and metal free methods.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.10.2021


Sustainable production of levulinic acid and its derivatives for fuel additives and chemicals: progress, challenges, and prospects

Green Chem., 2021, 23,9198-9238
DOI: 10.1039/D1GC02919C, Critical Review
Muhammad Sajid, Usman Farooq, Ghulam Bary, Muhammad Mohsin Azim, Xuebing Zhao
The research progress on the production of levulinic acid and its derivatives for fuel additives and chemicals from various sugars and biomass feedstocks have been comprehensively reviewed, focusing on the chemical processes and mechanisms.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.10.2021


Mechanistic understanding of the catalytic hydrogenation of bio-derived aromatics

Green Chem., 2021, 23,9239-9253
DOI: 10.1039/D1GC03037J, Critical Review
Iris K. M. Yu
The pressing need for “zero carbon” calls for a transition from the petroleum refinery to biorefinery of renewable feedstocks. This review addresses the kinetic and thermodynamic understanding in the hydrogenative upgrading of bio-derived aromatics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.10.2021


An iron(III)-catalyzed dehydrogenative cross-coupling reaction of indoles with benzylamines to prepare 3-aminoindole derivatives

Green Chem., 2021, 23,9610-9616
DOI: 10.1039/D1GC02849A, Paper
Wei-Li Chen, Kun Li, Wei-Cong Liao, Wang-Fu Liang, Pei-Wen Qiu, Cui Liang, Gui-Fa Su, Dong-Liang Mo
An iron(III)-catalyzed dehydrogenative cross-coupling reaction of indoles and benzylamines was developed to prepare various substituted 3-aminoindole derivatives in good to excellent yields.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.10.2021


Homogeneous modification of chitin and chitosan based on an alkali/urea soluble system and their applications in biomedical engineering

Green Chem., 2021, 23,9318-9333
DOI: 10.1039/D1GC03205D, Tutorial Review
Shichao Bi, Di Qin, Shipeng Yuan, Xiaojie Cheng, Xiguang Chen
The homogeneous chemical modification of chitosan and chitin in alkali/urea solvents and their possible applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.10.2021


Electrochemically enabled rhodium-catalyzed [4 + 2] annulations of arenes with alkynes

Green Chem., 2021, 23,9515-9522
DOI: 10.1039/D1GC03187B, Paper
Zi-Chen Wang, Rui-Tao Li, Qiang Ma, Jia-Yi Chen, Shao-Fei Ni, Ming Li, Li-Rong Wen, Lin-Bao Zhang
Herein, electrochemically driven, Rh(III)-catalyzed regioselective annulations of arenes with alkynes have been established.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.10.2021


Evaluating the environmental impacts of formic acid production from CO2: catalytic hydrogenation vs. electrocatalytic reduction

Green Chem., 2021, 23,9470-9478
DOI: 10.1039/D1GC02997E, Paper
Dongseong Kang, Jaewon Byun, Jeehoon Han
This study analyzes the environmental feasibility of formic acid production from CO2 in terms of greenhouse gas emission and fossil resource depletion, and describes the environmental bottlenecks of the CO2 utilization strategies.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.10.2021


Design of closed-loop recycling production of a Diels–Alder polymer from a biomass-derived difuran as a functional additive for polyurethanes

Green Chem., 2021, 23,9479-9488
DOI: 10.1039/D1GC02865K, Paper
Hochan Chang, Min Soo Kim, George W. Huber, James A. Dumesic
A sustainable closed-loop recycling system for production of a new performance polymer by acetalization, Diels–Alder reaction, and hydrolysis of biomass-derived 5-hydroxymethyl furfural.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.09.2021


Single-step preparation of zinco- and aluminosilicate delaminated MWW layers for the catalytic conversion of glucose

Green Chem., 2021, 23,9489-9501
DOI: 10.1039/D1GC02353E, Paper
Hyung-Ki Min, Sungjoon Kweon, Sohun Oh, Hyejin An, Yunhye Cho, Haehyun Min, Donghui Jo, Jeong F. Kim, Chae-Ho Shin, Sung Bong Kang, Min Bum Park
Simply synthesized Lewis acidic Zn-DML and Lewis–Brønsted acidic ZnAl-DML catalysts selectively produced fructose and 5-hydroxymethylfurfural, respectively, in a glucose conversion.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 07.09.2021


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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