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Dalton Transactions

Current research articles..




The scientific journal Dalton Transactions embraces all aspects of the chemistry of inorganic and organometallic compounds, including biological inorganic chemistry, solid-state inorganic chemistry, application of physicochemical and computational techniques, new or improved experimental techniques and syntheses.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles in the field of inorganic chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Inorganica Chimica Acta,

 - Inorganic Chemistry,

 - Inorganic Chemistry Communications,

 - European Journal of Inorganic Chemistry,

 - Russian Journal of Inorganic Chemistry.



Dalton Transactions - Abstracts



Metal‐Organic Framework Derived Carbon-Encapsulated Hollow CuO/Cu2O Heterostructure Heterohedron as an Efficient Electrocatalyst for Hydrogen Evolution Reaction

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04163K, Paper
Lixin Zhang, Congli Wang, Hongfang Jiu, Qianwen Xu, Xin Li, Wei Song, Shiyu Luo, Jiahui Zhao
It is of pivotal significance to probe highly efficient, cost-effective and low-cost catalysts for hydrogen evolution reaction. Herein, closely packed carbon-encapsulated CuO/Cu2O heterohedron with heterojunction structure is reported that combines...
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Datum: 28.01.2022


Polymorphism and Optical, Magnetic and Thermal Properties of the either Phyllo- or Inosilicate-analogous Borosulfate Cu[B2(SO4)4]

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04090A, Paper
Matthias Hämmer, Florian Pielnhofer, Oliver Janka, Hirotaka Takahashi, Peter Gross, Rainer Pöttgen, Henning A. Höppe
Two polymorphs of the borosulfate Cu[B2(SO4)4] can be selectively prepared by solvothermal syntheses. The crystal structures of inosilicate-analogous α-Cu[B2(SO4)4] (P , no. 2, a = 5.2636(2), b = 7.1449(2), c...
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Datum: 28.01.2022


Nanochannel-Based {BaZn}-Organic Framework for Catalytic Activity on Cycloaddition Reaction of Epoxides with CO2 and Deacetalization-Knoevenagel Condensation

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04231A, Paper
Lv Hongxiao, Liming Fan, Hongtai Chen, Xiutang Zhang, Yanpeng Gao
Because of the integrated properties from chemically dissimilar metals, microporous heterometallic MOFs have wider potential applicability, which prompts us to explore the tendency collocation of different metal cations in the...
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Datum: 28.01.2022


A highly sensitive sensor for colorimetric detection of palladium (II) in lysosome and its application

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03900H, Paper
Qiuchen Liu, Songtao Cai, Chang Liu, Song He, Liancheng Zhao, Xianshun Zeng, Jin Gong
Considering the scarcity of palladium ion probes with subcellular organelle targeting, especially probes with near-infrared (NIR) emission wavelengths fluorophores, our group has been working to overcome this problem and looking...
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Datum: 28.01.2022


Highly luminescent mixed-ligand bimetallic lanthanoid(III) complexes for photovoltaic applications

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04248C, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Gabriela Brito-Santos, Cecilio Hernández-Rodríguez, Beatriz Gil-Hernández, Benjamín González-Díaz, Inocencio Rafael Martín-Benenzuela, Ricardo Guerrero, Joaquin Sanchiz

Six new mixed-ligand bimetallic complexes [Eu2(bz)4(tta)2(phen)2] (1), [Gd2(bz)4(tta)2(phen)2] (2), [EuTb(bz)4(tta)2(phen)2] (3), [EuGd(bz)4(tta)2(phen)2] (4), [Eu1,2Gd0,8(bz)4(tta)2(phen)2] (5) and [Eu1,6Gd0,4(bz)4(tta)2(phen)2] (6) have been prepared with the Eu3+, Gd3+ and Tb3+ ions...


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Datum: 28.01.2022


Ohmic heating-assisted synthesis and characterization of Zn(II), Cu(II) and Pd(II) complexes of heterocyclic–fused chlorins

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04032D, Paper
Maria I. F. Moreira, José Almeida, Andreia Leite, Ana I. M. C. Lobo Ferreira, Luís M. N. B. F. Santos, Ana M.G. Silva, Maria Rangel
Chlorins are highly interesting compounds due to their spectroscopic properties both in the UV-Vis and NIR regions. Upon coordination to a metal ion, the corresponding metallochlorins demonstrate to own more...
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Datum: 28.01.2022


Nitric oxide generation study of unsymmetrical β-diketiminato copper(II) nitrite complexes

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03711K, Paper
Kuldeep Chand, Yu-Cheng Chu, Tzai-Wei Wang, Chai-Lin Kao, Ya-Fan Lin, Ming-Li Tsai, Sodio C.N. Hsu
The β-diketiminato copper(II) L1CuCl−L4CuCl and their nitrite complexes L1Cu(O2N) and L2Cu(O2N) has been synthesized and characterized. The X-ray structure of the L1CuCl−L4CuCl complexes clearly indicates towards the mononuclear structure with...
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Datum: 28.01.2022


Highly efficient functionalized MOF-LIC-1 for Extraction of U(VI) and Th(IV) from Aqueous Solution: Experimental and Theoretical Studies

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03317D, Paper
Venkata Sravani V, Somnath Sengupta, Sreenivasulu Balija, Gopakumar Gopinadhanpillai, Sarita Tripathi, Manish Chandra, C. V. S. Brahmananda Rao, A. Suresh, Nagarajan Sivaraman
A set of four new functionalized MOFs namely MOF-LIC-DPPC, MOF-LIC-GA, MOF-LIC-PCA, and MOF-LIC-SA were synthesized via post-synthetic modification (PSM) strategy using MOF-LIC-1 for efficient extraction of U(VI) and Th(IV) from...
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Datum: 27.01.2022


Well-defined cyclic silanol derivatives

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04270J, Frontier
Yujia Liu, Thanawat Chaiprasert, Armelle Ouali, Masafumi Unno
Cyclic silanol derivatives (CSDs), possessing siloxane rings consisting of T-unit silicon and oxygen atoms, are considered efficient precursors for the preparation of versatile well-defined building blocks of hybrid materials such...
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Datum: 27.01.2022


Enhancement of the catalytic activity of Mg / Al layered double hydroxide for the production of glycerol oligomers

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03817F, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Fernando José Soares Barros, Yue Liu, Clarissa Dantas Paula, F. Murilo T. Luna, Rodrigo Silveira Vieira, Enrique Rodriguez-Castellon
In this study, the impact of rehydration on the catalytic properties of Mg/Al layered double hydroxides (LDH) for glycerol oligomerization was assesed. Although previous works have employed other LDH derived...
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Datum: 27.01.2022


Insight into fragmentation of phosphirane to form phosphinidene complex: an illustration with 1-phenylselenylphosphirane W(CO)5 complex.

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04208D, Communication
Lingzhi Qiu, Qiao-Yu Zhang, donghui wei, Rongqiang Tian, Zheng Duan
Density functional theory (DFT) calculations with 1-phenylselenylphosphirane complex 1 provide an insight into phosphirane fragmentation to phosphinidene complex. The FMO and ELF analysis show that the cleavage of two P-C...
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Datum: 27.01.2022


One-pot synthesis of stable and functional hydrophilic CsPbBr3 perovskite quantum dots for “turn-on” fluorescence detection of Mycobacterium tuberculosis

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03624F, Paper
Xue Jiang, Hongwei Zeng, Changyuan Duan, Qianfang Hu, Qiaomin Wu, Yang Yu, Xiaolan Yang
All-inorganic CsPbBr3 perovskite quantum dots (QDs) are widely studied owing to their excellent optoelectronic properties, however they are usually hydrophobic and unstable in water that seriously limit their biomedical applications....
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Datum: 26.01.2022


Lithium and magnesium complexes from the employment of pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and utilization as catalysts for the hydroboration of carbonyl compounds

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03235F, Paper
Yafei Li, Huifen Pan, Yanhua Lu, Yanshu Luo, Yan Dang, Yalan Wang, Shengwang Xia, Yahong Li, Yuanzhi Xia
The push for environmentally benign and sustainable chemical processes has reinforced the demand to displace transition metals with cheap, nontoxic and naturally abundant metals. To fulfil this requirement, we endeavored...
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Datum: 26.01.2022


Long-chain mercury carboxylates relevant to saponification in oil and tempera paintings: XRPD and ssNMR complementary study of the crystal structures

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04160F, Paper
Ruslan Barannikov, Eva Kočí, Petr Bezdička, Libor Kobera, Andrii Mahun, Jan Rohlíček, Jiri Plocek, Silvie Švarcová
Saponification, resulting from pigment-binder interactions, is one of the most endangering phenomenon affecting the appearance and stability of painted works of art. The crystallization of metal carboxylates (soaps) in paint...
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Datum: 26.01.2022


Fluorescent small molecules with alternating triarylamine-substituted selenophenothiophene and triarylborane: synthesis, photophysical properties and anion sensing studies

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03681E, Paper
Gulsen Turkoglu, Turan Ozturk
This study represents the first report of designed two small D–π-A molecules possessing conjugated selenopheno[3,2-b]thiophene and triarylamine derivatives as electron donors, and thiophene as π-spacer with dimesitylborane as an electron acceptor.
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Datum: 26.01.2022


Superstructure MOF as A Framework to Composite MoS2 with rGO for Li/Na-ion Batteries Storage with High-performance and Stability

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03949K, Paper
Lei Xu, Zhipeng Gong, Yinglin Qiu, Wenbo Wu, Zunxian Yang, Bingqing Ye, Yuliang Ye, Zhiming Cheng, Songwei Ye, Zihong Shen, Yuanqing Zhou, Qiaocan Huang, Zeqian Hong, Zongyi Meng, Zhiwei Zeng, Hongyi Hong, Qianting Lan, Tailiang Guo, Sheng Xu
Abstract: Metal sulfide, as one kind of electrode materials with very high theoretical capacity, has been widely studied in lithium and sodium ion batteries. However, there are some problems hindering...
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Datum: 26.01.2022


Photo- and triboluminescent pyridinophane Cu complexes: New organometallic tools for mechanoresponsive materials

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04305F, Frontier
Ayumu Karimata, Julia R Khusnutdinova
The development of mechanoresponsive polymers has emerged as a new, attractive area of research in which changes at the molecular level exert macrolevel effects in the bulk material, and vice...
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Datum: 26.01.2022


Solution-Processed Light Induced Multilevel Non-volatile Wearable Memory Device Based on CsPb2Br5 Perovskite

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03699H, Paper
Tufan Paul, Pranab Kumar Sarkar, Soumen Maiti, Aditi Sahoo, Kalyan Kumar Chattopadhyay
Despite of the recent advancements on memory devices, quest for the building materials having low-power consumption is still on with the ultimate focus over durability of system and reliability and...
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Datum: 26.01.2022


Benzothiazole-decorated iridium-based nano-photosensitizers for photodynamic therapy of cancer cells

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04315C, Paper
Xiang Wang, Kang Song, Yong Deng, Jie Liu, Qin Peng, Xiao Lao, Jiayu Xu, Dong Wang, Turong Shi, Yuhao Li, Dan Deng, Yuqing Miao
Photodynamic therapy (PDT) is an effective non-invasive treatment for tumors. The structure of the photosensitizer has an important influence on the light utilization and the efficiency of singlet-oxygen generation. In...
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Datum: 26.01.2022


New Molecularly Engineered Binuclear Ruthenium (II) Complexes for Highly Efficient Near-Infrared Light-Emitting Electrochemical Cell (NIR-LEC)

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03212G, Paper
Babak Nemati Bideh, Hashem Shahroosvand
Abstract: From practical point of view, the stability, response time and efficiency of near-infrared light-emitting electrochemical cell (NIR-LEC) are key factors. By using the high potential of chemical modification potential...
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Datum: 26.01.2022


A supported Cr-Cr sextuple bond in an all-metal cluster

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04360A, Communication
Xingman Liu, Min Zhang, Ying-Tao Liu, Shui-Xing Wu, Zhong-Min Su
Herein, we report a distinct Cr-Cr sextuple bond with ultra-short length stabilized by equatorial alkali metals. Bonding analyses indicate that the two desired 4p-pi bonds failed to be formed but...
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Datum: 26.01.2022


Charge compensation engineering towards high-performance dolomite-type BaTi(BO3)2:Eu3+ red-emitting phosphor for backlight display applications with wide color gamut

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04286F, Paper
Bin Yu, Jiale Chen, Minghao Sun, Nianmin Chen, Yuchan Li, Yunjian Wang
Exploiting high color purity phosphors is the core problem of developing phosphor conversion light-emitting diodes (pc-LEDs) for display devices. Eu3+-activated BaTi(BO3)2 (BTB) red-emitting phosphors were first synthesized via solid-state reaction...
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Datum: 25.01.2022


Al-MOF-derived spindle-like hierarchical porous activated carbon for advanced supercapacitors

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03395F, Paper
Xingyu Liu, Xiaoyue Wang, Rui Miao, Yanzhi Sun, Yongmei Chen, Yang Tang, Pingyu Wan, Junqing Pan
Spindle-like hierarchical porous activated carbon materials derived from Al-BTEC possess high specific capacitance and good cycling stability.
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Datum: 25.01.2022


Interfacially coupled thin sheet-like NiO/NiMoO4 nanocomposites synthesized by simple reflux method for excellent electrochemical performance

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04198C, Paper
Achal Singh Keshari, Prashant Dubey
Herein, hierarchical sheet-like assemblies of interfacially coupled NiO/NiMoO4 (NNMO) nanocomposites are prepared by simple and cost-effective one-step aqueous reflux method followed by post-thermal treatment. Reaction time is optimized for high...
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Datum: 25.01.2022


Efficiently increasing low-field magnetic entropy by incorporating SO32− into Gd22Ni21 clusters

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03314J, Communication
Ningfang Li, Yemin Han, Jianian Li, Qiao-Ling Chen, Yan Xu
One distinct nanosized cluster, Gd22Ni21, was isolated by the mixed-anion-templates (SO32- and SO42-), which was firstly reported in 3d-4f metal clusters. Additionally, Gd22Ni21 shows the largest low-field magnetic entropy change...
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Datum: 25.01.2022


Three Si-substituted polyoxovanadates as efficient catalysts for Knoevenagel condensation and selective oxidation of styrene to benzaldehyde

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03862A, Paper
Yu Shi, Tong Zhou, Jia-Qi Di, Wenhui Wang, Li Ma, Heng Zhang, Yuanzhe Gao
Three new Si-substituted polyoxovanadates (POVs), [Cd2(dien)2][Cd(dien)][Cd(Hdien)2][V15Si6O46(OH)2(H2O)]•7H2O (1), [Co(enMe)2]3[Co(enMe)(H2O)]2[V16Si4O44(OH)2(H2O)]•6H2O (2), [Co(teta)]4[V16Si4O42(OH)4(H2O)]•10H2O (3) (dien = diethylenetriamine; enMe = 1,2-diaminopropane; teta = triethylenetetramine) were synthesized by hydrothermal method and characterized. Structural analysis shed...
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Datum: 25.01.2022


Molecular surface modification of silver chalcogenolate clusters

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT00016D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lei Hu, Ming-Ming Sheng, Shun-Shun Qin, Hua-Tian Shi, Maria Strømme, Qian-Feng Zhang, Chao Xu
This study presents a molecular surface modification approach to synthesizing a family of silver chalcogenolate clusters (SCCs) containing the same [Ag12S6] core and different surface-bonded organic ligands (DMAc or pyridines;...
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Datum: 25.01.2022


Core-shell and heterostructured silver-nickel nanocatalysts fabricated by γ-radiation induced synthesis for oxygen reduction in alkaline media

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03897D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yi Yang, Gerard Montserrat-Sisó, Björn Wickman, Pavel Anatolyevich Nikolaychuk, Inna L. Soroka
To reach commercial viability for fuel cells, one needs to develop active and robust Pt-free electrocatalysts. Ag has great potential to replace Pt as the catalyst for oxygen reduction reaction...
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Datum: 25.01.2022


Activating the oxygen electrocatalytic activity of layer-structured Ca0.5CoO2 nanofibers by iron doping

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03883D, Paper
Mingyu Li, Bote Zhao, Yun Zhao, Yu Chen, Meilin Liu
Herein, layer-structured Ca0.5CoO2 nanofibers made of interconnected ultrathin nanoplates have been successfully synthesized by an electrospinning strategy. The OER activity of the Ca0.5CoO2 can be dramatically improved by iron doping,...
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Datum: 25.01.2022


Deep-blue emitting cerium(III) complexes with tris(pyrazolyl)borate and triflate ligand

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04072C, Paper
Wenchao Yan, Zelun Cai, Hao Qi, Ruoyao Guo, Zhiwei Liu, Zuqiang Bian
Red, green and blue emitting materials, the three-primary colors, are very important in lighting and display. Red-emitting Eu(III) complexes and green-emitting Tb(III) complexes exhibit high color purity and photoluminescence (PL)...
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Datum: 25.01.2022


Remarkable structure and luminescence regulation of Gd2LuAl5O12:Ce garnet phosphor with Ca2+/Si4+ pair for high-quality w-WLED lighting

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04183E, Paper
Qinghong Meng, G. Y. Zhao, Qi Zhu, Xudong Sun, Ji-Guang Li
Doping Gd2LuAl5O12:Ce with Ca2+/Si4+ pair produced a series of Gd1.97−xLuCaxAl5−xSixO12:0.03Ce (x = 0.0−1.2) garnet new phosphors, and remarkable regulation of the crystal structure and Ce3+ luminescence was achieved. Rietveld refinement...
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Datum: 24.01.2022


Nanoporous germanium prepared by a mechanochemical reaction with enhanced lithium storage properties

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03316F, Paper
Xianyu Liu, Qianliang Zhang, Yansong Zhu, Shengjie Xu, Jia Zhang, Yanping Zheng, Lei Zhang, Mingguang Ma, Honghong Rao, Zheng Liu
It remains a grand challenge for the cost-effective and facile fabrication of nanostructured germanium for lithium-ion batteries (LIBs). Herein, a nanoporous Z-Ge was generated via a facile two-step mechanochemical-etching reaction...
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Datum: 24.01.2022


Dual-sensitized Eu(III)/Tb(III) complexes exhibiting tunable luminescent emission and application in cellular-imaging

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT00051B, Paper
Cui Zhang, Xiufang Ma, Peipei Cen, Huifang Yang, Zixin He, Yan Guo, Danian Tian, Xiangyu Liu
Two novel dual-photosensitized stable complexes, namely [Eu(dpq)(BTFA)3] (1) and [Tb(dpq)(BTFA)3] (2), have been successfully assembled via a mixed ligand approach using dipyrido[3,2-d:2’,3’-f]quinoxaline (dpq) and 3-benzoyl-1,1,1-trifluoroacetone (BTFA) . The crystallographic data...
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Datum: 24.01.2022


Evaluation of the Binding Mode of a Cytotoxic Dinuclear Nickel Complex to two Neighboring Phosphates of the DNA Backbone

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03813C, Paper
Jasmin Simon, Claudia Horstmann, Andreas Mix, Anja Stammler, Jan Oldengott, Hartmut Bögge, Thorsten Glaser
A family of dinuclear complexes based on 2,7-disubstituted 1,8-naphthalenediol-ligands has been designed to bind covalently to two neighboring phosphate diester groups in the backbone of DNA. The dinuclear CuII and...
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Datum: 24.01.2022


Synthesis and characterization of rare-earth metallate amido complexes bearing 2-amidate-functionalized indolyl ligand and their application in the hydroboration of esters with pinacolborane

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT03384K, Paper
Yun Wei, Qin Bao, Lulu Song, Dongjing Hong, Jianjian Gao, Shaowu Wang, Xiancui Zhu, Shuangliu Zhou, Xiaolong Mu
The reactions of 2-amidate-functionalized indolyl proligand 2-(2,6-iPr2C6H3NHC=O)C8H5NH (H2L) with [(Me3Si)2N]3RE(μ-Cl)Li(THF)3 were studied leading to the synthesis and characterization of a series of novel discrete trinuclear rare-earth metal metallate amido complexes...
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Datum: 24.01.2022


Structural determinations and magnetic properties of a “chiral at metal” complex and its resulting [Cu–Ln]2 compounds

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04249A, Paper
Jean-Pierre Costes, Carine Duhayon, Laure Vendier, Wolfgang Wernsdorfer
Reaction of the (S)-[LCu]pipH complex with LnIII ions does not allow to keep the stereogenic Cu centre present in the starting CuII complex.
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Datum: 24.01.2022


Defects engineered SnO2 nanoparticles enable strong CO2 chemisorption toward efficient electroconversion to formate

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D1DT04045F, Paper
Baoxing Ning, Miaomiao Liu, Yanjie Hu, Hao Jiang, Chunzhong Li
Oxygen vacancies (Ov) engineering of SnO2 electrocatalysts plays a crucial role in realizing efficient CO2 electroreduction (CO2RR) into formate. Herein, we demonstrate the rational synthesis of high-dispersive SnO2 nanoparticles electrocatalysts...
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Datum: 22.01.2022


Sterically rigid bismuth pincer complexes; observation of the growing polymer chain in polar monomer polymerisation

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04297A, Paper
Zoë R. Turner, Jamie T. Wilmore, Nicholas H. Rees, Jean-Charles Buffet
A family of pyridine dipyrrolide bismuth complexes have been prepared and investigated as initiators for the ring-opening polymerisation of lactide monomers.
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Datum: 21.01.2022


Carboxamide substituted tetramethylcyclopentadiene – synthesis, characterisation and its iridium(III) complex catalysed reduction of imines

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT00149G, Paper
Joseph M. Mwansa, Matthew J. Stirling, Gemma Sweeney, Jiří Hanusek, Jiří Váňa, Michael I. Page
The novel dimeric iodo-iridium(III) complex bearing an amide moiety within the tetramethylcyclopentadiene ring, has been synthesised, characterised and its catalytic activity has been evaluated in the transfer hydrogenation of imines.
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Datum: 20.01.2022


Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04168A, Frontier
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Felix J. de Zwart, Vivek Sinha, Monica Trincado, Hansjörg Grützmacher, Bas de Bruin
This Frontiers article summarizes the reported computational research performed on ruthenium catalyzed methanol dehydrogenation reactions performed in the past decade, and serves as a guide for future research.
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Datum: 19.01.2022


B–O–B bridged BOPPY derivatives: synthesis, structures, and acid-catalyzed cis–trans isomeric interconversion

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04203C, Paper
Sisi Wang, Zhaoli Wang, Wenting Song, Hu Gao, Fan Wu, Yue Zhao, Kin Shing Chan, Zhen Shen
A new class of BOPPY derivatives has been facilely synthesized by a two-step reaction of coupling 3,5-dimethylpyrrole-2-carbaldehyde with 2,3-dihydrazinoquinoxaline (QDH) followed by coordinating with BF3·OEt2.
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Datum: 18.01.2022


Highly thermostable white-emitting Ca9ZnK(PO4)7:Ce3+,Dy3+ single-phase phosphor with tunable photoluminescence and energy transfer

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04124J, Paper
Youkui Zheng, Zizheng Wang, Dan Yang, Zhenyu Fang, Yuefei Xiang, Tongsheng Yang, Shuqing Yang, Yong Mao, Kai Xiong, Jing Zhu
A facile Ce3+ → Dy3+ energy transfer strategy was used to obtain a single-phase white-emitting phosphor Ca9ZnK(PO4)7:Ce3+,Dy3+ with highly thermostable behavior.
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Datum: 17.01.2022


Enantiopure, luminescent, cyclometalated Ir(III) complexes with N-heterocyclic carbene-naphthalimide chromophore: design, vibrational circular dichroism and TD-DFT calculations

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04006E, Paper
Antoine Groué, Eve Montier-Sorkine, Yaping Cheng, Marie Noelle Rager, Marion Jean, Nicolas Vanthuyne, Jeanne Crassous, Amalia C. Lopez, Alejandra Saavedra Moncada, Andrea Barbieri, Andrew L. Cooksy, Hani Amouri
Chiral [Ir(N^C)2(C^C:)] complexes are described. At room temperature they act as emitters in the red and NIR regions. Their optical and chiroptical properties were studied. Remarkably VCD and TD-DFT allow us to ascertain their stereochemistry.
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Datum: 14.01.2022


Multinuclear mesoionic 1,2,3-triazolylidene complexes: design, synthesis, and applications

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04221A, Frontier
Emmanuel B. Patricio-Rangel, Verónica Salazar-Pereda, Omar Cortezano-Arellano, Daniel Mendoza-Espinosa
In this short review article, recent progress on the design and synthesis of multinuclear triazolylidene complexes (di- to tetranuclear species) is discussed.
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Datum: 14.01.2022


Electrochemically activated Co-Prussian blue analogue derived amorphous CoB nanostructures: an efficient electrocatalyst for the oxygen evolution reaction

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03947D, Paper
Rajat K. Tripathy, Aneeya K. Samantara, J. N. Behera
A series of cobalt borides (CoBs) have been prepared by reducing the Co-PBA with NaBH4 coupled with annealing in the temperature range of 300 °C to 650 °C. After electrochemical activation in alkaline medium, CoB@300 catalyses the OER efficiently.
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Datum: 13.01.2022


A tumor microenvironment-responsive Co/ZIF-8/ICG/Pt nanoplatform for chemodynamic and enhanced photodynamic antitumor therapy

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04120G, Paper
Fan Jiang, Yajie Zhao, Chunzheng Yang, Ziyong Cheng, Min Liu, Bengang Xing, Binbin Ding, Ping'an Ma, Jun Lin
A tumor microenvironment-responsive nanoplatform Co/ZIF-8/ICG/Pt (CZIP) was successfully constructed for chemodynamic therapy (CDT) and enhanced photodynamic therapy (PDT).
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Datum: 13.01.2022


Cobalt silicate: critical synthetic conditions affect its electrochemical properties for energy storage and conversion

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03818D, Paper
Tao Hu, Yang Wang, Xueying Dong, Yang Mu, Xiaoyu Pei, Xuyang Jing, Miao Cui, Changgong Meng, Yifu Zhang
The valence state of cobalt determined by the reaction system is the most important factor affecting the electrochemical performance of cobalt silicate.
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Datum: 11.01.2022


Inner-sphere electron transfer at the ruthenium-azo interface

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03934B, Paper
Sanjib Panda, Aditi Singh, Sanchaita Dey, Kuo-Wei Huang, Goutam Kumar Lahiri
Intramolecular metal-to-ligand electron transfer induced multi-step reduction of azobis(1-methylbenzimidazole) and its varying binding scenarios have been illustrated on selective {RuII(acac)2} (acac=acetylacetonate) and CuI-platforms.
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Datum: 11.01.2022


Enhancing the peroxidase-like activity of MIL-88B by ligand exchange with polydopamine

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03832J, Paper
Changzhi Hu, Yuhao Xiong, Ling Liang, Weiyuan Zuo, Fanggui Ye, Shulin Zhao
A simple ligand exchange method with polydopamine was used to synthesize PDA-MIL-88B with enhanced peroxidase-like activity.
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Datum: 11.01.2022


Surface plasmon resonance allied applications of silver nanoflowers synthesized from Breynia vitis-idaea leaf extract

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03592D, Paper
Ruby, Aryan, Mohan Singh Mehata
An environmentally friendly, green synthesis process has been adopted to synthesize silver nanoparticles (AgNPs) in an aqueous solution from a new remedial plant.
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Datum: 07.01.2022


Norbornene based-sulfide-stabilized silylium ions: synthesis, structure and application in catalysis

Dalton Trans., 2022, 51,1407-1414
DOI: 10.1039/D1DT04009J, Paper
Aymeric Dajnak, Gül Altınbaş Özpınar, Romaric Lenk, Nathalie Saffon-Merceron, Antoine Baceiredo, Tsuyoshi Kato, Thomas Müller, Eddy Maerten
A sulfide-stabilized silylium ion has emerged as an easy-to-handle Lewis acid catalyst for Diels–Alder cycloadditions and hydrodefluorination reactions.
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Datum: 07.01.2022


Recent advances in structures and applications of coordination polymers based on cyclohexanepolycarboxylate ligands

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03888E, Perspective
Yong-Cong Ou, Ri-Ming Zhong, Jian-Zhong Wu
The conformations of cylcohexanepolycarboxylates and auxiliary ligands would regulate the structure of coordination polymers which show interesting properties.
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Datum: 06.01.2022


Tunable TiO2–BN–Pd nanofibers by combining electrospinning and atomic layer deposition to enhance photodegradation of acetaminophen

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03715C, Paper
Syreina Sayegh, Fida Tanos, Amr Nada, Geoffroy Lesage, François Zaviska, Eddy Petit, Vincent Rouessac, Igor Iatsunskyi, Emerson Coy, Roman Viter, Daina Damberga, Matthieu Weber, Antonio Razzouk, Juliette Stephan, Mikhael Bechelany
TiO2–BN–Pd materials were successfully prepared by combining electrospinning and atomic layer deposition. The obtained materials show outstanding properties for the degradation of acetaminophen (ACT) under UV and visible light as well as high stability and recyclability.
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Datum: 06.01.2022


LaTiO2N nanopowders (NPs) with low surface defect density via nitridation of flame made NPs retaining simple perovskite structure

Dalton Trans., 2022, 51,1571-1579
DOI: 10.1039/D1DT03687D, Paper
Yoshiyuki Abe, Richard M. Laine
LaTiO2N NP synthesized from flame made LaTiO3 NP exhibits less absorption background above the optical absorption edge than that synthesized from flame made La2Ti2O7 NP, suggesting a low surface defect density.
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Datum: 06.01.2022


Polar hydrogen species mediated nitroarenes selective reduction to anilines over an [FeMo]Sx catalyst

Dalton Trans., 2022, 51,1553-1560
DOI: 10.1039/D1DT03107D, Paper
Siqi Li, Zhipeng Huang, Huifang Liu, Meijiang Liu, Chaofeng Zhang, Feng Wang
We herein present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and hydrazine over an iron-molybdenum sulfide catalyst ([FeMo]Sx).
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Datum: 06.01.2022


The reaction of rhenium nitrosyl with a sterically hindered NHC-carbene

Dalton Trans., 2022, 51,1521-1526
DOI: 10.1039/D1DT03966K, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
G. Grieco, O. Blacque
The paper presents both the new complex [ReCl3(NO)2(OPPh3)] (3) and its reaction with the bulky NHC carbene IMes, that yields the oximate—Re complex [(OPPh3)Re(V)(NO)(ONIMes)Cl3] (4). The reactivity of the NO toward the IMes is explained.
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Datum: 06.01.2022


Waste-honeycomb-derived in situ N-doped Hierarchical porous carbon as sulfur host in lithium–sulfur battery

Dalton Trans., 2022, 51,1502-1512
DOI: 10.1039/D1DT03705F, Paper
Hong Li, Zirui Zhao, Yuyun Li, Mingwu Xiang, Junming Guo, Hongli Bai, Xiaofang Liu, Xinzhou Yang, Changwei Su
Waste honeycomb derived porous carbon with a high specific surface area of 1683.6 m2 g−1 are prepared via a facile simultaneous activation/carbonization. The corresponding porous carbon/sulfur composite cathode exhibits a durable stable performance up to 500 cycles at 1 C.
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Datum: 06.01.2022


Detailed structural and spectroscopic elucidation of ferrocenium coupled N-heterocyclic carbene gold(I) complexes

Dalton Trans., 2022, 51,1533-1541
DOI: 10.1039/D1DT03174K, Paper
Garrett L. Reinhard, Selvakumar Jayaraman, Joshua W. Prybil, Jonathan F. Arambula, Kuppuswamy Arumugam
Unambiguous assignment of redox sites on ferrocene coupled N-heterocyclic carbene gold(I) anticancer therapeutic agents is described.
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Datum: 06.01.2022


Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear CuII/MnII complexes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04074J, Communication
Evangelos Pilichos, Pradip Bhunia, Mercè Font-Bardia, Ashutosh Ghosh, Júlia Mayans, Albert Escuer
Induced SMM responses for polynuclear systems derived from isotropic cations have been characterized for three CuII/MnII clusters with several nuclearities and S ground states. Comparison with isotropic SIMs suggests a similar relaxation mechanism.
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Datum: 05.01.2022


Structural distortion induced broad emission in vacancy-ordered halide triple perovskites

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03474J, Paper
Maruthi Mala, Tamilselvan Appadurai, Aravind Kumar Chandiran
This paper reports the role of distortion in vacancy-ordered halide perovskites in photoluminescence properties. The mixture of trivalent sites in Cs2SbxBi2−xX6 leads to the creation of distortion leading to enhanced photoluminescence.
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Datum: 05.01.2022


V2CTX catalyzes polysulfide conversion to enhance the redox kinetics of Li–S batteries

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04158D, Paper
Fengfeng Han, Qi Jin, Junpeng Xiao, Lili Wu, Xitian Zhang
V2CTX with a nanobelt structure was successfully prepared. A separator modified by V2CTX and KB was designed to accelerate redox kinetics and realize long-term cycling stability.
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Datum: 05.01.2022


Chemical design of a new displacive-type ferroelectric

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03693A, Perspective
Mitsuru Itoh, Yosuke Hamasaki, Hiroshi Takashima, Rie Yokoi, Ayako Taguchi, Hiroki Moriwake
Ferroelectricity in various kinds of oxides is discussed based on the chemical bonds between cations and oxygen. Covalency plays a crucial role in the evolution of ferroelectricity in oxides.
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Datum: 03.01.2022


An efficient chemodosimeter for the detection of Hg(II) via diselenide oxidation

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04038C, Paper
Pratiksha P. Deshmukh, Gauri S. Malankar, Arunima Sakunthala, Ambuja Navalkar, Samir K. Maji, Dhiraj P. Murale, Raju Saravanan, Sudesh T. Manjare
A coumarin based turn-on sensor for the selective detection of Hg(II) through oxidation of diselenide. The sensing mechanism supported with single crystal XRD of monoselenide. Sensitivity of the probe for the detection of Hg(II) confirmed with imaging in MCF-7 cells.
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Datum: 03.01.2022


Photophysical, photooxidation, and biomolecule-interaction of meso-tetra(thienyl)porphyrins containing peripheral Pt(II) and Pd(II) complexes. Insights for photodynamic therapy applications

Dalton Trans., 2022, 51,1646-1657
DOI: 10.1039/D1DT03565G, Paper
Isadora Tisoco, Maria Carolina Donatoni, Henrique Fernandes Vieira Victória, José Roberto de Toledo, Klaus Krambrock, Otávio Augusto Chaves, Kleber Thiago de Oliveira, Bernardo Almeida Iglesias
Novel Pt(II)- and Pd(II) cationic porphyrins in photobiological process applications.
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Datum: 03.01.2022


A novel cyclic dinuclear gold(I) complex induces anticancer activity via an oxidative stress-mediated intrinsic apoptotic pathway in MDA-MB-231 cancer cells

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT03546K, Paper
Ahmed K. Abogosh, Meshal K. Alghanem, Saeed Ahmad, Abdullah Al-Asmari, Homood M. As Sobeai, Adam A. A. Sulaiman, Mohammed Fettouhi, Saheed A. Popoola, Ali Alhoshani, Anvarhusein A. Isab
The complex was found to display cytotoxic effect via oxidative stress-mediated intrinsic apoptotic pathway in MDA-MB-231 cancer cells, as indicated by Annexin V-FITC/Propidium iodide double staining, ROS production, mitochondrial membrane potential and migration assays.
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Datum: 30.12.2021


A proton-conductive metal–organic framework based on imidazole and sulphate ligands

Dalton Trans., 2022, 51,1313-1317
DOI: 10.1039/D1DT04129K, Communication
Fu-Qi Mi, Fa-Xue Ma, Shui-Xiang Zou, Dong-Sun Zhan, Teng Zhang
Built from a combination of metal cations, neutral azole ligands and sulphate anions, the MOF [Cu2(DHBDI)3(SO4)2]n exhibits good chemical stability in acids, bases and boiling water while showing high hydrophilicity and proton conductivity.
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Datum: 28.12.2021


Fluorinated tris(pyridyl)borate ligand support on coinage metals

Dalton Trans., 2022, 51,1308-1312
DOI: 10.1039/D1DT04136C, Communication
Mukundam Vanga, Alvaro Muñoz-Castro, H. V. Rasika Dias
Chemically robust, tris(pyridyl)borate with a fluorine-lined coordination pocket allows the stabilization and detailed investigation of organometallic complexes of group 11 metal ions involving a small gaseous molecule, ethylene.
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Datum: 27.12.2021


Solution-phase decomposition of ferrocene into wüstite-iron oxide core–shell nanoparticles

Dalton Trans., 2022, 51,1603-1611
DOI: 10.1039/D1DT03222D, Paper
Matthys J. Loedolff, Rebecca O. Fuller, Gareth L. Nealon, Martin Saunders, Mark A. Spackman, George A. Koutsantonis
FeO core–shell nanoparticles (NPs) are obtained by thermal decomposition of Cp2Fe in 1-octadecene and oleic acid and oleylamine. Cubic and spherical NPs are obtained whose size and shape can be controlled through adjusting reaction parameters.
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Datum: 24.12.2021


Selective 1,2 addition of polar X–H bonds to the Ga–P double bond of gallaphosphene L(Cl)GaPGaL

Dalton Trans., 2022, 51,1612-1616
DOI: 10.1039/D1DT04299H, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Mahendra K. Sharma, Christoph Wölper, Stephan Schulz
Gallaphosphene 1 reacts with a series of polar X–H bonds exclusively with 1,2 addition to the Ga–P double bond. The gallium atom serve as electrophile whereas the nucleophilic phosphorous atom is protonated by the H-acidic substrates.
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Datum: 24.12.2021


Boosting oxygen evolution of layered double hydroxide through electronic coupling with ultralow noble metal doping

Dalton Trans., 2022, 51,1527-1532
DOI: 10.1039/D1DT03906G, Paper
Zhao Li, Dongsheng Liu, Xinhua Lu, Minglin Du, Zhenyang Chen, Jingrui Teng, Ruiqi Sha, Lin Tian
Electrocatalytic water oxidation is a rate-determining step in the water splitting process; however, its efficiency is significantly hampered by the limitations of cost-effective electrocatalysts.
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Datum: 22.12.2021


Stable and inert macrocyclic cobalt(II) and nickel(II) complexes with paraCEST response

Dalton Trans., 2022, 51,1580-1593
DOI: 10.1039/D1DT03217H, Paper
Paulo Pérez-Lourido, Enikő Madarasi, Fanni Antal, David Esteban-Gómez, Gaoji Wang, Goran Angelovski, Carlos Platas-Iglesias, Gyula Tircsó, Laura Valencia
Saturation of the paramagnetically shifted amide 1H NMR signals of Co(II) and Ni(II) macrocyclic pyclen derivatives provides an efficient pathway for the saturation of bulk water.
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Datum: 22.12.2021


The “silent CO”: a new technique for calculating transition metal carbonyl force fields

Dalton Trans., 2022, 51,1434-1445
DOI: 10.1039/D1DT03186D, Paper
John A. Timney, James J. Turner
The “silent CO group” is introduced to enable energy-factored force fields to be estimated accurately for molecules where there are fewer ν(CO) frequencies than force constants in the force field.
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Datum: 22.12.2021


A Nd6 molecular butterfly: a unique all-in-one material for SMM, MCE and maiden photosensitized opto-electronic device fabrication

Dalton Trans., 2022, 51,1617-1633
DOI: 10.1039/D1DT02364K, Paper
Krishna Sundar Das, Sayan Saha, Baishakhi Pal, Amit Adhikary, Shruti Moorthy, Sukhen Bala, Sohel Akhtar, Pradeepta Kumar Ghose, Saurabh Kumar Singh, Partha Pratim Ray, Raju Mondal
We report herein an aesthetically pleasing hexanuclear Nd6 molecular butterfly using a rather nonconventional N-rich pyridyl-pyrazolyl based ligand and their concomitant SMM and MCE properties along with elusive electronic properties.
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Datum: 21.12.2021


Shape-selective one-step synthesis of branched gold nanoparticles on the crystal surface of redox-active PdII-macrocycles

Dalton Trans., 2022, 51,1318-1324
DOI: 10.1039/D1DT03973C, Paper
Yutaro Yamashita, Shohei Tashiro, Yoshiki Ishii, Takayuki Uchihashi, Nobuyuki Matsushita, Ryou Kubota, Mitsuhiko Shionoya
Redox-active PdII3-macrocycle crystals were found to provide an excellent platform for gold reduction and growth of immobilized particles, leading to the one-step synthesis of stable, monodisperse, Konpeito-shaped gold nanoparticles.
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Datum: 20.12.2021


Self-assembly of non-macrocyclic triangular Ni3Ln clusters

Dalton Trans., 2022, 51,1446-1453
DOI: 10.1039/D1DT03742K, Paper
Tyson N. Dais, Rina Takano, Takayuki Ishida, Paul G. Plieger
Four new non-macrocyclic triangular Ni3M (M = LaIII, EuIII, GdIII, or BaII) complexes with planar Ni3MO6 cores are reported, including structural and magnetic characterisation.
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Datum: 20.12.2021


Host–guest complexes vs. supramolecular polymers in chalcogen bonding receptors: an experimental and theoretical study

Dalton Trans., 2022, 51,1325-1332
DOI: 10.1039/D1DT03925C, Paper
Encarnación Navarro-García, Bartomeu Galmés, José Luis Esquivel, María D. Velasco, Adolfo Bastida, Fabiola Zapata, Antonio Caballero, Antonio Frontera
Cl and Br anions induce the formation of a supramolecular polymer by chalcogen bonding interactions in a selenophene-based tripodal receptor.
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Datum: 20.12.2021


Ion-bearing stairs: alkali metal complexes of 1,2-diaza-4-phospholides

Dalton Trans., 2022, 51,1634-1645
DOI: 10.1039/D1DT03601G, Paper
Minggang Zhao, Tingting Xue, Ru-ru He, Jianping Ma, Wenjun Zheng
1,2-Diaza-4-phospholide alkali metal complexes showed stair-shaped chain structures, where P(III) could be oxidized by S8 and Se. The 1H DOSY NMR spectroscopy analysis suggested that they dissociated into monomers in the solution.
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Datum: 20.12.2021


Ru(III) complexes with pyrazolopyrimidines as anticancer agents: bioactivities and the underlying mechanisms

Dalton Trans., 2022, 51,1333-1343
DOI: 10.1039/D1DT02765D, Paper
Yun-Qiong Gu, Wen-Ying Shen, Qi-Yuan Yang, Zhen-Feng Chen, Hong Liang
Ruthenium(III) complex with pyrazolopyrimidine inhibited tumor cells proliferation, caused DNA damage by interacting with DNA and inhibition of the Topo I enzyme, induced cell cycle arrest in S phase and apoptosis via mitochondrial dysfunction.
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Datum: 20.12.2021


Four mononuclear dysprosium complexes with neutral Schiff-base ligands: syntheses, crystal structures and slow magnetic relaxation behavior

Dalton Trans., 2022, 51,1415-1422
DOI: 10.1039/D1DT03701C, Paper
Hui Yang, Shan-Shan Liu, Yin-Shan Meng, Yi-Quan Zhang, Lin Pu, Xincheng Wang, Shijing Lin
Subtle modifications of neutral Schiff-base ligands lead to diverse magnetic behavior in four mononuclear Dy-based complexes.
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Datum: 20.12.2021


Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum

Dalton Trans., 2022, 51,1384-1394
DOI: 10.1039/D1DT03753F, Paper
Lukas Mai, Dina Maniar, Frederik Zysk, Judith Schöbel, Thomas D. Kühne, Katja Loos, Anjana Devi
The influence of different polymer side chains on the vapor phase infiltration with TMA is investigated and supported by DFT-calculations.
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Datum: 17.12.2021


Enhancement of the thermoelectric properties of Zintl phase SrMg2Bi2 by Na-doping

Dalton Trans., 2022, 51,1513-1520
DOI: 10.1039/D1DT03704H, Paper
Fang Yu, Xiang Meng, Lu Li, Cuilian Wen
A new Zintl SrMg2Bi2 phases is systematically investigated by Na-doping to reveal its potential for thermoelectric application.
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Datum: 17.12.2021


Fe and Cu dual-doped Ni3S4 nanoarrays with less low-valence Ni species for boosting water oxidation reaction

Dalton Trans., 2022, 51,1594-1602
DOI: 10.1039/D1DT03902D, Paper
Xiaoqiang Du, Jiaxin Li, Xiaoshuang Zhang
It is worth noting that when Fe–Cu–Ni3S4 is used as anode and cathode, a small cell voltage of 1.59 V at 10 mA cm−2 is obtained to achieve stable overall water splitting.
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Datum: 17.12.2021


One-pot synthesis of TEA functionalized and NiSe embedded rGO nanocomposites for supercapacitor application

Dalton Trans., 2022, 51,1542-1552
DOI: 10.1039/D1DT03399A, Paper
Sornalatha Manickam, Hemalatha Kuzhandaivel, Yogapriya Selvaraj, Manik Clinton Franklin, Karthick Sivalingam Nallathambi
NiSe and NG-NiSe were prepared by one-pot synthesis. The triethanolamine in NG-NiSe prevents the restacking of rGO nanosheets, and rGO restricts the NiSe agglomeration leads to superior electrochemical behavior and cyclic stability in supercapacitor.
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Datum: 16.12.2021


De novo synthesis of hybrid d–f block metal complex salts for electronic charge transport applications

Dalton Trans., 2022, 51,1561-1570
DOI: 10.1039/D1DT02722K, Paper
Shreya Mahato, Amit Mondal, Mainak Das, Mayank Joshi, Partha Pratim Ray, Angshuman Roy Choudhury, C. Malla Reddy, Bhaskar Biswas
The work demonstrates the introduction of hybrid d–f block complex salts of the type M(II)–Ce(IV) and their charge-transport behaviour.
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Datum: 15.12.2021


Luminescent chromium(0) and manganese(I) complexes

Dalton Trans., 2022, 51,1297-1302
DOI: 10.1039/D1DT03763C, Frontier
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Christina Wegeberg, Oliver S. Wenger
In this Frontier article, recently discovered chromium(0) and manganese(I) complexes emitting from metal-to-ligand charge transfer (MLCT) excited states are highlighted.
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Datum: 15.12.2021


Ruthenium(II)-diphosphine complexes containing acylthiourea ligands are effective against lung and breast cancers

Dalton Trans., 2022, 51,1489-1501
DOI: 10.1039/D1DT02851K, Paper
Gregory F. Grawe, Katia M. Oliveira, Celisnolia M. Leite, Tamires D. de Oliveira, João Honorato, Antonio G. Ferreira, Eduardo E. Castellano, Marcia R. Cominetti, Rodrigo S. Correa, Alzir A. Batista
Acylthiourea ligands can form new ruthenium compounds that are effective against cancer cells.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 15.12.2021


Effect of an axial coordination environment on quantum tunnelling of magnetization for dysprosium single-ion magnets with theoretical insight

Dalton Trans., 2022, 51,1464-1473
DOI: 10.1039/D1DT03678E, Paper
Arpan Mondal, Sanjit Konar
Axial ligand fields control the relaxation time for quantum tunnelling of magnetization in dysprosium single ion magnets.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.12.2021


Polymerisation of styrene using pincer type amine functionalized azo aromatic complexes of Co(II) as catalysts

Dalton Trans., 2022, 51,1454-1463
DOI: 10.1039/D1DT02622D, Paper
Bappaditya Goswami, Manas Khatua, Subhas Samanta
Azo-aromatic complexes of Co(II), 1–3 have shown efficient polymerization of styrene upon activation of MMAO. The isolated polystyrenes have high Mw (32.9 to 144.0 kg mol−1) in a narrow range of Đ values (1.1–1.8) and good plastic/soft behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.12.2021


A6Mo2P4O19 (A = Rb, Cs) and Rb2MoP2O9: new molybdophosphates with distinct polyanionic configurations

Dalton Trans., 2022, 51,1481-1488
DOI: 10.1039/D1DT03756K, Paper
Maierhaba Abudoureheman, Juanjuan Zheng, Peng Wang, Bo Wei, Zhiyong Guo, Zhaohui Chen, Yanna Chen
Several new Mo(v) phosphates Rb2MoP2O9, Rb6Mo2P4O19 and Cs6Mo2P4O19 with dissimilar polyanionic configurations to be synthesized through a spontaneous nucleation method.
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Datum: 13.12.2021


Organic solvent-assisted co-precipitation synthesis of red-emitting K2TiF6:Mn phosphors with improved quantum efficiency and optimized morphology

Dalton Trans., 2022, 51,1378-1383
DOI: 10.1039/D1DT03679C, Paper
Bojana Milićević, Yingyuan Chen, Junhao Li, Miroslav D. Dramićanin, Jianbang Zhou, Mingmei Wu
The organic solvent-assisted (OSA) crystal growth of K2TiF6:Mn4+ red phosphors has been achieved and the morphology of the aimed crystals can be controlled and the emission efficiency can be enhanced by using the n-butanol-assisted co-precipitation route.
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Datum: 13.12.2021


MXene nanofibers confining MnOx nanoparticles: a flexible anode for high-speed lithium ion storage networks

Dalton Trans., 2022, 51,1423-1433
DOI: 10.1039/D1DT03718H, Paper
Ying Guo, Deyang Zhang, Zuxue Bai, Ya Yang, Yangbo Wang, Jinbing Cheng, Paul K. Chu, Yongsong Luo
A flexible MnOx-MXene/CNF negative electrode shows enhanced Li+ adsorption and electrical/ion transmission. The strong anchoring effect between MXene and MnOx results in extraordinary performance and cycling stability.
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Datum: 11.12.2021


Recent advances in externally controlled ring-opening polymerisations

Dalton Trans., 2022, 51,1241-1256
DOI: 10.1039/D1DT03471E, Perspective
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sandeep Kaler, Matthew D. Jones
Switchable catalysis is a powerful tool in the polymer chemist's toolbox as it allows on demand access to a variety of polymer architectures.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.12.2021


Reversible colour/luminescence colour changes of tetracyanoruthenium(II) complexes by sorption/desorption of water molecules in crystals

Dalton Trans., 2022, 51,1474-1480
DOI: 10.1039/D1DT03666A, Paper
Shingo Hattori, Tomoya Nagai, Akiko Sekine, Takuhiro Otsuka, Kazuteru Shinozaki
We report reversible vapochromic behaviour of tetracyanorutenium(II) complexes by the sorption/desorption of water molecules in crystal.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.12.2021


Investigations of the reactivity, stability and biological activity of halido (NHC)gold(I) complexes

Dalton Trans., 2022, 51,1395-1406
DOI: 10.1039/D1DT03528B, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Sina Katharina Goetzfried, Paul Kapitza, Caroline Marie Gallati, Anna Nindl, Monika Cziferszky, Martin Hermann, Klaus Wurst, Brigitte Kircher, Ronald Gust
The significance of the halido ligand (Cl, Br, I) in (NHC)gold(I) complexes in ligand exchange reactions, including the ligand scrambling to the bis(NHC)gold(I) complex 5, was evaluated by HPLC and discussed in relation to the biological activity in A2780 cell lines.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.12.2021


Accessible triplet excited states in the photoisomerization of allenes with extended conjugation

Dalton Trans., 2022, 51,1357-1363
DOI: 10.1039/D1DT03688B, Paper
Jonathan Álvarez-García, Ramón García-Lago, José Lorenzo Alonso-Gómez, Carlos Silva López, María Magdalena Cid
Triplet states play a key role in the photochemistry of Re(I) complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.12.2021


A metal-free hydroxyl functionalized quaternary phosphine type ionic liquid polymer for cycloaddition of CO2 and epoxides

Dalton Trans., 2022, 51,1303-1307
DOI: 10.1039/D1DT03232A, Communication
Wuying Zhang, Qian He, Yaju Chen, Rongchang Luo, Xiantai Zhou, Hongbing Ji
The Friedel–Crafts alkylation strategy was used to prepare a hypercrosslinked polymer catalyst, which showed superior performance towards the cycloaddition reaction of CO2 with epoxides.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.12.2021


Water-soluble sulfonated phosphorus(V) corrolazines and porphyrazines: the effect of macrocycle contraction and pyrazine ring fusion on spectral, acid–base and photophysical properties

Dalton Trans., 2022, 51,1364-1377
DOI: 10.1039/D1DT02453A, Paper
Svetlana S. Ivanova, Denis S. Salnikov, Gleb Knorr, Olesja Ledovich, Valerij Sliznev, Pavel Kubat, Veronika Novakova, Pavel A. Stuzhin
Water-soluble sulfophenyl substituted P(V) corrolazines are effective photosensitizers in aqueous solutions. Fluorescence quenching accompanying the acid ionization of the central P(OH)2 moiety can be used for the development of pH-sensors.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.12.2021


Heterobimetallic Pd/Mn and Pd/Co complexes as efficient and stereoselective catalysts for sequential Cu-free Sonogashira coupling–alkyne semi-hydrogenation reactions

Dalton Trans., 2022, 51,1344-1356
DOI: 10.1039/D1DT03757A, Paper
Reike Clauss, Saral Baweja, Dmitri Gelman, Evamarie Hey-Hawkins
A series of heterobimetallic PdII/MII complexes (MII = Mn, Co) were synthesised and tested as precatalysts for sequential Sonogashira coupling–alkyne semi-hydrogenation reactions to form Z-aryl alkenes in a one-pot fashion.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Reductively disilylated N-heterocycles as versatile organosilicon reagents

Dalton Trans., 2022, 51,1281-1296
DOI: 10.1039/D1DT03331J, Perspective
Padmini Sahoo, Moumita Majumdar
The reductively disilylated N-heterocyclic systems diligently give up electrons thereby demonstrating as versatile reagents in the salt-free reduction of transition metals, main-group halides, in organic transformations and in materials syntheses.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.11.2021


Phosphorescent NIR emitters for biomedicine: applications, advances and challenges

Dalton Trans., 2022, 51,1257-1280
DOI: 10.1039/D1DT03077A, Perspective
Pavel S. Chelushkin, Julia R. Shakirova, Ilya S. Kritchenkov, Vadim A. Baigildin, Sergey P. Tunik
This review describes the current state of the art in the chemistry of phosphorescent NIR emitters with a particular focus on their application in biomedicine as luminescent probes, sensors and theranostic agents.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 15.11.2021


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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