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Dalton Transactions

Current research articles..




The scientific journal Dalton Transactions embraces all aspects of the chemistry of inorganic and organometallic compounds, including biological inorganic chemistry, solid-state inorganic chemistry, application of physicochemical and computational techniques, new or improved experimental techniques and syntheses.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles in the field of inorganic chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Inorganica Chimica Acta,

 - Inorganic Chemistry,

 - Inorganic Chemistry Communications,

 - European Journal of Inorganic Chemistry,

 - Russian Journal of Inorganic Chemistry.



Dalton Transactions - Abstracts



Successive constructions of regular tetra-, hexa- and octanuclear microporous polyoxovanadates(III) for gas adsorptions

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01360F, Paper
Zhenlang Xie, Dongli An, Weizheng Weng, Zhao-Hui Zhou
Pyrazole-assisted tetranuclear microporous polyoxovanadates(III) (POVs) (NH4)2K2[V4(μ2-OH)4(ox)4(pz)4]·9H2O (1, ox = oxalate, pz = pyrazole) and (NH4)2Na2[V4(μ2-OH)4(ox)4(4-mpz)4]·7H2O (2, 4-mpz = 4-methylpyrazole) have been constructed in reduced media, along with their triazole neutral...
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Datum: 02.07.2022


A Microporous Zr6@Zr-MOF for the Separation of Xe and Kr

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01108E, Communication
Fua-An Guo, Kang Zhou, Jiaqi Liu, Xingyu Li, Hao Wang
We report here the self-assembly of a she-type zirconium-based metal-organic framework with discrete hexanuclear Zr-oxo clusters residing inside its pore windows. The overall structure features microporosity showing preferential adsorption of...
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Datum: 02.07.2022


Exploring the Structure Dependence of Metal-free Carbon Electrocatalysts on Zinc-based Metal-organic Framework Types

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01718K, Paper
Wenfang Si, Qianjie Xie, Ruiyi Zhang, Zheng Wang, Yehua Shen, Hiroshi Uyama
Metal-organic frameworks (MOFs) have widely used as precursor to derive carbon-based electrocatalysts for the oxygen reduction reaction (ORR), due to the high porosity and tunable chemical composition/structure. However, the influence...
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Datum: 01.07.2022


Sulfur-source-dependent phase-selective preparation of Cu3NiInSnS6 nanocrystals and their optical and magnetic properties

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01643E, Paper
Qinghuan Bian, Huanxi Liao, Changcun Tang, Kunjiao Li, Jiabao Wan, Yanhe Xiao, Baochang Cheng, Shuijin Lei
Multifunctional multinary metal chalcogenides have long been a research hotspot in the field of materials chemistry due to their rich composition, flexible structure, excellent properties and wide range of applications....
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Datum: 01.07.2022


Modifying the Internal Substituents of Self-Assembled Cages Controls their Molecular Recognition and Optical Properties

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01451C, Paper
Connor Z. Woods, Hoi-Ting Wu, Courtney Ngai, Bryce da Camara, Ryan R. Julian, Richard James Hooley
Self-assembled Fe4L6 cage complexes with variable internal functions can be synthesized from a 2,7-dibromocarbazole ligand scaffold, which orients six functional groups to the cage interior. Both ethylthiomethylether and ethyldimethylamino groups...
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Datum: 01.07.2022


Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag2SeO4: Combining experimental data and theoretical insights

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01057G, Paper
Ivo Mateus Pinatti, Ana Cristina Tello Mora, Paula F. S. Pereira, Aline B. Trench, Márcio Daldin Teodoro, Ieda Lucia Viana Rosa, Alberico da Silva, Elson Longo, Juan Andrés, A. Z. Simoes
A systematic theoretical and experimental study was carried out to find a relationship between photoluminescence emissions and photocatalytic activity of Ag2SeO4 obtained by different synthesis methods (sonochemistry, ultrasonic probe, coprecipitation...
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Datum: 01.07.2022


Luminescent early-late-hetero-tetranuclear group IV – Au(I) bisamidinate complexes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT00458E, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cedric Uhlmann, Thomas J. Feuerstein, Tim P. Seifert, André P. Jung, Michael T. Gamer, Ralf Köppe, Sergei Lebedkin, Manfred M. Kappes, Peter W. Roesky
Reaction of the ethynyl compound [{HCCC(NDipp)2}2Au2] with n-BuLi followed by Cp2MCl2 (M = Ti, Zr) leads to two group IV – gold(I) heterobimetallic complexes with different photoluminescence properties.
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Datum: 01.07.2022


Tetra germanium nonaselenide enwrapped with reduced graphene oxide and functionalized carbon nanotubes (Ge4Se9/RGO/FCNTs) hybrids for improved energy storage performances

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01637K, Paper
Jogendra Nath Behera, Jiban Krushna Das, Abhisek Padhy, Smrutimedha Parida, Radha Madhab Pathi
The development of multifunctional layered semiconductor materials and their carbonaceous hybrids as acceptable positive electrode materials for supercapacitor application is the key of interest. Ternary germanium selenide (Ge4Se9) with reduced...
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Datum: 01.07.2022


Recent Developments on the Transformation of CO2 Utilising Ligand Cooperation and Related Strategies

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01609E, Perspective
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
A Ramaraj, Issam Abdalghani, Rosenildo Correa Da Costa, Gareth Richard Owen
A portfolio of value-added chemicals, fuels and building block compounds can be envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities of CO2, however, present a...
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Datum: 01.07.2022


An S-scheme α-Fe2O3/Cu2O photocatalyst for an enhanced primary amine oxidative coupling reaction under visible light

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT00646D, Paper
Zhen Li, Shan Ye, Ping Qiu, Xiaoyuan Liao, Yue Yao, Jingzhao Zhang, Yan Jiang, Shuxiang Lu
Photoredox catalysis under visible light has been recorded as a potential and reassuring recipe for organic synthesis.
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Datum: 01.07.2022


One-pot Production of Sea Urchin-Like Alloy Electrocatalyst for Oxygen Electro-Reduction Reaction

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01268E, Paper
Hau Quoc Pham, Tai Thien Huynh
Designing a cost-effective catalyst with high performance towards oxygen electro-oxidation reaction (ORR) is of key interest for the development of green energy storage and conversion technologies. We report herein a...
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Datum: 01.07.2022


N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Vanadium(III) and Vanadium(V)

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01250B, Paper
Günther Horrer, Sophie Mann, Ivo Krummenacher, Holger Braunschweig, Udo Radius
[VCl3(THF)3] offers a convenient entrance point into the chemistry of carbene stabilized V(III) complexes. Herein we report the paramagnetic mono- and biscarbene complexes [VCl3(cAACMe)] 1, [VCl3(cAACMe)(THF)] 1(thf), [VCl3(IMes)] 2, [{VCl2(IiPrMe)(µ-Cl)}2]...
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Datum: 01.07.2022


New strategies towards advanced CT contrast agents. Development of neutral and monoanionic sulfur-bridged W(V) dimeric complexes

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01470J, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hristo Plamenov Varbanov, Toma N Glasnov, Ferdinand Belaj, Simon Herbert, Thomas Brumby, Nadia Carmen Moesch-Zanetti
Multinuclear tungsten complexes are intriguing candidates for new contrast media that can provide substantial improvements in CT imaging diagnostics. Herein, we present a ligand strategy, based on amino acids, and...
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Datum: 30.06.2022


Accelerating Electrochemically Catalyzed Nitrogen Reductions on Metalloporphyrin-Mediated Metal-Nitrogen-Doped Carbon (M-N-C) Catalysts

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01258H, Paper
Xinyi Dong, Weihua Zhu, Xu Liang
Herein, a series of transition metal coordinated metalloporphyrin-mediated M-N-C catalysts with single and dual metal atoms were prepared and characterized. Interestingly, these M-N-C catalysts exhibit accelerating N2 reduction behaviors through...
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Datum: 30.06.2022


Rapid one–pot synthesis of magnetically separable Fe3O4–Pd nanocatalysts: a highly reusable catalyst for the Suzuki–Miyaura coupling reaction

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01422J, Paper
Xiangyun Xiao, Sunhee Lee, Hyeonjong Ma, Jiwoong Yang, Won-Sik Han, Taekyung Yu
Heterogeneous catalysts comprising noble metals and magnetic materials allow a straightforward separation from a reaction using an external magnet and recovery easily. In this study, we synthesized magnetic Fe3O4–Pdn hybrid...
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Datum: 30.06.2022


A novel symmetric pyrazine (pyz)-bridged uranyl dimer [UO2Cl3(H2O)(Pyz)0.5]22-: Synthesis, structural and computational analysis

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01486F, Paper
Nicole M. Byrne, Mark Hopkins Schofield, Chris Cahill
Herein we report on the synthesis of (C4H6N)2[UO2Cl3(H2O)(Pyz)0.5]2.2H2O which features a novel pyrazine-bridged uranyl dimer, [UO2Cl3(H2O)(Pyz)0.5]22-. A rigorous computational and experimental analysis of this compound was performed to fully explore...
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Datum: 30.06.2022


Inside or outside the box? Effect of substrate location on coordination-cage based catalysis

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01713J, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atena B. Solea, Burin Sudittapong, Christopher G. P. Taylor, Michael D. Ward
In this work we compare and contrast the hydrolysis of two different aromatic esters using an octanuclear cubic Co8 coordination cage host as the catalyst. Diacetyl fluorescein (DAF) is too...
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Datum: 30.06.2022


Eldfellite structured NaCr(SO4)2: A potential anode for Rechargeable Na-ion and Li-ion batteries

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT00573E, Paper
Preetam Singh, Saurabh Kumar, Rakesh Mondal, Rajiv Prakash
Abstract: Recent global concern over continuously increasing air pollution and related health risks due to automobile exhaust has shifted our attention towards green transportation. Recent decades are a witness to...
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Datum: 30.06.2022


Two-Dimensional Metal–Organic Layers Constructed from Hf6/Hf12-oxo Clusters and Trigonal Pyramidal Phosphine Oxide Ligand

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01239A, Communication
Jiawei Chen, Zhi Ye, Peican Chen, Huihui Hu, Shuhong Zhang, Han Xu, Lingyun Cao, Cheng Wang
Metal–organic layer (MOL), a category of two-dimensional materials, has attracted wide interest due to its molecular tunability and the ease for surface modification. Herein we reported the synthesis and structural...
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Datum: 29.06.2022


Cyclometalated Iridium(III) Complex of a 1,2,3-Triazole-based Ligand for Highly Selective Sensing of Pyrophosphate Ion

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01634F, Paper
Snehadrinarayan Khatua, Monosh Rabha, Bhaskar Sen, Sanjoy Kr Sheet, Kripamoy Aguan
A new cyclometalated Ir(III) complex of methylene bridged benzimidazole substituted 1,2,3-triazole methanol ligand has been synthesized for the photoluminescent detection of pyrophosphate (H2P2O72-) anion. The solution structure of 1[PF6] was...
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Datum: 29.06.2022


Closing the loop in the synthesis of heteroscorpionate-based aluminium helicates. Catalytic studies for cyclic carbonate synthesis.

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01645A, Paper
Agustin Lara, José Antonio Castro-Osma, Michael North, Miguel Ángel Gaona, Felipe de la Cruz-Martínez, Ana María Rodríguez, María del Prado Caballero Espinosa, Enrique Francés-Poveda, Antonio Rodríguez Diéguez
Novel polynuclear helical aluminium complexes supported by bulky heteroscorpionate ligands have been developed and characterised. The use of bulkier ligands has allowed the isolation of unprecedented intermediates for the preparation...
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Datum: 29.06.2022


Water-soluble ruthenium complex-pyrene dyads with extended triplet lifetimes for efficient energy transfer applications

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01157C, Paper
Arne Sell, Julius C. Wetzel, Matthias Schmitz, A. Wouter Maijenburg, Georg Woltersdorf, Robert Naumann, Christoph Kerzig
Long triplet lifetimes of excited photosensitizers are essential for efficient energy transfer reactions in water, given that the concentrations of dissolved oxygen and suitable acceptors in aqueous media are typically...
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Datum: 28.06.2022


Visible-Light NO-Photolysis of Ruthenim Nitrosyl Complexes with N2O2 Ligands Bearing π-Extended Rings and their Photorelease Dynamics

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01019D, Paper
Minyoung Kim, Seongchul Park, Dayoon Song, Dohyun Moon, Youngmin You, Manho Lim, Hong-In Lee
NO photorelease and its dynamics of two {RuNO}6 complexes, Ru(salophen)(NO)Cl (1) and Ru(naphophen)(NO)Cl (2), with salen-type ligands bearing π-extended systems (salophenH2 = N,N'-(1,2-phenylene)-bis(salicylideneimine) and naphophenH2 = N,N'-1,2-phenylene-bis(2-hydroxy-1-naphthylmethyleneimine)) were investigated. NO...
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Datum: 28.06.2022


Diastereoselectively self-sorted low-symmetry binuclear metallomacrocycle and trinuclear metallocage

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01571D, Paper
Srabani Srotoswini Mishra, Dillip Kumar Chand
A pyridine/aniline appended unsymmetrical bis-monodentate ligand N-(3-aminophenyl)nicotinamide, Lun is synthesized by condensation of nicotinic acid with excess of m-phenylene diamine. Low-symmetry binuclear complex of Pd2L'2Lun2 type and extremely rare trinuclear...
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Datum: 28.06.2022


Cationic Palladium(II)-Indenyl complexes bearing phosphines as ancillary ligands: synthesis, study of indenyl amination and anticancer activity

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01821G, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Thomas Scattolin, Fabiano Visentin, Enrica Bortolamiol, Isabella Caligiuri, Flavio Rizzolio, Luigi Cavallo, Ziyun Zhang, Nicola Demitri, Francesco Fama
The reactivity of palladium(II) indenyl derivatives and their applications are topics relatively little studied, though in recent times these compounds have been used as pre-catalysts able to promote challenging cross-coupling...
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Datum: 28.06.2022


New Alkaline-Earth Amidosulfates and their Unexpected Decomposition to S4N4

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01380K, Paper
Peter Gross, Yue Zhang, Lkhamsuren Bayarjargal, Bjoern Winkler, Henning A. Höppe
The amidosulphates Mg(NH 2 SO 3 ) 2 · 4 H 2 O (P2 1 /c), Mg(NH 2 SO 3 ) 2 · 3 H 2 O (P ̄), Ca(NH...
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Datum: 28.06.2022


Sonogashira coupling of the ethynyl monocarborane [CB11H11-12-CCH]−

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01048H, Paper
Fan Liu, Tao Chen, Kang Zhang, Tao Jiang, Jiyong Liu, Simon Duttwyler
The Sonogashira coupling of 12-ethynyl monocarborane with bromoarenes provides access to aryl carboranyl alkynes with high functional group tolerance.
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Datum: 28.06.2022


Spin transitions in ferric catecholate complexes mediated by outer-sphere counteranion

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01207C, Paper
Maxim Chegerev, Oleg Demidov, Pavel Nikolaevich Vasilyev, N. N. Efimov, Stanislav Petrovich Kubrin, Andrey Starikov, Valery Vlasenko, Alexandr Vladimirovich Piskunov, Svetlana Shapovalova, Alexander A. Guda, Yury V. Rusalev, Alexander V Soldatov
The family of salt-like ferric catecholate complexes 14 bearing disubstituted 3,6-di-tert-butyl-catecholate ligand (3,6-DBCatH2) and tetradentate tris(2-pyridylmethyl)amine (TPA) was prepared and their spin transitions were investigated. Variation of the outer-sphere counteranion...
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Datum: 27.06.2022


Ruthenium(II) complexes with phosphonate-substituted 1,10-phenanthroline ligands: synthesis, characterization and use in organic photocatalysis

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01364A, Paper
Gleb V. Morozkov , Anton S. Abel, Mikhail A. Filatov, Sergey E Nefedov, Vitaly Alexandrovich Roznyatovsky, Andrei Vladimirovich Cheprakov, Alexander Yu. Mitrofanov, Ilia S. Ziankou , Alexei Averin, Irina P Beletskaya, Julien Michalak , Christophe Bucher, Laurent Bonneviot, Alla Bessmertnykh-Lemeune
Ru(II) complexes with polypyridyl ligands play a central role in the development of photocatalytic organic reactions. This work is aimed at the structural modification of such complexes to increase their...
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Datum: 27.06.2022


Significant enhancement of scintillation performance by inducing oxygen vacancy in alkali metal ions (A+ = Li+, Na+, K+) incorporated (Lu, Sc)BO3: Ce

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01432G, Paper
Yun-Ling Yang, Jia-Xuan Chen, Fan Guo, Meng Huang, Shan-Shan Liang, Qian-Li Li, Jianfeng Hu, Jing-Tai Zhao, Xingyu Gao, Ya-Nan Fu, Hui Lin, Shuai Cheng, Zhi-Jun Zhang
The incorporation of Sc3+ can stabilize calcite phase LuBO3: Ce3+ for growing large-sized single crystals, but leads to the significant degradation of scintillation performance. In the present work, alkali metal...
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Datum: 27.06.2022


Hierarchical NiFeV Hydroxide Nanotubes: Synthesis, Topotactic Transformation and Electrocatalysis towards Oxygen Evolution Reaction

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01235A, Paper
Qingying Li, Xiaohe Liu, Zhicheng Zheng, Gen Chen, Renzhi Ma, Hao Wan
Electrocatalytic overall water splitting is a sustainable approach to realizing the clean production of hydrogen energy, however, is mainly hindered by the sluggish kinetics of oxygen evolution reaction (OER) half...
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Datum: 27.06.2022


A chemical perspective on the clinical use of platinum-based anticancer drugs

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01875F, Perspective
Shoohb Alassadi, Michelle J. Pisani, Nial Wheate
Platinum drugs have been a mainstay of cancer chemotherapy since the introduction of cisplatin in the 1970s. Since then, carboplatin and oxaliplatin have been approved world-wide and nedaplatin, lobaplatin, heptaplatin,...
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Datum: 27.06.2022


Intrinsic reactivity of [5-1,3-(Me3Si)2C5H3]2U(4-C4Ph2) in small molecule activation

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01730J, Paper
Shichun Wang, Yi Heng, Tongyu Li, Dongwei Wang, Guohua Hou, Guofu Zi, Marc D Walter
The uranium metallacyclocumulene, [5-1,3-(Me3Si)2C5H3]2U(4-C4Ph2) (3) was isolated from the reaction mixture containing [5-1,3-(Me3Si)2C5H3]2UCl2 (1), potassium graphite (KC8) and 1,4-diphenylbutadiyne (PhCC-CCPh) in good yield. The reactivity of 3 towards various small...
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Datum: 27.06.2022


High yield of a variety of silicon-boron radicals and their reactivity

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01318E, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Herbert W Roesky, Mohd Nazish, Yi Ding, Christina M. Legendre, Arun Kumar, Nico Graw, Brigitte Schwederski, Regine Herbst-Irmer, Parvathy P, Pattiyil Parameswaran, Dietmar Stalke, Wolfgang Kaim
Herein we report stable silicon-boron radicals of composition LSi(NMe2)-B(Br)Tip (1), LSi(NMe2)-B(I)Tip (2) LSi(tBu)-B(I)Tip (3) [L=PhC(NtBu)2]. They were prepared in high yield using a one-pot reaction of LSiR, X2BTip, and KC8...
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Datum: 25.06.2022


Low temperature thermal ALD process for nickel utilizing dichlorobis(triethylphosphine)nickel(II) and 1,4-bis(trimethylgermyl)-1,4-dihydropyrazine

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01347A, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anton Vihervaara, Timo Hatanpää, Kenichiro Mizohata, Mykhailo Chundak, Georgi Popov, Mikko Ritala
In this work, we developed a new ALD process for nickel metal from dichlorobis(triethylphosphine)nickel(II) (NiCl2(PEt3)2) and 1,4-bis(trimethylgermyl)-1,4-dihydropyrazine ((Me3Ge)2DHP). A series of phosphine adducts of nickel and cobalt halides was synthesized...
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Datum: 25.06.2022


Encapsulating electron-deficient dyes into Metal-Organic Capsules To Achieve High Reduction Potentials

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01166B, Communication
Jiayou Yuan, Zhong Wei, Keshen Shen, Yang Yang, Mingxu Liu, Xu Jing, Chunying Duan
The design of artificial supramolecular systems that mimic the structure and functionality of natural enzymes to achieve efficient chemical conversions is a promising subject. In this work, we assembled a...
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Datum: 24.06.2022


Phase-sensitive radioluminescent and photoluminescent features in Tm3+-doped yttrium tantalates for cyan and white light generation

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01455F, Paper
Hayra do Prado Labaki, Fábio José Caixeta, Natasha Policei Marques, Eder Jose Guidelli, Rogéria Rocha Gonçalves
Radioluminescence and visible photoluminescent tunability features from a single Tm3+-doped yttrium tantalate phosphor prepared by a soft sol–gel method designed to afford cubic Y3TaO7 and monoclinic M’-YTaO4 crystalline phases are...
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Datum: 24.06.2022


Phosphorus-doped potassium peroxyniobate electrocatalyst with enriched oxygen vacancy boosts electrocatalytic nitrogen reduction to ammonia

Dalton Trans., 2022, Accepted Manuscript
DOI: 10.1039/D2DT01501C, Paper
Shuhui Fan, Fei Zhao, Xuansheng Wang, Qi Wang, Qiang Zhao, Jinping Li, Guang Liu
Electrochemical ammonia synthesis is an environmentally friendly method for ammonia production, but still impeded by the bottleneck of N2 activation and challenging hydrogen evolution reaction (HER). Rational design and develop...
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Datum: 24.06.2022


Modulating the reactivity of phosphanylidenephosphoranes towards water with Lewis acids

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01575G, Paper
Fabian Dankert, Malte Fischer, Christian Hering-Junghans
Prone to manipulations: Phospha-Wittig reagents react with water to give primary phosphine oxides, which form O-coordinated Lewis acid-base adducts. Adding the Lewis acid first and water in a second step afforded protio-phosphino-phosphonium cations.
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Datum: 23.06.2022


Informing our understanding of the copper–cuprizone reaction with computational chemistry

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01476A, Paper
M. Jake Pushie, Graham N. George
The coordination chemistry of copper–cuprizone has presented considerable challenges for over 70 years. Using computational chemistry we elucidate key events in copper–cuprizone complex formation, including the asymmetric hydrolysis of cuprizone.
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Datum: 23.06.2022


Generalized synthesis of NaCrO2 particles for high-rate sodium ion batteries prepared by microfluidic synthesis in segmented flow

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D1DT04333A, Paper
Do-Hyun Quak, Massih Sarif, Phil Opitz, Martin Lange, Olga Jegel, Dang Hieu Pham, Martha Koziol, Leon Prädel, Mihail Mondeshki, Muhammad Nawaz Tahir, Wolfgang Tremel
Ternary oxides NaMO2 (M = Cr, Fe, Co, Al) were prepared by microfluidic processing in water-in-oil emulsions followed by a short annealing step.
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Datum: 23.06.2022


Synthesis and structural characterization of copper–cuprizone complexes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01475K, Paper
M. Jake Pushie, Kelly L. Summers, Kurt H. Nienaber, Ingrid J. Pickering, Graham N. George
The chemistry of copper with cuprizone has challenged chemists for over 70 years. We characterize the classical ‘blue’ product, containing Cu(III) and hydrolyzed cuprizone, and a green multimeric Cu(II) product, containing unhydrolyzed cuprizone.
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Datum: 23.06.2022


Pushing steric limits in osmium(IV) tetraaryl complexes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01706G, Paper
Joseph M. Parr, Clarissa Olivar, Thomas Saal, Ralf Haiges, Michael S. Inkpen
Air-stable osmium(IV) tetraaryl complexes are obtained using the precursor (Oct4N)2[OsBr6] in yields of 5–73% that correlate with ligand steric bulk. Os(mesityl)4 exhibits a particularly distorted geometry and an unusual 1+/2+ solution redox feature.
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Datum: 22.06.2022


Unsaturated amido-substituted six-vertex mixed silicon germanium clusters

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01746F, Paper
Joschua Helmer, Jörn Droste, Michael Ryan Hansen, Alexander Hepp, Felicitas Lips
Mixed silicon and germanium clusters SixGe6−x{N(SiMe3)Dipp}4 1–3 (x = 3.7, 3.1, 2.1) with amido-substituents and two ligand-free Ge atoms were obtained in co-reductions using {N(SiMe3)Dipp}SiBr3 and {N(SiMe3)Dipp}GeBr3 in three different ratios.
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Datum: 22.06.2022


Organopnictogen(III) bis(arylthiolates) containing NCN-aryl pincer ligands: from synthesis and characterization to reactivity

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01436J, Paper
Gabriel Duneş, Albert Soran, Cristian Silvestru
A family of new hypercoordinated organopnictogen(III) di(thiolates), RPn(SC6H3Me2-2,6)2 (Pn = Sb, Bi; R = NCN-pincer ligand), has been prepared and their reactivity towards chalcogens and iodine has been investigated.
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Datum: 22.06.2022


Interfacial engineered RDX/TATB energetic co-particles for enhanced safety performance and thermal stability

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01421A, Paper
Yanzhou Qu, Wen Qian, Jianhu Zhang, Feiyan Gong, Zhengfeng Xie, Zhijian Yang, Fude Nie, Xu Zhao
Interfacial engineered energetic co-particles exhibited ultralow mechanical sensitivity and enhanced thermal stability, providing an effective strategy to improve the thermal and mechanical safety performance of an explosive.
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Datum: 21.06.2022


GaIIItriarylcorroles with push–pull substitutions: synthesis, electronic structure and biomedical applications

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01262F, Paper
Yingjie Niu, Lin Wang, Yingxin Guo, Weihua Zhu, Rodah C. Soy, Balaji Babu, John Mack, Tebello Nyokong, Haijun Xu, Xu Liang
Two GaIIItriarylcorroles with carbazole substitutions at 10-positions were synthesized, characterized, and their biomedical propeties were also investigated.
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Datum: 21.06.2022


Crystal-field induced tuning of luminescence properties of Na3GaxAl1−xF6:Cr3+ phosphors with good thermal stability for NIR LEDs

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01559E, Paper
Jianbang Zhou, Pengyun Chen, Junhao Li, Mingming Yang, Wei Jiang, Qiuhong Zhang, Haiyong Ni, Jiansheng Huo
The crystal field, PL intensity, peak position and FWHM of Cr3+-activated Na3GaxAl1−xF6:Cr3+ phosphors can be well controlled by changing the Ga/Al ratio.
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Datum: 21.06.2022


A lanthanide–tellurium heterometal encapsulated sandwich-type heteropolyoxoniobate with a 3D pcu-type hydrogen-bonded network

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01472F, Paper
Rong-Da Lai, Hui-Lin Feng, Yan-Qiong Sun, Xin-Xiong Li, Shou-Tian Zheng
A 3D Eu-incorporated niobictellurate supramolecular framework with pcu topology is constructed from a sandwich-type cluster [Ln(H2O)3Te6Nb18O64(OH)4]15− and copper–amine complexes with proton conduction and water vapor adsorption properties.
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Datum: 21.06.2022


A hierarchical CoMoO4@CoFe-LDH heterostructure as a highly effective catalyst to boost electrocatalytic water oxidation

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01257J, Paper
Liang Tian, Qiangqiang Wang, Yuyang Li, Xiang Ren, Qin Wei, Dan Wu
A hierarchical CoMoO4@CoFe-LDH/NF heterostructure is constructed as an efficient catalyst for the oxygen evolution reaction. In alkaline solution, it only needs 245 mV to drive the process at 10 mA cm−2 and long-term stability for 47 h.
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Datum: 20.06.2022


Acceptorless dehydrogenation of alcohols to carboxylic acids by palladium nanoparticles supported on NiO: delving into metal–support cooperation in catalysis

Dalton Trans., 2022, 51,9922-9934
DOI: 10.1039/D2DT01311H, Paper
Krisangi Bordoloi, Gauravjyoti D. Kalita, Pankaj Das
Pd nanoparticles (NPs) supported on NiO as an efficient heterogeneous catalyst for acceptorless dehydrogenation of primary alcohols to carboxylic acids with a low catalyst loading.
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Datum: 20.06.2022


Cellular imaging properties of phosphorescent iridium(III) complexes substituted with ester or amide groups

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01551J, Paper
Peiling Dai, Jiangshan Li, Man Tang, Dong Yan, Zihan Xu, Yonghua Li, Zejing Chen, Shujuan Liu, Qiang Zhao, Kenneth Yin Zhang
A phosphorescent iridium(III) complex substituted with two ester groups revealed whole-cell staining. The nuclear uptake of the complex was mediated by clathrin and microtubules. The nuclear uptake efficiency was related to the cell division cycle.
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Datum: 17.06.2022


The surface structure, stability, and catalytic performances toward O2 reduction of CoP and FeCoP2

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01408D, Paper
Mengru Huang, Chunyan Sun, Xiangrui Zhang, Peijie Wang, Shusheng Xu, Xue-Rong Shi
CoP and FeCoP2 exhibit a similar equilibrium crystal shape and facet-dependent activity toward the O2 reduction reaction, but the activity varies.
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Datum: 16.06.2022


Synthesis and characterization of Pd/NHCF complexes with fluorinated aryl groups

Dalton Trans., 2022, 51,9843-9856
DOI: 10.1039/D2DT00892K, Paper
Darya O. Prima, Roman O. Pankov, Alexander Yu. Kostyukovich, Mikhail E. Minyaev, Julia V. Burykina, Valentine P. Ananikov
The series of novel Pd/NHCF complexes were synthesized via a straightforward approach from fluorine-containing anilines. Computational and structural studies were performed to assess the effect of fluorine on the Pd–NHC bond.
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Datum: 16.06.2022


Synthesis and single crystal X-ray study of phenylselenyl embedded coumarin-based sensors for selective detection of superoxide

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01079H, Paper
Gauri S. Malankar, Divyesh S. Shelar, Ray J. Butcher, Sudesh T. Manjare
Coumarin containing phenylselenyl based probes (4 and 5) for selective and sensitive detection of superoxide. In single crystal X-ray structure of probe 4, phenylselenide group is parallel to the coumarin while in probe 5 it is perpendicular.
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Datum: 16.06.2022


5d → 4f transition of a lanthanide-activated MGa2S4 (M = Ca, Sr) semiconductor for mechanical-to-light energy conversion mediated by structural distortion

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT00883A, Paper
Xianhui Zhang, Dong Yang, Shaofan Wu, Xieming Xu, Ronghua Ma, Dengfeng Peng, Zhilin Wang, Shuaihua Wang
A new piezophotonic chalcogenide ML host family MGa2S4 (M = Ca, Sr) has been developed, which shows high efficiency mechanical-to-light conversion activated by lanthanide ions originating from structural distortion.
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Datum: 15.06.2022


Triphenylamine-containing imine-linked porous organic network for luminescent detection and adsorption of Cr(VI) in water

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01046A, Communication
Man Wang, Han-Shu Li, Xin Ding, Lizan Jiang, Pengyan Wu, Ruiting Zheng, Guoyue Bao, Guoliang Liu, Jian Wang
An imine-linked porous organic network can be used as a turn-off luminescent sensor for the detection and adsorption of Cr(VI) (CrO42− and Cr2O72−) in water.
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Datum: 15.06.2022


Effective high-throughput screening of two-dimensional layered materials for potential lithium-ion battery anodes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01769E, Paper
Chunmei Tang, Cheng Wang, Yu Huang, Jiangfeng Gong
Lithium-ion batteries (LIBs) are considered the promising next-generation advanced energy storage devices.
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Datum: 14.06.2022


Review of metal oxides as anode materials for lithium-ion batteries

Dalton Trans., 2022, 51,9584-9590
DOI: 10.1039/D2DT01415G, Frontier
Jiakai Du, Qingmeng Li, Jiali Chai, Lei Jiang, Qianqian Zhang, Ning Han, Wei Zhang, Bohejin Tang
Lithium-ion batteries with a stable circulation capacity, high energy density and good safety are widely used in automobiles, mobile phones, manufacturing and other fields.
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Datum: 14.06.2022


Utilizing the energy transfer mechanism to realize color tunable luminescence

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01259F, Paper
Shuang-Yin Zhu, Dan Zhao, Rui-Juan Zhang, Yan-Ping Fan, Wen Liu
By using the Bi3+ → Eu3+ energy transfer mechanism, color tunable luminescence from cyan, through white to orange, and finally to red can be successfully realized.
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Datum: 14.06.2022


In-site hydrogen bubble template method to prepare Ni coated metal meshes as effective bi-functional electrodes for water splitting

Dalton Trans., 2022, 51,9681-9688
DOI: 10.1039/D2DT00886F, Paper
Yucheng Dong, Shan Ji, Hui Wang, Vladimir Linkov, Rongfang Wang
From smooth metal mesh to metal mesh with porous structure after electrodeposition. The schematic diagram of electroplating cell and bubble template method reflects the experimental method of this study.
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Datum: 13.06.2022


Fluorinated click-derived tripodal ligands drive spin crossover in both iron(II) and cobalt(II) complexes

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01005D, Paper
Maite Nößler, David Hunger, Nicolás I. Neuman, Marc Reimann, Felix Reichert, Mario Winkler, Johannes Klein, Tobias Bens, Lisa Suntrup, Serhiy Demeshko, Jessica Stubbe, Martin Kaupp, Joris van Slageren, Biprajit Sarkar
A fluorophenyl-substituted ligand drives complete and partial spin-crossover in Fe(II) and Co(II) complexes, respectively.
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Datum: 13.06.2022


TiO2 supported cobalt oxide for olefin epoxidation reaction – characterization, catalytic activities and mechanism – using a DFT model

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01118B, Paper
Subhashree Mishra, Simon Watre Sangma, Mukesh Kumar Poddar, Rajaram Bal, G. P. Singh, Ratan Kumar Dey
Conversion of olefin to epoxide: Surface acidic sites of the catalysts allow the electron rich olefin to get adsorb on the catalyst and facilitate the bond cleavage to form epoxides.
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Datum: 11.06.2022


Magnetic orientation behavior of L-type zeolite with rare-earth elements under low magnetic field

Dalton Trans., 2022, 51,9601-9605
DOI: 10.1039/D2DT01374F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Tomomi Tabata, Anna Nagai, Motohide Matsuda
A finding that L-type zeolite ion-exchanged with magnetic rare-earth elements can be oriented in a 0.9 T magnetic field is presented.
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Datum: 10.06.2022


Energetic bimetallic complexes as catalysts affect the thermal decomposition of ammonium perchlorate

Dalton Trans., 2022, 51,9894-9904
DOI: 10.1039/D2DT00593J, Paper
Wen-Shuai Dong, Wen-Li Cao, Qamar-un-Nisa Tariq, Xiao-Wei Wu, Yong Hu, Chao Zhang, Jian-Guo Zhang
BMEP-1 and BMEP-2 have different three-dimensional structures and both have good catalytic effects on the decomposition of ammonium perchlorate.
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Datum: 09.06.2022


Covalent triflates as synthons for silolyl- and germolyl cations

Dalton Trans., 2022, 51,9836-9842
DOI: 10.1039/D2DT01446G, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wiebke Marie Wohltmann, Marc Schmidtmann, Thomas Müller
Not the antiaromatic heterol cations but their complexes with Lewis bases are obtained from covalent heterolyltriflates.
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Datum: 09.06.2022


Bichromophoric ruthenium(II) bis-terpyridine-BODIPY based photosensitizers for cellular imaging and photodynamic therapy

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01137A, Paper
Subhadeep Paul, Sanmoy Pathak, Somarupa Sahoo, Ram Chandra Maji, Utso Bhattacharyya, Dipankar Nandi, Akhil R. Chakravarty
Bichromophoric Ru(II) bis-terpyridine-BODIPY-based theranostic photosensitizers, developed as alternatives to tetrapyrrolic clinical photosensitizers, are studied for bioimaging and type-I/II photodynamic therapy.
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Datum: 09.06.2022


Cluster self-assembly and anion binding by metal complexes of non-innocent thiazolidinyl–thiolate ligands

Dalton Trans., 2022, 51,9611-9615
DOI: 10.1039/D2DT01339H, Communication
Madeline N. Riffel, Lukas Siegel, Allen G. Oliver, Emily Y. Tsui
Self-assembled thiolate-bridged trimers supported by a redox-active and proton-switchable ligand can hydrogen-bond anions.
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Datum: 08.06.2022


Bidirectional noninnocence of hinge-like deprotonated bis-lawsone on selective ruthenium platform: a function of varying ancillary ligands

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT01466A, Paper
Yogita Arya, Sudip Kumar Bera, José Luis Priego, Reyes Jiménez-Aparicio, Goutam Kumar Lahiri
Deprotonated bis-lawsone-based discreate ruthenium complexes beyond 3d metal/Ga-derived systems and their bidirectional (fractional) noninnocence have been highlighted.
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Datum: 08.06.2022


Combined experimental and theoretical investigation on the magnetic properties derived from the coordination of 6-methyl-2-oxonicotinate to 3d-metal ions

Dalton Trans., 2022, 51,9780-9792
DOI: 10.1039/D2DT00838F, Paper
Laura Razquin-Bobillo, Oier Pajuelo-Corral, Beñat Artetxe, Andoni Zabala-Lekuona, Duane Choquesillo-Lazarte, Antonio Rodríguez-Diéguez, Eider San Sebastian, Javier Cepeda
A structurally diverse family of coordination compounds with 6-methyl-2-oxonicotinate ligand and 3d metal ions is described. Magnetic properties are analysed from experimental and theoretical viewpoints.
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Datum: 08.06.2022


A porphyrin(2.1.2.1) bis-boron complex as a deep-red AIE luminophore induced by intermolecular F–π interaction

Dalton Trans., 2022, 51,9606-9610
DOI: 10.1039/D2DT01289H, Communication
Ningchao Liu, Xiaojuan Lv, Bentian Xiao, Daiki Kuzuhara, Peifeng Mei, Naoki Aratani, Hiroko Yamada, Fengxian Qiu, Jianming Pan, Songlin Xue
Four novel boron complexes were synthesized from saddle-shaped porphyrins(2.1.2.1) as new cyclic ligands. The saddle shape confers unique structure-dependent photophysical properties, especially in emission.
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Datum: 08.06.2022


Exploring the synergistic effect of alloying toward hydrogen evolution reaction: a case study of Ni3M (M = Ti, Ge and Sn) series

Dalton Trans., 2022, 51,9728-9734
DOI: 10.1039/D2DT00956K, Paper
Dong Zhang, Shen-Jing Ji, Yu Cao, Nian-Tzu Suen
In this work, we have demonstrated that one can control the intrinsic activity of Ni metal toward the hydrogen evolution reaction (HER) by simply alloying Ni with different elements (i.e. Ti, Ge or Sn).
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Datum: 07.06.2022


Sparfloxacin – Cu(II) – aromatic heterocyclic complexes: synthesis, characterization and in vitro anticancer evaluation

Dalton Trans., 2022, 51,9878-9887
DOI: 10.1039/D2DT00077F, Paper
Qi-Yan Liu, Yong-Yu Qi, Dai-Hong Cai, Yun-Jun Liu, Liang He, Xue-Yi Le
Two new ternary sparfloxacin copper(II) complexes induce apoptosis of Eca-109 cells through DNA damage and mitochondrial dysfunction.
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Datum: 07.06.2022


The role of permanent and induced electrostatic dipole moments for Schottky barriers in Janus MXY/graphene heterostructures: a first-principles study

Dalton Trans., 2022, 51,9905-9914
DOI: 10.1039/D2DT00584K, Paper
Yu-Qi Chen, Huan-Huan Zhang, Bo Wen, Xi-Bo Li, Xiao-Lin Wei, Wen-Jin Yin, Li-Min Liu, Gilberto Teobaldi
The Schottky barrier height (ESBH) is a crucial factor in determining the transport properties of semiconductor materials and it directly regulates the carrier mobility in opto-electronics devices.
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Datum: 06.06.2022


Separation of amino acids by selective sorption through reconstructive intercalation in calcined MgAl-layered double hydroxide

Dalton Trans., 2022, 51,9915-9921
DOI: 10.1039/D2DT01115H, Paper
Bhojaraj, C. Nethravathi, Michael Rajamathi
Mg–Al LDH shows high selectivity in the intercalation of amino acids with the order of preference being acidic > neutral > basic amino acids.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Inert cationic iridium(III) complexes with phenanthroline-based ligands: application in antimicrobial inactivation of multidrug-resistant bacterial strains

Dalton Trans., 2022, 51,9653-9663
DOI: 10.1039/D2DT00752E, Paper
Natalia Busto, Gloria Vigueras, Natalia Cutillas, Begoña García, José Ruiz
New iridium complexes with phenanthroline-based ligands show great potential as antimicrobials, being even more effective than the broad-spectrum antibiotic norfloxacin in Gram positive bacteria.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Understanding the thermodynamic, dynamic, bonding, and electrocatalytic properties of low-dimensional MgPSe3

Dalton Trans., 2022, 51,9689-9698
DOI: 10.1039/D2DT01194H, Paper
Tarik Ouahrani, Ayoub Daouli, Michael Badawi, Loubna Bendaoudi, Ángel Morales-García, Daniel Errandonea
In this work it is studied the potential use of novel two-dimensional perovskite-based MgPSe3 structures for technological applications in photocatalysis or in optoelectronics.
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Datum: 06.06.2022


Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe4S4 surrogates

Dalton Trans., 2022, 51,9748-9769
DOI: 10.1039/D2DT00419D, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Georgia R. F. Orton, Shishir Ghosh, Lucy Alker, Jagodish C. Sarker, David Pugh, Michael G. Richmond, František Hartl, Graeme Hogarth
Ferrocenyl diphosphine bridged diiron dithiolate complexes have been prepared and their redox properties investigated by CV and IR SEC supported by DFT calculations to give insight into their proton reduction and hydrogen oxidation activity.
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Datum: 06.06.2022


Thermally stimuli-responsive materials with transformable double channels of nonlinear optical and dielectric properties

Dalton Trans., 2022, 51,9857-9863
DOI: 10.1039/D2DT01413K, Paper
Zhi-Cheng Zhang, Tie Zhang, Pei-Zhi Huang, Ting Shao, Da-Wei Fu, Yi Zhang
Ordered–disordered motion of cations induces phase transitions accompanying dielectric and nonlinear optical dual channels.
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Datum: 04.06.2022


Enhanced luminescence of tris(carboxylato)uranyl(VI) complexes and energy transfer to Eu(III): a combined spectroscopic and theoretical investigation

Dalton Trans., 2022, 51,9803-9817
DOI: 10.1039/D2DT00849A, Paper
Satendra Kumar, S. Maji, K. Sundararajan
Enhanced luminescent tris(carboxylato) uranyl(VI) complexes are reported. In a very dilute mixture of [UO2(L)3] and Eu(III), energy transfer from uranyl to Eu(III) is observed.
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Datum: 03.06.2022


Construction of spin-crossover dinuclear cobalt(II) compounds based on complementary terpyridine ligand pairing

Dalton Trans., 2022, 51,9888-9893
DOI: 10.1039/D2DT00436D, Paper
Shu-Ya Zhang, Hui-Ying Sun, Run-Guo Wang, Yin-Shan Meng, Tao Liu, Yuan-Yuan Zhu
Three dinuclear cobalt(II) SCO-active compounds have been successively prepared employing the strategy of complementary terpyridine ligand pairing.
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Datum: 01.06.2022


N-Hydroxy–N-oxide photoinduced tautomerization and excitation wavelength dependent luminescence of ESIPT-capable zinc(II) complexes with a rationally designed 1-hydroxy-2,4-di(pyridin-2-yl)-1H-imidazole ESIPT-ligand

Dalton Trans., 2022, 51,9818-9835
DOI: 10.1039/D2DT01232D, Paper
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Sofia N. Vorobyova, Alexey S. Berezin, Victor F. Plyusnin, Dmitry Yu. Naumov, Natalia V. Pervukhina, Elena B. Nikolaenkova, Alexsei Ya. Tikhonov, Mark B. Bushuev
ESIPT-capable zinc(II) complexes with an ESIPT-ligand featuring spatially separated metal binding and ESIPT sites have been synthesized. The complexes undergo phototautomerization and show excitation wavelength dependent fluorescence.
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Datum: 01.06.2022


Trinuclear coordination assemblies of low-spin dicyano manganese(II) (S = 1/2) and iron(II) (S = 0) phthalocyanines with manganese(II) acetylacetonate, tris(cyclopentadienyl)gadolinium(III) and neodymium(III)

Dalton Trans., 2022, 51,9770-9779
DOI: 10.1039/D2DT01052F, Paper
Nikita R. Romanenko, Alexey V. Kuzmin, Maxim V. Mikhailenko, Maxim A. Faraonov, Salavat S. Khasanov, Evgeniya I. Yudanova, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev
Trinuclear assemblies {cryptand(K+)}2{MII(CN)2Pc·(MF)2}2−·nC6H4Cl2 (MII = MnII and FeII), where MF is Mn(II) acetylacetonate (S = 5/2), tris(cyclopentadienyl)gadolinium(III) (S = 7/2) or Nd(III) (S = 3/2) were obtained and studied.
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Datum: 01.06.2022


Treatment dependent sodium-rich Prussian blue as a cathode material for sodium-ion batteries

Dalton Trans., 2022, 51,9622-9626
DOI: 10.1039/D2DT01171A, Communication
Peiyuan Wang, Yonghao Li, Denggui Zhu, Feilong Gong, Shaoming Fang, Yonghui Zhang, Shumin Sun
Sodium ascorbate aqueous solution as the washing solution for the preparation of Prussian blue can inhibit the loss of Na+ and the oxidation of Fe2+, so as to achieve excellent electrochemical sodium storage performance.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2022


Electron coupled FeS2/MoS2 heterostructure for efficient electrocatalytic ammonia synthesis under ambient conditions

Dalton Trans., 2022, 51,9720-9727
DOI: 10.1039/D2DT01467J, Paper
Bo Wang, Chao Yan, Guangqing Xu, Xia Shu, Jun Lv, Jiewu Cui, Dongbo Yu, Zhiyong Bao, Yucheng Wu
The modulated electronic structure of FeS2/MoS2 nanosheets with ultrathin features (∼3 nm) was designed by a one-step hydrothermal process for efficient electrochemical nitrogen reduction reaction.
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Datum: 01.06.2022


Co-existence of five- and six-coordinate iron(II) species captured in a geometrically strained spin-crossover Hofmann framework

Dalton Trans., 2022, 51,9596-9600
DOI: 10.1039/D2DT01371A, Communication
Luonan Xu, Zixi Xie, Katrina A. Zenere, Jack K. Clegg, Elise Kenny, Nicole J. Rijs, Guy N. L. Jameson, Cameron J. Kepert, Benjamin J. Powell, Suzanne M. Neville
The use of an angular ligand drives the formation of an irregular Hofmann framework whereby 6-coordinate and rare 5-coordinate FeII species co-exist – the 6-coordinate species show a spin-crossover transition.
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Datum: 01.06.2022


An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality

Dalton Trans., 2022, 51,9591-9595
DOI: 10.1039/D2DT00743F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Joshua Csucker, Da Kyung Jo, Qaisar Nadeem, Olivier Blacque, Thomas Fox, Henrik Braband, Roger Alberto
We report the synthesis of novel rhenium and 99mTc ansa-arenophane complexes with bridging isoindolines. Inter-instead of intramolecular isoindoline formation leads to dinuclear macrocycles, one of which exhibits axial chirality.
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Datum: 01.06.2022


Construction of a chiral zinc–camphorate framework for enantioselective separation

Dalton Trans., 2022, 51,9627-9631
DOI: 10.1039/D2DT01221A, Communication
Chengfeng Zhu, Hongzhao Wang, Yongfei Mu, Ziwei Zhang, Lanjun Cheng, Tianfu Li, Yanming Fu, Xiang Wu, Yougui Li
A chiral zinc–camphorate framework with accessible chiral pores and multiple recognition sites is constructed. Acting as a recyclable chiral host, it can resolve a variety of racemic alcohols and epoxides with excellent enantioselectivities.
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Datum: 01.06.2022


Halo complexes of gold(I) containing glycoconjugate carbene ligands: synthesis, characterization, cytotoxicity and interaction with proteins and DNA model systems

Dalton Trans., 2022, Advance Article
DOI: 10.1039/D2DT00423B, Paper
Alfonso Annunziata, Giarita Ferraro, Maria Elena Cucciolito, Paola Imbimbo, Angela Tuzi, Daria Maria Monti, Antonello Merlino, Francesco Ruffo
New neutral Au(I) glycoconjugate carbene complexes show stability in aqueous solutions and interact with both DNA and protein model systems. Cytotoxicity studies demonstrate that the activity depends on the halide ancillary ligand.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2022


Phosphorus guiding palladium: [4 + 4] metallomacrocyclic PdII complex and self-assembly of heterometallic PdII/ZnII grid-type complex

Dalton Trans., 2022, 51,9632-9641
DOI: 10.1039/D2DT01176J, Paper
Reike Clauss, Evamarie Hey-Hawkins
The heteroditopic ligand 1 demonstrates a distinctive coordination behavior for the one-pot self-assembly of the heterometallic PdII/ZnII grid-type complex. Moreover, mono- or dinuclear and [4 + 4] metallomacrocyclic PdII complexes have been obtained.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 31.05.2022


An isolated doughnut-like molybdenum(V) cobalto-phosphate cluster exhibiting excellent photocatalytic performance for carbon dioxide conversion

Dalton Trans., 2022, 51,9616-9621
DOI: 10.1039/D2DT01276F, Communication
Cheng Li, Heng-Yu Jiang, Ji-Lei Wang, Run-Kun Kang, Hua Mei, Yan Xu
An isolated doughnut-like molybdenum(V) cobalto-phosphate cluster [Co@{Co16Mo16}] were successfully synthesized by hydrothermal method. And its photocatalytic CO2 performance is up to 6764.3 μmol g−1 h−1.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 31.05.2022


Growth behavior of Ir metal formed by atomic layer deposition in the nanopores of anodic aluminum oxide

Dalton Trans., 2022, 51,9664-9672
DOI: 10.1039/D2DT01358D, Paper
Lin Zhu, Geng-Lai Yang, Wen-Juan Ding, Yan-Qiang Cao, Wei-Ming Li, Ai-Dong Li
The growth behavior of ALD metallic Ir has been explored on various surfaces and in AAO nanopores systematically. The surface hydrophilicity and O2 partial pressure are crucial. The Ir infiltration depth into AAO follows a diffusion-limited model.
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Datum: 31.05.2022


Improvement of multiple attenuation characteristics of two-dimensional lamellar ferrocobalt@carbon nanocomposites as excellent electromagnetic wave absorbers

Dalton Trans., 2022, 51,9793-9802
DOI: 10.1039/D2DT01503J, Paper
Junjie Pan, Weijun Tu, Shanhong Ma, Xin Sun, Qiliang Zhao, Hongjiao Qu, Tao Wang, Jianping He
Two-dimensional lamellar carbon matrix ferrocobalt nanocomposites are prepared by the NaCl template recrystallization and the coordination reaction. The Co0.9Fe0.1/C exhibits a broadband microwave absorption of 5.4 GHz at a thickness of 1.65 mm.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 31.05.2022


Multinuclear Ni(II) and Cu(II) complexes of a meso 6 + 6 macrocyclic amine derived from trans-1,2-diaminocyclopentane and 2,6-diformylpyridine

Dalton Trans., 2022, 51,9735-9747
DOI: 10.1039/D2DT01329K, Paper
Janusz Gregoliński, Katarzyna Ślepokura, Julia Kłak, Maciej Witwicki
Tetra- and hexanuclear nitrate, chloride and sulphate Ni(II) and Cu(II) complexes have been synthesized from metal salts and 6 + 6 macrocycle. The ligand conformation in the complexes depends on the number of metal cations bound with the macrocycle.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2022


Ruthenium-based assemblies incorporating tetrapyridylporphyrin panels: a photosensitizer delivery strategy for the treatment of rheumatoid arthritis by photodynamic therapy

Dalton Trans., 2022, 51,9673-9680
DOI: 10.1039/D2DT00917J, Paper
Manuel Gallardo-Villagrán, Lucie Paulus, Jean-Louis Charissoux, David Yannick Leger, Pascale Vergne-Salle, Bruno Therrien, Bertrand Liagre
Ruthenium-based assemblies containing tetrapyridylporphyrin derivatives in their structures have been evaluated as photosensitizers to treat rheumatoid arthritis by photodynamic therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2022


New insights into progressive ligand replacement from [Ru2Cl(O2CCH3)4]: synthetic strategies and variation in redox potentials and paramagnetic shifts

Dalton Trans., 2022, 51,9708-9719
DOI: 10.1039/D2DT00909A, Paper
Almudena Inchausti, Aarón Terán, Alberto Manchado-Parra, Alessandra de Marcos-Galán, Josefina Perles, Miguel Cortijo, Rodrigo González-Prieto, Santiago Herrero, Reyes Jiménez-Aparicio
Synthesis of [Ru2Cl(Dp-FPhF)x(O2CCH3)4−x] compounds and the study of how electronic density variation of the Ru25+ core affects their physicochemical properties.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.05.2022


A new bis(thioether)-dipyrrin N2S2 ligand and its coordination behaviors to nickel, copper and zinc

Dalton Trans., 2022, 51,9699-9707
DOI: 10.1039/D2DT01282K, Paper
Tengdie Wu, Shen Wang, Yongxing Lv, Tianyue Fu, Jinhai Jiang, Xin Lu, Zhipeng Yu, Jie Zhang, Lianke Wang, Hongping Zhou
A new tetradentate N2S2 ligand containing a central dipyrrin donor functionalized with two thioether-substituted aryl units forms nickel, copper and zinc complexes with various coordination spheres.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.05.2022


Surface modification of hydroxyapatite nanoparticles for bone regeneration by controlling their surface hydration and protein adsorption states

Dalton Trans., 2022, 51,9572-9583
DOI: 10.1039/D2DT00969B, Perspective
Zizhen Liu, Shota Yamada, Yuichi Otsuka, Tania Guadalupe Peñaflor Galindo, Motohiro Tagaya
The control of the hydration and protein adsorption states on hydroxyapatite surface was systematically discussed, which is very important for the proper understanding of the controllable interfacial interactions between cells and bioceramics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2022


Ultrafast oxidative desulfurization of diesel fuel catalyzed by a polyoxometalate-based catalyst immobilized on functionalized Y-SBA-15

Dalton Trans., 2022, 51,9864-9877
DOI: 10.1039/D2DT00911K, Paper
Zhe Zhang, Jian Wang, Ming Chen, Tao Zhang, Biao Yang, Xuelian Peng, Du Tian, Linfeng Zhang, Huadong Wu, Jia Guo
The synthesized amphiphilic catalyst [Bmim]PMoO/Y-SBA-15 showed high catalytic activity in dibenzothiophene oxidative desulfurization, and the desulfurization rate reached 100% within 40 min under optimal conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.05.2022


Tuning of spin crossover properties in a series of mononuclear cobalt(II) complexes based on a macrocyclic tetradentate ligand and pseudohalide coligands

Dalton Trans., 2022, 51,9642-9652
DOI: 10.1039/D0DT02546A, Paper
Subrata Ghosh, Subramani Selvamani, Sujit Kamilya, Sakshi Mehta, Abhishake Mondal
Spin-state switching temperature has been significantly modified and tuned by the ligand field strength of coligands in mononuclear cobalt(II) complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.08.2020


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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