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Chemical Communications

Current research reports and chronological list of recent articles..




The international scientific journal Chemical Communicationsoffers urgent high quality communications from across the chemical sciences.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

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Additional research articles in the field of general chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Angewandte Chemie International Edition,

 - Chemical Monthly,

 - The Chemical Record,

 - Chemistry Central Journal,

 - Chemistry Letters,

 - Journal of the American Chemical Society,

 - Nature Chemistry.



Chemical Communications - Abstracts



Doubleisomerization / cycloisomerization / aromatization of 1-(allyloxy)-2-(cyclopropylmethyl)benzenes to give 2-ethyl-3-isopropylbenzofurans using multitasking single rhodium catalyst

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06163A, Communication
Yuta Sato, Tsuyoshi Matsuzaki, Tsunayoshi Takehara, Makoto Sako, Takeyuki Suzuki, Mitsuhiro Arisawa
Multitasking single-catalyst systems that allow multiple chemical transformations within a single reaction vessel are important for the development of eco-compatible chemistry. Here, we have developed a rhodium-catalyzed system that transforms...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Electrochemiluminescene detection of oxygen vacancies in layered double hydroxides

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05990D, Communication
Rui Zou, Ruyu Xie, Liren Wang, Yanjun Lin, Chao Lu
A novel electrochemiluminescence (ECL) platform was established to screen oxygen vacancies in layered double hydroxides (LDHs) by fabricating graphitic carbon nitride/LDH nanocomposites. The oxygen vacancy concentrations determined by the developed...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Engineering an Au Nanostar-based Liquid Phase Interfacial Ratiometric SERS platform with Programmable Entropy-driven DNA Circuits to Detect Protein biomarkers in clinical samples

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05975K, Communication
Guanli Fan, Xiaorong Gao, Shuling Xu, Qi Zhanf, Xia Li, Caifeng Dai, Qingwang Xue, Huaisheng Wang
Developing sensing platforms that simultaneously integrate high sensitivity and accuracy has been a promising but challenging task for protein biomarkers in clinical samples. Herein, we engineered an Au nanostar-based liquid...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Total Synthesis of (–)-Strempeliopine via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06278F, Communication
Yi An, Mengjuan Wu, Weijian Li, Yaling Li, Zhenzhen Wang, Yansong Xue, Pei Tang, Fen-Er Chen
Reported herein a concise and enantioselective total synthesis of Schizozygine alkaloids (–)-strempeliopine. This synthetic strategy features a palladium-catalyzed decarboxylative asymmetric allylic alkylation of N-benzoyl lactam to set up the absolute...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Structure and hydration of polyvinylpyrrolidone-hydrogen peroxide

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06047C, Communication
Luke I. Chambers, Dimitrii S. Yufit, Mark A Fox, Osama Musa, Jonathan W Steed
The structure of the commercially important polyvinylpyrrolidone-hydrogen peroxide complex can be understood by reference to the co-crystal structure of a hydrogen peroxide complex and its mixed hydrates of a two-monomer...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Metalla-phenalene complexes: synthesis, structure and aromaticity

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05855J, Communication
Yue Sun, Yan Zhou, Wei Bai, Li Yang, Yilun Wang
Metallaaromatics show a diversity of aromaticity. In this work, we report the synthesis and structural characterization of the first rhena-phenalene complexes. In addition to Hückel aromaticity and σ-aromaticity, pseudo π...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Catalytic Enantioselective Oxysulfenylation of o-Vinylanilides

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05835E, Communication
Arunachalam Kesavan, Pazhamalai Anbarasan
Tf2NH-assisted BINAM-derived thiophosphoramide catalysis has been accomplished for the enantioselective oxysulfenylation of o-vinylanilides with N-(aryl/alkylthio)imides. The developed reaction offers access to diverse substituted aryl/alkylthio tethered 3,1-benzoxazines in excellent yield and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.12.2021


Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05942D, Communication
Adrian Saura-Sanmartin, Aurelia Pastor, Alberto Martinez-Cuezva, Jose Berna
Self-templating two-component coupling reactions allowed the isolation of two threaded products with different molecular sizes: a lasso-type [1]rotaxane and a [c2]daisy chain rotaxane. Their distribution in the final reaction mixture...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Verification of Thermodynamic Theories of Strain-induced Polymer Crystallization

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC04134G, Communication
Chunbo Zhang, Chang Liu, Lei Wang, Ying Zhao, Guoming Liu, Dujin Wang
We studied the crystallization of nearly “homogeneous” polyethylene glycol (PEG) networks prepared by end-crosslinking of tetra-armed PEG. The influence of stretching ratio and strand length on the melting and crystallization...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Bisulfite-free and quantitative detection of 5-formylcytosine in DNA through qPCR

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05987D, Communication
Yafen Wang, Xiang Zhou, Jizhou Liu, Wei Yang, Xiong Zhang
An easily operated bisulfite-free method was presented to detect and quantify 5fC through quantitative real-time PCR. Malononitrile can selectively label 5fC under mild reaction conditions causing a C-to-T conversion that...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Free carbonate-based molecules in the electrolyte leading to severe safety concern of Ni-rich Li-ion batteries

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06694C, Communication
Nattanon Joraleechanchai , Ruttiyakorn Donthongkwa, Salatan Duangdangchote, Nutthaphon Phattharasupakun, Poramane Chiochan, Kan Homlamai, Montree Sawangphruk
The safety of Li-ion batteries is one of the most important factors, if not the most, determining their practical applications. We have found that free carbonate-based solvent molecules in the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Supramolecular capture of highly polar amidosquaraine dye in water with nanomolar affinity and large turn-on fluorescence

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05039G, Communication
Madushani Dharmarwardana, Janel M. Dempsey, Sasha Padilla-Coley, Tia S. Jarvis, Kejia Shi, Kirk M. Atkinson, Bradley D. Smith
A high-affinity supramolecular dye-capture system with “turn on” visible fluorescence is used to create a new assay for phospholipase-mediated liposome leakage.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Efficient full-spectrum driven ammonia synthesis over heterostructured TiO2 nanosheet arrays

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06489D, Communication
Xiaowei Mu, Shuang Cai, Rong Fu, Yumeng Qian, Ziye Pan, Lu Li
Here, we report that efficient photocatalytic ammonia synthesis was realized across the entire solar spectrum by using Ru modified anatase/TiO2(B) heterostructured nanosheet arrays. The superior NH3 production rates of 2004...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


The O/S Heteroatom effect of Covalent Triazine Framework for Photocatalytic Hydrogen Evolution

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05619K, Communication
Manying Liu, Kangni Yang, Zhenyang Li, Erchuang Fan, Like Zhang , Huafeng Fu, Yange Zhang, Zhi Zheng
The S/O heterocyclic covalent triazine frameworks (CTFs i.e., CTF – 7 and CTF - 8) were synthesized using thiophene and furan as building blocks, respectively. The hydrogen evolution rate of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Annulation–Retro-Claisen Cascade of Bifunctional Peroxides for the Synthesis of Lactone Natural Products

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06207G, Communication
Qianlan Xu, Jialin Li, Xuemin Li , Lin Hu
A new and highly efficient annulation–retro-Claisen cascade, which involves a [4+1] or [5+1] annulation of α-benzoylacetates with bielectrophilic peroxides and a subsequent debenzoylation process under mild basic conditions, has been...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Photoacoustic Measurement of Localized Optical Dichroism in Chiral Crystals

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05961K, Communication
Gil Otis, Matan Benyamin, Yitzhak Mastai, Zeev Zalevsky
In this communication, we present a novel method to measure local optical dichroism (OD) in opaque crystal powder suspensions using photoacoustic (PA) effect. Our method is based upon the novel...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Ethylene Oligomerization on Ni2+ Single Sites within Lacunary Defects of Wells Dawson Polyoxometalates

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05377A, Communication
Yoonrae C Cho, Jessica Muhlenkamp, Allen Grayson Oliver, Jason C. Hicks
Oligomerization of light olefins has become an essential step to convert gaseous olefins to liquid fuels and value-added chemicals. Here, we report that the synthesis and application of nickel single...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Non-invasive, 3D printed, colourimetric, early wound-infection indicator

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06147J, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yusufu Dilidaer, Erin Magee, Brendan Gilmore, Andrew Mills
A simple, non-invasive, colour-based CO2 indicator is described which provides an indirect response to the rapid microbial colonisation of an underlying wound when used in conjunction with an occlusive (i.e....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.11.2021


Photo-modulated supramolecular self-assembly of ortho-nitrobenzyl ester-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2′-yl)pyridine complexes

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05754E, Communication
Andy Shun-Hoi Cheung, Michael Ho-Yeung Chan, Charlotte Po, Eugene Yau-Hin Hong, Vivian Wing-Wah Yam
The enhanced supramolecular self-assembly behaviors of photo-caged platinum(II) complexes have been triggered by applying light as the external stimulus.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Nucleophilic borylation of fluorobenzenes with reduced arylboranes

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06225E, Communication
Hendrik Budy, Sven E. Prey, Christoph D. Buch, Michael Bolte, Hans-Wolfram Lerner, Matthias Wagner
Two challenging but rewarding topics in chemical synthesis are C–F-bond activation and the development of B-centered nucleophiles. We have now tackled both subjects simultaneously by forming aryl–B bonds via SNAr-type...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Finned hierarchical MOFs supported on cellulose for the selective adsorption of n-hexane and 1-hexene

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC04548B, Communication
Xinyang Yin, Jie Zha, Skyler Gregor, Shengzhe Ding, Ahmad Alsuwaidi, Xueyi Zhang
Finned hierarchical MOF particles (Cu(BDC) nanosheets as fins grown perpendicularly on Ni2(BDC)2(DABCO) hexagonal prisms) were synthesized on modified cellulose support. The hierarchical MOF particles exposed the open Cu(II) sites on...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Cp*Rh(III)/Boron Hybrid Catalysis for Directed C–H Addition to β-Substituted α,β-Unsaturated Carboxylic Acids

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05956D, Communication
Ryo Tanaka, Yuki Hirata, Masahiro Kojima, Tatsuhiko Yoshino, S Matsunaga
The C–H bond addition reaction of 2-phenylpyridine derivatives with α,β-unsaturated carboxylic acids catalyzed by Cp*Rh(III)/BH3·SMe2 is reported. Activation of C–H bonds with the rhodium catalyst and activation of α,β-unsaturated carboxylic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Individual Concave Twin ZnO Microdisk with Optical Resonance

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05332A, Communication
Yumin Chen, Zhen Liu, Xiaohui Qiu, Xinfeng Liu
We synthesized concave twin ZnO microdisks, whose outer surfaces are entirely enclosed by high-energy facets. Different from hexagonal planar WGM microdisks, individual concave twin ZnO microdisk shows Fabry-Pérot resonances and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Deep-blue-emitting nanoaggregates from carbazole-based dyes in water

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05441D, Communication
Xiaohui Li, Qi Zhang, Xin Zhang
New amphiphilic carbazole-based dyes assemble in water into deep-blue-emitting, highly fluorescent helical aggregates as observed by transmission electron microscope and atomic force microscopy. Single crystal X-ray diffraction and NMR spectroscopy...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Polyaniline Modified Surface of Electrode for Boosting the Electrocatalysis on Hydrogen Evolution Reaction and Ethanol Oxidation Reaction

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC04163K, Communication
Yankun Huang, Feng Bao, Muwei Ji, Yanzhao Hu, Liu Huang, Huichao Liu, Jiali Yu, Guangtao Cong, Caizhen Zhu, Jian Xu
Here, polyaniline (PANI) is reported loaded on carbon paper to modify the carbon paper-PANI-Pt electrode surface, tailoring the electrocatalytic capability on hydrogen evolution reaction and ethanol oxidation reaction. The reasons...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Light-Driven Dissipative Self-Assembly of a Peptide Hydrogel

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC04971B, Communication
Mengmeng Liu, Cassidy Creemer, Thomas Reardon, Jon Parquette
Light energy provides an attractive fuel source for energy dissipating systems because of the lack of waste production, wavelength tunability and the potential for spatial and temporal resolution. In this...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


M©B7O7+ (M = Ni, Pd, Pt): Aromatic molecular stars with a planar heptacoordinate transition metal

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05844D, Communication
Bo Jin, Rui Sun, Bin Huo, Caixia Yuan, Yanbo Wu
The dynamically stable global minima M©B7O7+ (M = Ni, Pd, Pt) are interesting in that they possess σ-aromaticity alone within its B7M core moiety, which can be attributed to the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Au(I)-Mediated N2-Elimination from Triazaphospholes: A One-Pot Synthesis of Novel N2P2-Heterocycles

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06205K, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Erlin Yue, Lea Dettling, Julian Sklorz, Selina Kaiser, Manuela Weber, Christian Muller
Novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and structurally characterized. In an attempt to prepare the corresponding Au(I)-complexes with stoichiometric amounts of AuCl·S(CH3)2, cyclo-1,3-diphospha(III)-2,4-diazane-AuCl-complexes were obtained instead. Our here presented...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Ratiometric fluorescence detection of pathogenic bacteria based on dual-recognition nanoprobes with controllable G-quadruplex release

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05966A, Communication
Yizhong Shen, Tingting Wu, Huanhuan Chen, Yingwang Ye, Jing-Juan Xu
A dual-recognition carbon dots-based nanoprobe with controllable G-quadruplex release is developed for ratiometric fluorescence detection of pathogenic bacteria in a fast and precise way, which opens a promising avenue for...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Activator-induced quencher-detachment-based turn-on probe with a cationic substrate moiety for acetylcholinestera

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05132F, Communication
Masahiro Oe, Koji Miki, Akito Masuda, Kohei Nogita, Kouichi Ohe
We report a choline ester-grafted turn-on fluorescence probe to detect acetylcholinesterase (AChE) in living cells. AChE-mediated hydrolysis of the choline ester moiety producing carboxylate initiates the activation of Cy5 fluorophore...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Metal-Free C-Se Cross-Coupling Enabled by Photoinduced Intermolecular Charge Transfer

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06152F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Chen Zhu, Serik Zhumagazy, Huifeng Yue, Magnus Rueping
Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


MOFs-derived ruthenium-doped amorphous molybdenum dioxide hybrid for highly efficient hydrogen evolution reaction in alkaline media

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05683B, Communication
Ji-Yuan Han, Sheng-Hao Cai, Ji-Yu Zhu, Shuang Yang, Ji-Sen Li
Ruthenium-doped amorphous molybdenum dioxide coupled with reduced graphene oxide hybrid (Ru-MoO2@PC/rGO) is synthesized using POMOF/GO as precursor. Benefitting from the synergistic effect of numerous exposed active sites, Ru dopants, and...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Coronene-Embedded ‘Super’ Coumarins

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC04976C, Communication
Venkatakrishnan Parthasarathy, Nitisha Kashyap, Prabhakar Chetti
The non-planar π-enlarged coronene-embedded coumarin achieved via pyranone-annulation and its cyanated derivative possess bright orange to red emission in both solution and solid states leaving scope for bio-imaging application. Multiple...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Cobalt-Catalyzed Alkyne Hydrosilylation as a New Frontier to Selectively Access Silyl-Hydrocarbons

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06214J, Highlight
Jung-Woo Park
Hydrosilylation of alkynes is a chief chemical method in accessing a range of alkenylsilanes, which can be derivatized to obtain value-added hydrocarbons and utilized in diverse applications. While noble-metal-based catalytic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.11.2021


Total syntheses of ericifolione and analogues via a biomimetic inverse-electron-demand Diels-Alder reaction

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06361H, Communication
Tingting Zhou, Anquan Zheng, Luqiong Huo, Changgeng Li, Haibo Tan, Sasa Wang, Huiyu Chen
Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.11.2021


Sub-5 nm Homeotropically Aligned Columnar Structures of Hybrids Constructed by Porphyrin and Oligo(Dimethylsiloxane)

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05886J, Communication
Weilu Yang, Dong Liu, Longfei Luo, Peiyun Li, Yun Liu, Zhihao Shen, Ting Lei, Huai Yang, Xinghe Fan, Qi-Feng Zhou
A series of tetraphenylporphyrin-based thermotropic liquid crystals containing oligo(dimethylsiloxane) were synthesized. These disc-coil hybrids form ordered nanostructures with periodic sizes on the sub-5 nm scale, including oblique columnar, lamellar, and...
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Datum: 27.11.2021


Molecular Recognition and Photoprotection of Riboflavin in Water by a Biomimetic Host

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05818E, Communication
Hong Zhang, Li-Li Wang, Xin-Yu Pang, Liu-Pan Yang, Wei Jiang
A water-soluble tetralactam macrocycle with 2,6-diethoxynaphthalene group as side walls is able to strongly bind riboflavin (Ka >107 M−1) in water through hydrogen bonding and the hydrophobic effect. The encapsulated...
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Datum: 27.11.2021


Highly active oxygen reduction reaction on Fe-nanoclustered hierarchical porous carbon derived from CO2

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05390F, Communication
Ayeong Byeon, Hodong Kim, Jae Hyun Park, Gi Mihn Kim, Jae W. Lee
Fe-nanoclustered CO2-derived porous carbon exhibits a comparable oxygen reduction reaction performance to platinum based catalysts.
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Datum: 26.11.2021


Oxide nanowire microfluidics addressing previously-unattainable analytical methods for biomolecules towards liquid biopsy

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05096F, Feature Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Hiromi Takahashi, Yoshinobu Baba, Takao Yasui
Nanowire microfluidics using a combination of self-assembly and nanofabrication technologies is expected to provide bioanalytical methods for liquid biopsy, which are impossible to achieve with conventional technologies.
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Datum: 26.11.2021


AgCu@CuO Aerogels with Peroxidase-Like Activity and Photoelectric Response for Sensitive Biosensing

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06177A, Communication
Jinli Li, Yu Wu, Ying Qin, Mingwang Liu, Guojuan Chen, Liuyong Hu, Wenling Gu, Chengzhou Zhu
Photoelectrochemical (PEC) enzymatic biosensors integrate the excellent selectivity of enzymes and high sensitivity of PEC bioanalysis, while the shortcomings of high cost, poor stability, as well as tedious immobilization of...
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Datum: 26.11.2021


New Approaches to Ondansetron and Alosetron Inspire a Versatile, Flow Photochemical Method for Indole Synthesis.

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC05700F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wei Sun, William Raimbach, Luke D Elliot, Kevin Booker-Milburn, David Harrowven
An oxidative photocyclisation of N-arylenaminones to indoles is described, that mirrors the Fischer indole synthesis but uses anilines in place of arylhydrazines. Its value is exemplified with new approaches to...
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Datum: 26.11.2021


Competitive Gold/Nickel Transmetalation

Chem. Commun., 2021, Accepted Manuscript
DOI: 10.1039/D1CC06064C, Communication
Mitchell J. Demchuk, Joseph A Zurakowski, Brady Austen, David James Nelson, Marcus W. Drover
Transmetalation is a key method for the construction of element-element bonds. Here, we disclose the reactivity of [NiII(Ar)(I)(diphosphine)] compounds with arylgold(I) transmetalating agents, which is directly relevant to cross-coupling catalysis....
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Datum: 26.11.2021


Catalytic regioselective construction of phenylthio- and phenoxyldifluoroalkyl tetrazoles from difluorodiazoketones

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05890H, Communication
Hong-Song Shi, Shuo-Han Li, Fa-Guang Zhang, Jun-An Ma
Two bench-stable difluorodiazoketone reagents have been designed, synthesized, and utilised in a silver-catalysed regioselective [3+2] cycloaddition reaction with aryldiazonium salts.
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Datum: 25.11.2021


Red-light-activatable ruthenium phthalocyanine catalysts

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06307C, Communication
Yuta Ishikawa, Tatsuya Kameyama, Tsukasa Torimoto, Hajime Maeda, Masahito Segi, Taniyuki Furuyama
Phthalocyanine ruthenium complexes were identified as red-light activatable catalysts for trifluoromethylation reactions.
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Datum: 24.11.2021


Tandem vinyl radical Minisci-type annulation on pyridines: one-pot expeditious access to azaindenones

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06204B, Communication
Dong Xia, Xin-Fang Duan
A new regiospecific alkylative/alkenylative cascade annulation of pyridines has been achieved, providing an expeditious access to azaindenones and related compounds with the problem of C2/C4 regioselectivity of pyridines being well addressed.
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Datum: 24.11.2021


Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05684K, Communication
Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
The Ir/(S)-DTBM-SEGPHOS catalyst promotes intramolecular hydroarylation of allylic aryl ethers without assistance from a directing group on the aryl groups.
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Datum: 24.11.2021


A one-pot two-step synthesis of tertiary alcohols combining the biocatalytic laccase/TEMPO oxidation system with organolithium reagents in aerobic aqueous media at room temperature

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06460F, Communication
Marina Ramos-Martín, Ramón Lecuna, Luciana Cicco, Paola Vitale, Vito Capriati, Nicolás Ríos-Lombardía, Javier González-Sabín, Alejandro Presa Soto, Joaquín García-Álvarez
A hybrid one-pot tandem protocol combining s-block reagents with enzymes (laccase from Trametes versicolor), in aqueous media, at room temperature and under air, is disclosed.
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Datum: 23.11.2021


High-performance NH3 production via NO electroreduction over a NiO nanosheet array

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06113E, Communication
Pengyu Liu, Jie Liang, Jiaqian Wang, Longcheng Zhang, Jun Li, Luchao Yue, Yuchun Ren, Tingshuai Li, Yonglan Luo, Na Li, Bo Tang, Qian Liu, Abdullah M. Asiri, Qingquan Kong, Xuping Sun
A NiO nanosheet array is active for NH3 electrosynthesis via a NO reduction reaction, attaining a faradaic efficiency of 90% and an NH3 yield of 2130 μg h−1 cm−2. Its aqueous Zn–NO battery offers a power density of 0.88 mW cm−2 and an NH3 yield of 228 μg h−1 cm−2.
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Datum: 23.11.2021


Dicationic oligotelluroxane or mononuclear telluronium cation? Elucidation of the true catalytic species and activation mechanism of the benzylic carbon-halogen bond

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06311A, Communication
Koji Takagi, Nao Sakakibara, Shoko Kikkawa, Seiji Tsuzuki
The application of diaryltelluronium cations as a chalcogen bonding organocatalyst is described.
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Datum: 23.11.2021


Synthesis and reactivity of heteroleptic zinc(I) complexes toward heteroallenes

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05617D, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Bin Li, Kevin Huse, Christoph Wölper, Stephan Schulz
Heteroleptic zinc(I) complexes Cp*Zn–ZnL1/2 were synthesized and reactions of Cp*Zn–ZnL2 2 with t-BuNCO and organoazides RN3 proceeded with insertion into the Zn–Zn bond and formation of novel zinc carbamate, bis-hexazene, triazenide, and azide complexes 4–7.
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Datum: 23.11.2021


A two-stage energy tuning strategy via salt and glycine programmed DNA-engineered crystals

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05432E, Communication
Yanqiu Du, Xiang Zhou, Jing Jin, Haojun Liang, Yongfeng Men, Wei Jiang
This work presents a two-stage energy tuning strategy by salt and glycine for preparing high-quality DNA-engineered crystals at room temperature.
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Datum: 23.11.2021


Specific detection of IMP-1 β-lactamase activity using a trans cephalosporin-based fluorogenic probe

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05955F, Communication
Liqiang Hu, Runqiu Liu, Zheng Ma, Tao Yu, Ziyao Li, Yingqiu Zou, Chang Yuan, Fangfang Chen, Hexin Xie
A novel fluorogenic probe for the highly specific detection of IMP-1 β-lactamase activity has been developed.
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Datum: 23.11.2021


Iron catalyzed tandem ring opening/1,6-conjugate addition of cyclopropanols with p-quinone methides: new access to γ,γ-diaryl ketones

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05997A, Communication
Sachin R. Shirsath, Sagar M. Chandgude, M. Muthukrishnan
An efficient and straightforward synthesis of γ,γ-diaryl ketones was developed via the iron catalyzed tandem ring opening/1,6-conjugate addition of cyclopropanols to p-quinone methides.
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Datum: 23.11.2021


An NAD+-type earth-abundant metal complex enabling photo-driven alcohol oxidation

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC04665A, Communication
Hideki Ohtsu, Mikio Takaoka, Yosuke Tezuka, Kiyoshi Tsuge, Koji Tanaka
A unique photo-oxidation of various alcohols induced by an unprecedented NAD+-type zinc(II) complex has been successful.
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Datum: 23.11.2021


Enantioselective construction of a tetrasubstituted stereocenter in isoindolinones via an organocatalyzed reaction between ketones and 3-hydroxyisoindolinones

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05761H, Communication
Mateja Matišić, Matija Gredičak
In a reaction catalyzed by a chiral phosphoric acid, ketones and in situ generated ketimines afford isoindolinone derivatives with a tetrasubstituted stereogenic center in high yields, and high diastereo- and enantioselectivities.
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Datum: 23.11.2021


Pyridinium-conjugated polynorbornenes for nanomolar ATP sensing using an indicator displacement assay and a PET strategy

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05500C, Communication
Ling-Xi Huang, Yue-Bo He, Jaewon Kim, Amit Sharma, Qian-Yong Cao, Jong Seung Kim
Novel polynorbornene-based probes for fluorescence sensing of ATP at nanomolar levels via the indicator displacement assay (IDA) method are reported.
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Datum: 23.11.2021


Pillararene-based molecular-scale porous materials

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC06105D, Feature Article
Meng-Hao Li, Xin-Yue Lou, Ying-Wei Yang
This feature article discusses the synthetic methods, functionalisation approaches and application potential of pillararene-based molecular-scale porous materials.
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Datum: 23.11.2021


Hypocrellin B-based activatable photosensitizers for specific photodynamic effects against high H2O2-expressing cancer cells

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05823A, Communication
Takashi Kitamura, Hirotaka Nakata, Daisuke Takahashi, Kazunobu Toshima
A purpose-designed synthetic H2O2-activatable photosensitizer 4 based on hypocrellin B (3) exhibited selective photo-cytotoxicity against target cancer cells upon photo-irradiation with highly tissue penetrating 660 nm light.
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Datum: 22.11.2021


Self-crystallisation, an unexpected property of 45S5 Bioglass®

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC04847C, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Djurdja Vukajlovic, Katarina Novakovic, Oana Bretcanu
Self-crystallisation of 45S5 Bioglass® was observed at room temperature and atmospheric pressure, without further processing, one year after fabrication.
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Datum: 22.11.2021


Correction: Unusual design strategy for a stable and soluble high-molecular-weight copper(I) arylacetylide polymer

Chem. Commun., 2021, 57,12856-12856
DOI: 10.1039/D1CC90407H, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Li Jiang, Jiangtao Jia, Yongchang Zhai, Zhiqiang Zhao, Yu Chen, Fengchao Cui, Yuyang Tian, Zheng Bian, Hongkun Tian, Chuanqing Kang, Lianxun Gao, Mohamed Eddaoudi, Guangshan Zhu
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Datum: 22.11.2021


The effect of the particle size on Fischer–Tropsch synthesis for ZSM-5 zeolite supported cobalt-based catalysts

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC04844A, Communication
Hao Wang, Ziwei Wang, Sheng Wang, Chengguang Yang, Shenggang Li, Peng Gao, Yuhan Sun
The highly selective synthesis of various middle distillate fuels including gasoline, jet fuel and diesel range hydrocarbons is achieved for hierarchical ZSM-5 zeolite supported cobalt catalysts with different cobalt particle sizes for syngas conversion.
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Datum: 22.11.2021


Rh(III)-catalyzed diastereoselective cascade annulation of enone-tethered cyclohexadienones via C(sp2)–H bond activation

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05941F, Communication
Sandip B. Jadhav, Sundaram Maurya, N. Navaneetha, Rambabu Chegondi
Herein, we report highly diastereoselective arylative cyclization of enone-tethered cyclohexadienones via Rh(III)-catalyzed C–H activation of N-methoxybenzamides.
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Datum: 22.11.2021


A cooperative Pd/Co catalysis system for the asymmetric (4+2) cycloaddition of vinyl benzoxazinones with N-acylpyrazoles

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05952A, Communication
Wei Xiong, Xuan Jiang, Mao-Mao Zhang, Wen-Jing Xiao, Liang-Qiu Lu
An asymmetric [4+2] cycloaddition was developed by exploiting a new cooperative Pd/Co catalysis system. This protocol provides a new access to chiral tetrahydroquinolines with unprecedented cis-configuration in high yields and enantioselectivity.
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Datum: 22.11.2021


Direct imaging of lattice planes in atomically precise noble metal cluster crystals using a conventional transmission electron microscope

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05643C, Communication
Ananthu Mahendranath, Biswajit Mondal, Korath Shivan Sugi, Thalappil Pradeep
A methodology to image finer structural details of atomically precise nanocluster crystals using a conventional TEM.
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Datum: 22.11.2021


Ultrasound-assisted dopamine polymerization: rapid and oxidizing agent-free polydopamine coatings on membrane surfaces

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05960B, Communication
Aydın Cihanoğlu, Jessica D. Schiffman, Sacide Alsoy Altinkaya
Ultrasound-assisted polymerization is a green, controllable and facile way of accelerating the slow kinetics of dopamine polymerization in the bulk phase and the deposition rate of the PDA coating on the surface of the polymeric membranes.
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Datum: 19.11.2021


Photoresponsive macrocycles for selective binding and release of sulfate

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05506B, Communication
Shenglun Xiong, Qing He
This work reports the synthesis of four photoresponsive macrocycles and their selective binding and release of SO42− via light irradiation.
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Datum: 19.11.2021


Chiral macrocycle-induced circularly polarized luminescence of a twisted intramolecular charge transfer dye

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05902E, Communication
Tiejun Li, Hao Guo, Yuan Wang, Guanghui Ouyang, Qi-Qiang Wang, Minghua Liu
The host–guest binding between a chiral macrocycle and an achiral dye could suppress the twisted intramolecular charge transfer process, leading to enhanced emission and bright circularly polarized luminescence from the TICT-dye.
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Datum: 19.11.2021


UV to NIR multistate electrochromism and electrofluorochromism in dibenzophenazine-arylamine derivatives

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05138E, Communication
Bahadur Sk, Madhurima Sarkar, Kuldeep Singh, Arunava Sengupta, Abhijit Patra
Multistate UV to NIR electrochromism and electrofluorochromism via smart modulation of intramolecular and intervalence charge transfer transitions in dibenzophenazine-arylamine derivatives was demonstrated.
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Datum: 18.11.2021


Enhanced electrochemical performance of Li2.72Na0.31MnPO4CO3 as a cathode material in “water-in-salt” electrolytes

Chem. Commun., 2021, 57,12840-12843
DOI: 10.1039/D1CC04350A, Communication
Baowei Xie, Ryo Sakamoto, Ayuko Kitajou, Liwei Zhao, Kosuke Nakamoto, Shigeto Okada, Ken Albrecht, Wataru Kobayashi, Masaki Okada, Toshiya Takahara
A full cell composed of ion-exchanged Li2.72Na0.31MnPO4CO3 from Na3MnPO4CO3 and LiTi2(PO4)3 with a water-in-salt electrolyte exhibites operation voltage of approximately 1 V.
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Datum: 17.11.2021


The modern role of boron as a ‘magic element’ in biomedical science: chemistry perspective

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05481C, Highlight
Saurav Chatterjee, Nitesh Mani Tripathi, Anupam Bandyopadhyay
This article discusses in a big-picture manner popular boron chemistries that are a focus in multidisciplinary applications.
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Datum: 17.11.2021


Intermediates and mechanism in iron-catalyzed C–H methylation with trimethylaluminum

Chem. Commun., 2021, 57,12784-12787
DOI: 10.1039/D1CC05607G, Communication
Shilpa Bhatia, Joshua C. DeMuth, Michael L. Neidig
Iron-catalyzed C–H methylation with organoaluminum reagents accesses reactive cyclometalated iron(II) intermediates.
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Datum: 16.11.2021


A new metal–organic framework based on rare [Zn4F4] cores for efficient separation of C2H2

Chem. Commun., 2021, 57,12788-12791
DOI: 10.1039/D1CC05196B, Communication
Wen-Juan Shi, Yong-Zhi Li, Jing Chen, Run-Han Su, Lei Hou, Yao-Yu Wang, Zhonghua Zhu
Assembly via 1,4-benzenedicarboxylate linker and Zn2+ ions afforded a new MOF containing novel [Zn4F4] cubane cores, showing excellent C2H2 separation from C2H2–CO2 and C2H2–CH4 mixtures.
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Datum: 16.11.2021


Directional copper dewetting to grow graphene ribbon arrays

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05030C, Communication
Xiaogang Li, Xuyao Xiong, Congcong Ning, Qian Yang, Dongling Li, Zegao Wang, Yan Jin, Wenbin Zhao, Baoshan Hu
A novel strategy that employs V-shaped grooves to confine the directional dewetting of a Cu film facilitates the CVD growth of graphene ribbons.
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Datum: 15.11.2021


Biocompatible photoinduced CuAAC using sodium pyruvate

Chem. Commun., 2021, 57,12844-12847
DOI: 10.1039/D1CC05566F, Communication
Jaepil Jeong, Grzegorz Szczepaniak, Saigopalakrishna S. Yerneni, Francesca Lorandi, Hossein Jafari, Sushil Lathwal, Subha R. Das, Krzysztof Matyjaszewski
The use of sodium pyruvate as a photoreducing agent for copper-mediated azide–alkyne cycloaddition (CuAAC) under UV irradiation is described.
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Datum: 12.11.2021


Porphyrin(2.1.2.1) as a novel binucleating ligand: synthesis and molecular structures of mono- and di-rhodium(I) complexes

Chem. Commun., 2021, 57,12808-12811
DOI: 10.1039/D1CC05641G, Communication
Songlin Xue, Ningchao Liu, Peifeng Mei, Daiki Kuzuhara, Mingbo Zhou, Jianming Pan, Hiroko Yamada, Fengxian Qiu
Porphyrin(2.1.2.1) could be developed as a new binucleating ligand for making bimetallic complexes.
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Datum: 12.11.2021


Dendronized polydiacetylenes via photo-polymerization of supramolecular assemblies showing thermally tunable chirality

Chem. Commun., 2021, 57,12780-12783
DOI: 10.1039/D1CC05358B, Communication
Yanjun Liu, Yaodong Lin, Yuexin Cao, Aomiao Zhi, Jiabei Chen, Wen Li, Baris Demir, Debra J. Searles, Andrew K. Whittaker, Afang Zhang
Dendronized polydiacetylenes showing thermoresponsiveness were fabricated via photopolymerization of assembled ribbons from amphiphilic dendronized diacetylene in aqueous solutions, which simultaneously showed thermally switchable chiralities.
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Datum: 10.11.2021


Inexpensive gram scale synthesis of porous Ti4O7 for high performance polymer electrolyte fuel cell electrodes

Chem. Commun., 2021, 57,12772-12775
DOI: 10.1039/D1CC05144J, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Mitsuharu Chisaka, Waka Nagano, Byambasuren Delgertsetseg, Tatsuya Takeguchi
More than 2 grams of porous Ti4O7 supports for high performance fuel cell electrodes were synthesized in a single reaction by simply increasing the precursor mass used in the developed inexpensive route.
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Datum: 10.11.2021


O-Protected NH-free hydroxylamines: emerging electrophilic aminating reagents for organic synthesis

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05282A, Highlight
Dilsha Jinan, Pinku Prasad Mondal, Anagha Veluthanath Nair, Basudev Sahoo
O-Protected NH-free hydroxylamines have emerged as electrophilic aminating reagents for constructing nitrogen-enriched compounds with high regio-, and stereoselectivity in the unprotected form, through biocatalysis, organo-, and metal catalysis.
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Datum: 10.11.2021


Cationic π-extended heteroaromatics via a catalytic C–H activation annulative alkyne-insertion sequence

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC05590A, Feature Article
Pirudhan Karak, Samim Sohel Rana, Joyanta Choudhury
Herein, the recent progress of an annulative alkyne-insertion π-extension (AAIPEX) strategy to construct opto-electronically significant cationic polycyclic heteroaromatic compounds (cPHACs) is showcased.
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Datum: 10.11.2021


Development of hypoxia-activated PROTAC exerting a more potent effect in tumor hypoxia than in normoxia

Chem. Commun., 2021, 57,12852-12855
DOI: 10.1039/D1CC05715D, Communication
Weiyan Cheng, Shasha Li, Xueqian Wen, Siyuan Han, Suhua Wang, Han Wei, Zhizhen Song, Yueqin Wang, Xin Tian, Xiaojian Zhang
In this manuscript, for the first time, we report the development of a kind of hypoxia-activated PROTAC that shows a more potent degradation activity in the tumor hypoxia environment than in normoxia.
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Datum: 10.11.2021


A simple liquid state 1H NMR measurement to directly determine the surface hydroxyl density of porous silica

Chem. Commun., 2021, 57,12804-12807
DOI: 10.1039/D1CC03959H, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
C. Penrose, P. Steiner, L. F. Gladden, A. J. Sederman, A. P. E. York, M. Bentley, M. D. Mantle
Silica is widely used in industrial applications and its performance is partially decided by its surface hydroxyl density αOH.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.11.2021


Light-induced synthesis of unsymmetrical organic carbonates from alcohols, methanol and CO2 under ambient conditions

Chem. Commun., 2021, 57,12800-12803
DOI: 10.1039/D1CC05833A, Communication
Sandhya Saini, Nand Kishor Gour, Shafiur Rehman Khan, Ramesh Chandra Deka, Suman L Jain
An organic base mediated reaction of CO2 with alcohols and methanol under light irradiation leads to unsymmetrical organic carbonates under atmospheric pressure and ambient temperature conditions.
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Datum: 09.11.2021


Elucidating the charge storage mechanism of carbonaceous and organic electrode materials for sodium ion batteries

Chem. Commun., 2021, Advance Article
DOI: 10.1039/D1CC04925A, Feature Article
Vincent Wing-hei Lau, Jae-Bum Kim, Feng Zou, Yong-Mook Kang
This article critically reviews the analytical methodologies and characterization techniques employed for elucidating the charge storage mechanism of carbonaceous and organic electrode materials for sodium ion batteries.
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Datum: 09.11.2021


Multichannel dual protein sensing using amphiphilic supramolecular assemblies

Chem. Commun., 2021, 57,12828-12831
DOI: 10.1039/D1CC05407D, Communication
Jingjing Gao, Theeraphop Prachyathipsakul, S. Thayumanavan
A supramolecular dual protein sensing approach embedded with protein–ligand binding features and enzyme-cleavable moiety activating multichannel fluorescence signals via three different mechanisms.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.11.2021


A self-assembled M2L2 truncated square and its application as a container for fullerenes

Chem. Commun., 2021, 57,12848-12851
DOI: 10.1039/D1CC05581J, Communication
Jun Yuan, Wanqian Lv, Anquan Li, Kelong Zhu
A truncated square-like M2L2 metallamacrocycle was successfully assembled and utilized as a container for the highly efficient encapsulation of fullerenes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.11.2021


A triple-pore tessellated square array by a metal-hexagonal ligand with reinforced tetra-connectors

Chem. Commun., 2021, 57,12832-12835
DOI: 10.1039/D1CC05428G, Communication
Suqing Li, He Zhao, Mingzhao Chen, Jun Wang, Wanying Zhong, Zhilong Jiang, Die Liu, Hui Liu, Pingshan Wang
This manuscript describes an unexplored triple-pore tessellated square array with three different kinds of pores. The discrete array can be assembled into multichannel tubular nanostructures through molecular packing.
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Datum: 05.11.2021


A free-standing 3D porous all-ceramic cathode for high capacity, long cycle life Li–O2 batteries

Chem. Commun., 2021, 57,12792-12795
DOI: 10.1039/D1CC02966E, Communication
Yuxin Wang, Da Han, Feiyu Kang, Dengyun Zhai
A porous all-ceramic RuO2@La0.7Ca0.3CuO3 cathode for Li–O2 batteries achieved a high capacity of 21 518 mA h g−1 and a high reversible cycling stability.
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Datum: 05.11.2021


KB3H8: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols

Chem. Commun., 2021, 57,12776-12779
DOI: 10.1039/D1CC05638G, Communication
Xinying Li, Tongge Mi, Wenjing Guo, Zhongrui Ruan, Yu Guo, Yan-Na Ma, Xuenian Chen
Selective reduction of aldehydes and ketones to alcohols using KB3H8 was achieved in water and THF.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.11.2021


TfOH catalysed domino-double annulation of arenes with propargylic alcohols: a unified approach to indene polycyclic systems

Chem. Commun., 2021, 57,12796-12799
DOI: 10.1039/D1CC05253E, Communication
Beeraiah Baire, Bhavna Yadav
TfOH catalysed domino-double annulation of arenes with propargylic alcohols is developed for the generation of indene based polycyclic systems. Three distinct reactions, dehydration–intramolecular hydroarylation–cationic cyclization were promoted.
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Datum: 04.11.2021


Heterometallic Al6Zn12 nano-plate with π-conjugated ligand: synthesis and nonlinear absorption properties

Chem. Commun., 2021, 57,12820-12823
DOI: 10.1039/D1CC05919J, Communication
San-Tai Wang, Chen-Hui Liu, Chan Zheng, De-Jing Li, Wei-Hui Fang, Jian Zhang
Presented herein is the synthesis of a heterometallic hybrid compound used as a candidate for third-order nonlinear optical (NLO) materials.
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Datum: 03.11.2021


G4-PROTAC: targeted degradation of a G-quadruplex binding protein

Chem. Commun., 2021, 57,12816-12819
DOI: 10.1039/D1CC05025G, Communication
Kiran M. Patil, Danielle Chin, Hui Ling Seah, Qi Shi, Kah Wai Lim, Anh Tuân Phan
A G-quadruplex (G4) motif was used as a warhead of a proteolysis-targeting chimera (G4-PROTAC) for targeted degradation of a G4-binding protein (RHAU/DHX36), providing a new way to explore G4-protein networks and develop potential therapeutics.
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Datum: 02.11.2021


Polyethyleneimine-complexed charge-reversed yeast cell walls for the enhanced oral delivery of pseudovirus-based antigens

Chem. Commun., 2021, 57,12768-12771
DOI: 10.1039/D1CC04901A, Communication
Fengmin Yang, Lu Meng, Sisi Lin, Feng Wu, Jinyao Liu
A facile approach for preparing oral delivery systems is reported via encapsulating antigen-carrying pseudoviruses inside positively charged polyethyleneimine-modified yeast capsules, providing a versatile platform for developing oral vaccines.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.11.2021


Simple one-pot synthesis and high-resolution patterning of perovskite quantum dots using a photocurable ligand

Chem. Commun., 2021, 57,12824-12827
DOI: 10.1039/D1CC05892D, Communication
Byeong M. Oh, Yongcheol Jeong, Jian Zheng, Na Young Cho, Myungkwan Song, Jin Woo Choi, Jong H. Kim
Photo-curable and surface stabilizable organic ligands for the micro-patterning of perovskite quantum dots.
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Datum: 02.11.2021


Amphiphilic DNA nanostructures for bottom-up synthetic biology

Chem. Commun., 2021, 57,12725-12740
DOI: 10.1039/D1CC04311K, Feature Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roger Rubio-Sánchez, Giacomo Fabrini, Pietro Cicuta, Lorenzo Di Michele
Here we review our recent efforts, and those of others, on the construction of biomimetic DNA nanostructures that imitate biological structures and functionalities, and could serve as a generalised platform for engineering artificial cellular systems.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.10.2021


Intercepting a transient non-hemic pyridine N-oxide Fe(III) species involved in OAT reactions

Chem. Commun., 2021, 57,12836-12839
DOI: 10.1039/D1CC04521K, Communication
Nhat Tam Vo, Christian Herrero, Régis Guillot, Tanya Inceoglu, Winfried Leibl, Martin Clémancey, Patrick Dubourdeaux, Geneviève Blondin, Ally Aukauloo, Marie Sircoglou
An unprecedented pyridine-N-oxide Fe(III) intermediate has been detected as a potent oxidizing species for catalytic OAT reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


Dye–polyoxometalate coordination polymer as a photo-driven electron pump for photocatalytic radical coupling reactions

Chem. Commun., 2021, 57,12812-12815
DOI: 10.1039/D1CC04209B, Communication
Zheng Ming, Tiexin Zhang, Wenming Tian, Jianing Li, Zhenhui Liu, Renhai Liu, Zhongmin Liu, Chunying Duan
Coordination polymer containing triphenylamine and polyoxometalate photoinduced long-lived charge-separation pairs, which unidirectionally pumped multiple electrons from external electron donors to acceptors, furnishing value-added radical couplings.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


A Cu(111)@metal–organic framework as a tandem catalyst for highly selective CO2 electroreduction to C2H4

Chem. Commun., 2021, 57,12764-12767
DOI: 10.1039/D1CC05376K, Communication
Zhen-Hua Zhao, Kai Zheng, Ning-Yu Huang, Hao-Lin Zhu, Jia-Run Huang, Pei-Qin Liao, Xiao-Ming Chen
Herein, we demonstrated a strategy via integrating a CO-producing Cu-based metal–organic framework and Cu(111) nanoparticles into a new type of tandem catalyst, which achieves a high performance for electroreduction of CO2 to C2H4.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.10.2021


Chiral nanotubes self-assembled from discrete non-covalent macrocycles

Chem. Commun., 2021, 57,12712-12724
DOI: 10.1039/D1CC04968B, Feature Article
P. B. Chamorro, F. Aparicio
Transference of chiral information from monomers to supramolecular nanotubes through the self-assembly of discrete non-covalent macrocycles.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.10.2021


Asymmetric hydrogenation of O-/N-functional group substituted arenes

Chem. Commun., 2021, 57,12741-12753
DOI: 10.1039/D1CC04722A, Feature Article
Bing-Ru Shao, Lei Shi, Yong-Gui Zhou
This feature article focuses on the progress in catalytic asymmetric hydrogenation and transfer hydrogenation of O/N substituted arenes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.10.2021


Construction of protocell-based artificial signal transduction pathways

Chem. Commun., 2021, 57,12754-12763
DOI: 10.1039/D1CC03775G, Highlight
Chong Chen, Xuejing Wang, Ying Wang, Liangfei Tian, Jinxuan Cao
In this review, we highlight the recent advances in how to build different artificial paracrine-like signaling pathways and juxtacrine-like signaling pathways.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.10.2021


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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