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Chemical Communications

Current research reports and chronological list of recent articles..




The international scientific journal Chemical Communicationsoffers urgent high quality communications from across the chemical sciences.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles in the field of general chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Angewandte Chemie International Edition,

 - Chemical Monthly,

 - The Chemical Record,

 - Chemistry Central Journal,

 - Chemistry Letters,

 - Journal of the American Chemical Society,

 - Nature Chemistry.



Chemical Communications - Abstracts



Highly active Rh1/CeO2 single-atom catalyst for low-temperature CO Oxidation

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00230E, Communication
Bing Han, Tianbo Li, Junying Zhang, Chaobin Zeng, Hiroaki Matsumoto, Yang Su, Botao Qiao, Tao Zhang
Rh1/CeO2 single-atom catalyst is highly active for CO oxidation which is potential to server as a multifunctional catalyst to save other noble metals in three way catalysts. The high activity...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.03.2020


Are Ionic Liquids and Liquid Coordination Complexes Really Different? - Synthesis, Characterization, and Catalytic Activity of AlCl3/Base Catalysts

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01452D, Communication
Rajkumar Kore, Steven Paul Kelley, Anand Sawant, Manish Kumar Mishra, Robin D. Rogers
Lewis acid/base catalysts of AlCl3/N-methyl-2-pyrrolidone (O-NMP) and AlCl3/1-methylimidazole (N-Mim) were prepared and found to have higher catalytic activity in the Friedel–Crafts alkylation of benzene than the known super acidic ionic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Transition Metal Dichalcogenide/Multi-walled Carbon Nanotube-based Fibers as Flexible Electrodes for Electrocatalytic Hydrogen Evolution

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00506A, Communication
Bo Chen, Gengzhi Sun, Jie Wang, Guigao Liu, Chaoliang Tan, Ye Chen, Hongfei Cheng, Junze Chen, Qinglang Ma, Ling Huang, Peng Chen, Hua Zhang
We report a general strategy for the fabrication of binder-free, flexible and weavable transition-metal dichalcogenide nanosheet-based hybrid fibers by using well-aligned multi-walled carbon nanotubes as host. The resulting hybrid fibers...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Atomically thin TiO2 nanosheets synthesized using liquid metal chemistry

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01456G, Communication
Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi Datta, Kibret Messalea, Baoyue Zhang, Muhammad Waqas Khan, Aaron James Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of true two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Here, micron-sized ultrathin rutile TiO2...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Multielectron C–H Photoactivation with an Sb(V) Oxo Corrole

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09892E, Communication
Christopher M Lemon, Andrew G. Maher, Anthony R. Mazzotti, David Charles Powers, Miguel I. Gonzalez, Daniel G. Nocera
Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report a Sb(V) bis-μ-oxo corrole that photochemically oxidises the C–H bonds of organic substrates. In the case...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Self-Sacrificial MOFs for Ultra-Long Controlled Release of Bisphosphonate Anti-Osteoporotic Drugs

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00439A, Communication
Konstantinos D. Demadis, Daphne Chandrinou, Duane Choquesillo-Lazarte, Kostas Papathanasiou, Petri Turhanen, Maria Vassaki, Chrystalleni Hadjicharalambous
In this paper we report drug delivery systems that are based on phosphonate MOFs. These employ biologically-acceptable metal ions (eg. Ca2+ and Mg2+) and several anti-osteoporosis bisphosphonate drugs (etidronate, pamidronate,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Nitroprusside as a promising building block to assemble organic-inorganic hybrid for thermo-responsive switching material

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01877E, Communication
Rong-Guan Qiu, Xiao-Xian Chen, Rui-Kang Huang, Dong-Dong Zhou, Wei-Jian Xu, Wei-Xiong Zhang, Xiao-Ming Chen
We present a new organic-inorganic hybrid, (Me2NH2)[KFe(CN)5(NO)], possessing a unique nitroprusside-based inorganic host anionic framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds together with...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Supramolecular Hydrogel Derived from a Simple Organic Salt Capable of Proton Conduction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01467B, Communication
Parthasarathi Dastidar, Poulami Chakraborty, Sourabh Bera, S. Datta, B. Das, P. Pal
Exploiting supramolecular synthon approach based on a Cambridge Structural Database (CSD) analysis, a series of easily accessible primary ammonium sulfonates have been synthesized as potential supramolecular gelators. Single crystal X-ray...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Ring-Opening Iodination and Bromination of Unstrained Cycloalkanols through β-Scission of Alkoxy Radicals

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01720E, Communication
Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou , Jianbo Wang
A ring-opening iodination and bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed. In this protocol the concentration of I2 is modulated through...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


On-demand hydrogen production from formic acid by light-active dinuclear iridium catalysts

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00704H, Communication
Yuki Sofue, Kotohiro Nomura, Akiko Inagaki
Light-active dinuclear iridium complexes catalyze the decomposition of formic acid to generate H2 under ambient temperature and base-free conditions. The catalyst activity is sensitive to light demonstrating the ON/OFF switching ability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


A promising p-type Co-ZnFe2O4 nanorods film as photocathode for photoelectrochemical water splitting

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00273A, Communication
Yayao Lan, Zhifeng Liu, Zhengang Guo, Mengnan Ruan, Xifei Li
The p-type Co-ZnFe2O4 film with one-dimensional (1D) rod-like morphology is firstly fabricated on Fluorine-doped tin oxide (FTO) through hydrothermal reaction and sintering treatment. The p-type Co-ZnFe2O4 is obtained by doping...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Correction: Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5]catenanes built from cyclo[18]carbon

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90137G, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nikita Fedik, Maksim Kulichenko, Dmitriy Steglenko, Alexander I. Boldyrev
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Acridine Orange as a Coreactant for Efficient Electrogenerated Chemiluminescence of Tris(2,2′-bipyridine)ruthenium(II) and Its use for Selective and Sensitive Detection of Thiourea

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01273D, Communication
Muhammad Saqib, Shahida Bashir, Shimeles Addisu Kitte, Haijuan Li, Yongdong Jin
A new and efficient anodic Ru(bpy)32+ ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in neutral medium. The developed Ru(bpy)32+–AO system displayed higher ECL intensity...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Modified Cation-Exchange Membrane for Phosphate Recovery in Electrochemically Assisted Adsorption-Desorption Process

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09563B, Communication
Kostadin Veselinov Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis de Smet, Ernst JR Sudholter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed. The separation is performed in an electrodialysis...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Intermediate Layer Modulation between NiCoP and Ni Foam Substrate in Microwire Array Electrode for Enhanced Hydrogen Evolution Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, jun lv
A hierarchical electrode consisting of Ni foam substrate, intermediate layer of Mo doped basic cobalt carbonate microwire array and surface NiCoP was fabricated for hydrogen evolution. The intermediate layer introduction...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Initiating ribosomal peptide synthesis with exotic building blocks

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01291B, Highlight
Christos Tsiamantas, Joseph Matthew Rogers, Hiroaki Suga
Ribosomal peptide synthesis begins almost exclusively with the amino acid methionine, across all domains of life. The ubiquity of methionine initiation raises the question; to what extent could polypeptide synthesis...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Highly selective hydrosilylation of equilibrating allylic azides

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01316A, Communication
Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue
The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-ene vs...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2020


Valence Tautomerism in a Cobalt-Verdazyl Coordination Compound

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01770A, Communication
Connor Fleming, Dorothy Chung, Servando Ponce, Raja Das, David James Rawsthorne Brook, Jeffrey daRos, Andrew Ozarowski, Sebastian A Stoian
Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(II) ion coordinated to two radical ligands with an S=3/2 ground...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


The Design of Hypercrosslinked Polymers from Benzyl Ether Self-Condensing Compounds and External Crosslinkers

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01002B, Communication
Robert Thomas Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes. These...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


Synthesis of Functionalized Tetrahydrobenzofuran via Cascade Cycloaddition Involving Silyloxyallyl Cation Intermediate

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01796E, Communication
Fatimat Badmus, Joshua Malone, Frank R Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via unsymmetrical silyloxyallyl cation is reported. Conveniently generated under catalytic Brønsted acid conditions, nucleophilic capture of this reactive intermediate with silylenolate, followed by...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


A Terbium(III) luminescent ATCUN-based peptide sensor for selective and reversible detection of Copper(II) in biological media.

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01007C, Communication
Enrico Falcone, Paulina Gonzalez, Lucie Lorusso, Olivier Sénèque, Peter Faller, Laurent Raibaut
The measurement of exchangeable Cu2+ levels in biological samples is gaining interest in the context of copper-related pathologies. Here, we report a Tb3+ luminescent turn-off sensor for Cu2+ based on...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


A Dual-Round Signal Amplification Strategy for Colorimetric/Photoacoustic/Fluorescence Triple Read-Out Detection of Prostate Specific Antigen

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01086C, Communication
Chao Jiang , Yan Huang, Ting He, Peng Huang, Jing Lin
The detection of prostate specific antigen (PSA) is extremely important for the early diagnosis of prostate cancer. Herein, we report a dual-round signal amplification strategy for colorimetric/fluorescence/photoacoustic triple read-out detection...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


A DNA-Tetrahedron-Based Molecular Computation Device for Logic Sensing of Dual MicroRNAs in Living Cells

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01231A, Communication
Qing Lin, Anmin Wang, Shiyuan Liu, Jing Li, Jiaoli Wang, Ke Quan, Xiaohai Yang, Jin Huang, Kemin Wang
Endogenous miRNA expression patterns are well cell type-specific, thereby offering high prediction accuracy regard to different cell identities, compared with single miRNA analysis. “AND” logic gate can be utilized as...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2020


Spontaneous deposition of Ir nanoparticles on 2D siloxene as high-performance HER electrocatalyst with ultra-low Ir loading

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00245C, Communication
Qi Dai, Qin Meng, Cuicui Du, Feng Ding, Junlin Huang, Jianhang Nie, Xiao-Hua Zhang, Jinhua Chen
Herein, 2D siloxene terminated by surface functional groups of Si–H and Si–OH, is demonstrated to be an effective support for the spontaneous deposition of iridium nanoparticles (Ir NPs) to promote...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Live cell fluorescent stain of bacterial curli and biofilm through supramolecular recognition between bromophenol blue and CsgA

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01643H, Communication
Lixia Zhang, Zhenhua Li, Zhijun Chen
Identification of curli-specific dyes for biofilm communities of microorganisms is an important task. We describe here a curli fluorescent light-up probe called bromophenol blue, which bind to curli via recognizing...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Mononuclear Calcium Complex for Effective Alkenes Hydrogenation

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01745K, Communication
Xianghui Shi, Cuiping Hou, Lanxiao Zhao, peng deng, Jianhua Cheng
Hydrogenolysis of the scorpionate-supported calcium benzyl complex [(TpAd,iPr)Ca(p-CH2C6H4-Me)(THP)] (TpAd,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate, THP = tetrahydropyran) (2-THP) afforded the mononuclear calcium hydrido complex [(TpAd,iPr)Ca(H)(THP)] (3). Under mild conditions (40 oC, 10 atm...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Correlated alkyl chain length to defect passivation efficacy in perovskite solar cells

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01197E, Communication
wenhuai feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
We for the first time correlated the alkyl chain length of amine molecules to the defect passivation efficacy, either on surface or at grain boundaries of perovskite films. Blade-coated perovskite...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Direct conversion of syngas into aromatics over bifunctional catalyst without net releasing CO2

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00608D, Communication
Wei Zhou, Cheng Zhou, Haoren Yin, Jiaqing Shi, Guoquan Zhang, Xinlei Zheng, Xiaojian Min, Zhiqiang Zhang, Kang Cheng, Jincan Kang, Qinghong Zhang, Ye Wang
Tandem catalysis via methanol intermediate is a promising route for the direct conversion of syngas into aromatics. However, the simultaneous formation of CO2 is a serious problem. Here, we demonstrate...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01732A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Hansjörg Grützmacher, Andrea Cosola, Riccardo Conti, Vijay Kumar Rana, Marco Sangermano, Annalisa Chiappone, Joëlle Levalois-Grützmacher
A new multi-photoactive γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) was successfully prepared via a convergent synthesis using a Phospha-Michael-addition, as confirmed by 1H-, 13C-, 31P-NMR and IR spectroscopy and mass...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Oxyanion Transport across Lipid Bilayers: Direct Measurements in Large and Giant Unilamellar Vesicles

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09888G, Communication
Krzysztof Marek Bąk, Bartjan van Kolck, Krystyna Maslowska-Jarzyna, Panagiota Papadopoulou, Alexander Kros, Michał Jan Chmielewski
A simple di(thioamido)carbazole 1 serves as a potent multispecific transporter for various biologically relevant oxyanions, such as drugs, metabolites and model organic phosphate. The transport kinetics of a wide range...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Agonistic or antagonistic mucosal-associated invariant T (MAIT) cell activity is determined by the 6-alkylamino substituent on uracil MR1 ligands

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00247J, Communication
Chriselle D Braganza, Chihiro Motozono, Koh-hei Sonoda, Sho Yamasaki, Kensuke Shibata, Mattie Simon Maria Timmer, Bridget L Stocker
Mucosal-associated invariant T (MAIT) are a subset of innate-like T cells that are activated by uracil ligands presented by MR1. For the first time, we demonstrate that changes to the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Single-step self-assembly to uniform fiber-like core-crystalline block copolymer micelles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00153H, Communication
Shaofei Song, Hang Zhou, Garion Hicks, Chandresh Kumar Rastogi, Qing Yu, Ian Manners, Mitchell A. Winnik
Accessing uniform fiber-like micelles by single-step crystallization-driven co-self-assembly of a block copolymer with a trace of homopolymer.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Carbon-11 carboxylation of trialkoxysilane and trimethylsilane derivatives using [11C]CO2

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00449A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Salvatore Bongarzone, Nicola Raucci, Igor Camargo Fontana, Federico Luzi, Antony D. Gee
A simple and rapid carbon-11 carboxylation radiosynthesis method.
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Datum: 25.03.2020


Solvent-Driven Migration of Highly Polar Monomers into Hydrophobic PDMS Produces Thick Graft Layer via Subsurface Initiated ATRP for Efficient Antibiofouling

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00768D, Communication
Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
The sucessful grafting of highly polar polymer chains both on the surface and in the subsurface of PDMS via subsurface initiated ATRP for improved antibiofouling performance is enabled by the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


One-Dimensional Co-crystallized Coordination Polymers Showing Reversible Mechanochromic Luminescence: Cation-Anion Interaction Directed Rapid Self-Recovery

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09806B, Communication
Yongsheng Yang, Xiaoyu Fang, SI-Si Zhao, Feng-Yang Bai, Zhen Zhao, Ke-Zhi Wang, Dongpeng Yan
Three one-dimensional (1D) chain polymers (1D-9HAC, 1D-Cd-9AC, 1D-Cd-9AC-HBIM) that contain different intermolecular interactions and stacking patterns have been designed and synthesized. Only 1D-Cd-9AC-HBIM with rigid (anion) and flexible (cation) units...
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Datum: 25.03.2020


Efficient Cellular Uptake of Click Nucleic Acid Modified Proteins

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09401F, Communication
Albert Harguindey, Heidi Culver, Jasmine Sinha, Christopher N Bowman, Jennifer N Cha
Efficient intracellular delivery of biomacromolecules such as proteins continues to remain a challenge despite its potential for medicine. In this work, we show that mScarlet, a non cytotoxic red fluorescent...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


Sustained release of Ag+ confined inside polyoxometalates for long-lasting bacterial resistance

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01676D, Communication
Zhewei Xu, Kun Chen, Mu Li, Chang-ying Hu, Panchao Yin
Polyoxometalate with Ag+ hosted, [AgP5W30O110]14-, is studied for its sustained and controlled release of Ag+ triggered by Na+ replacement at room temperature for long-lasting bacteriostasis action, whose antibacterial activity is...
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Datum: 25.03.2020


Synthetic method, growth mechanism and electrochemical properties of PbSnS2 nanosheets for supercapacitors

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01011A, Communication
Yuhan Zeng, Hehe Huang, Shenhu Huang, Tongtong Jiang, Zekai Fang, Lin Li, Yuming Dai
In this work, we have developed a feasible strategy to design ternary metal sulfides of PbSnS2, the mutual Pb2+/Sn2+ substitution in the structure of sulfide elongated c axis of SnS...
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Datum: 25.03.2020


CRISPR/Cas-directed programmable assembly of multi-enzyme complexes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01174F, Communication
Samuel Lim, Jiwoo Kim, Yujin Kim, Dawei Xu, Douglas S. Clark
We describe a versatile CRISPR/Cas-based strategy to construct multi-enzyme complexes scaffolded on a DNA template in programmable patterns. Catalytically inactive dCas9 nuclease was used in combination with SpyCatcher-SpyTag chemistry to...
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Datum: 25.03.2020


The Synergy between the CsPbBr3 Nanoparticle Surface and the Organic Ligand Becomes Manifest in a Demanding Carbon-Carbon Coupling Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01339K, Communication
Ignacio Rosa-Pardo, Carla Casadevall, Luciana Carina Schmidt, Miguel Claros, Raquel E. Eugenia Galian, Julio Lloret Fillol, Julia Perez-Prieto
We demonstrate here the suitability of CsPbBr3 nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and...
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Datum: 25.03.2020


Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01192D, Communication
Katie J Lamb, Mark Dowsett, Michael North, Rachel R Parker, Adrian Charles Whitwood
The synthesis of novel tetrahydroquinoxalines by a metal induced one–electron reductive cyclisation of salophen ligands was found to occur when a salophen ligand was treated with chromium(II) chloride or decamethylcobaltocene
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.03.2020


High performance of zinc stannate photoanode in dye sensitized solar cell with cobalt complex mediators

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01219J, Communication
Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The photoanode fabricated with agglomerated zinc stannate nanoparticles was applied into dye sensitized solar cell (DSC) based on cobalt complex mediators. The resultant device yields an impressive power conversion efficiency...
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Datum: 25.03.2020


Unambiguous localization of titanium and iron cations in doped manganese hollandite nanowires

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01888K, Communication
José M González-Calbet, Isabel Gómez-Recio, Alberto Azor-Lafarga, Luisa Ruiz-Gonzalez, María Hernando, Marina Parras, José Juan Calvino, Maria Teresa Fernandez-Diaz, David Portehault, Clément Sanchez
New insights into the chemical and structural features of iron or titanium-doped KxMnO2 hollandites are reported. Neutron diffraction and atomically resolved transmission electron microscopy elucidate the localization of the dopant...
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Datum: 25.03.2020


Cyanine dye mediated mitochondrial targeting enhances the anti-cancer activity of small-molecule cargoes

Chem. Commun., 2020, Advance Article
DOI: 10.1039/C9CC07931A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alexander R. Nödling, Emily M. Mills, Xuefei Li, Davide Cardella, Edward J. Sayers, Shih-Hsiung Wu, Arwyn T. Jones, Louis Y. P. Luk, Yu-Hsuan Tsai
Conjugation of small molecules to a simple cyanine dye can lead to organelle-specific delivery.
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Datum: 25.03.2020


Enhanced single-molecule magnetism in dysprosium complexes of a pristine cyclobutadienyl ligand

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01722A, Communication
James P. Durrant, Jinkui Tang, Akseli Mansikkamäki, Richard A. Layfield
Cyclobutadienyl ligands can generate much stronger axial crystal fields in dysprosium single-molecule magnets (SMMs) than more common cyclopentadienyl ligands, providing clues as to how the performance of SMMs can be substantially improved.
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Datum: 19.03.2020


Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00982B, Communication
Thien S. Nguyen, Cafer T. Yavuz
The impact of nitrogen atoms on CO2 binding was evaluated for two isostructural porous bisimidazole-linked polymers (BILPs), which serendipitously had identical surface areas and pore size distributions, a very rare observation.
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Datum: 19.03.2020


New fluorescent light-up quinoxalines differentiate between parallel and nonparallel G-quadruplex topologies using different excitation/emission channels

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01242D, Communication
Ming-Hao Hu, Xiao Chen
A fluorescent light-up quinoxaline probe that could differentiate between parallel and nonparallel G4 topologies via different excitation/emission channels was developed.
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Datum: 19.03.2020


Facile assembly of three cycloalkyne-modules onto a platform compound bearing thiophene S,S-dioxide moiety and two azido groups

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01810D, Communication
Tomohiro Meguro, Yuki Sakata, Takamoto Morita, Takamitsu Hosoya, Suguru Yoshida
An efficient method to assemble three cycloalkyne-modules onto a platform bearing a thiophene S,S-dioxide moiety and two azido groups has been developed. The sequential reactions without catalysis or additives enabled the facile preparation of trifunctional molecules by a simple procedure.
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Datum: 19.03.2020


Preparation of textured and transparent BiVO4 photoelectrodes based on Mo-doped BiVO4 nanoparticles for constructing a stand-alone tandem water splitting device

Chem. Commun., 2020, Advance Article
DOI: 10.1039/C9CC09305B, Communication
Ze Wang, Chunwei Dong, Sen Liang, Shiyu Yao, Zidong Wang, Qingsen Zeng, Chongming Liu, Yi Liu, Bai Yang, Hao Zhang
Crystallographic orientation control is an effective method to improve the photoelectrochemical water splitting efficiency of BiVO4 photoanodes.
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Datum: 18.03.2020


A fluorescent nanobiosensor for the facile analysis of m6A RNA demethylase activity

Chem. Commun., 2020, Advance Article
DOI: 10.1039/C9CC10054G, Communication
Seo-Hee Yim, Hyung Jin Cha, Se-Jin Park, Yeajee Yim, Jae-Sung Woo, Dal-Hee Min
A fluorescent nanobiosensor for efficient quantitative analysis of the cancer-associated, m6A RNA demethylase ALKBH5 activity is developed, which shows high potential for robust anticancer drug screening against m6A RNA demethylase.
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Datum: 18.03.2020


Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00420K, Communication
Xue-Ya Gou, Bo-Sheng Zhang, Xin-Gang Wang, Wei-Yu Shi, Hong-Chao Liu, Yang An, Zhe Zhang, Yong-Min Liang
Visible-light-induced C–H phosphorylation of para-CAr–H and heteroarenes was realized using cost-effective RuCl3 as a catalyst.
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Datum: 18.03.2020


Correction: Fabrication of red blood cell membrane-camouflaged Cu2−xSe nanoparticles for phototherapy in the second near-infrared window

Chem. Commun., 2020, 56,3697-3697
DOI: 10.1039/D0CC90122A, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhou Liu, Jinquan Wang, Kangqiang Qiu, Xinxing Liao, Thomas W. Rees, Liangnian Ji, Hui Chao
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Datum: 18.03.2020


Palladium-catalyzed α-arylation of indolin-3-ones

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00435A, Communication
Yu-Hsuan Chang, Wan-Ling Peng, I-Chia Chen, Hsin-Yun Hsu, Yen-Ku Wu
A general route to C2-(hetero)arylated indolin-3-ones bearing a fully substituted α-center was established.
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Datum: 18.03.2020


Sporormielones A–E, bioactive novel C–C coupled orsellinic acid derivative dimers, and their biosynthetic origin

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00855A, Communication
Guo-Dong Chen, Dan Hu, Mei-Juan Huang, Jia Tang, Xiao-Xia Wang, Jian Zou, Jun Xie, Wei-Guang Zhang, Liang-Dong Guo, Xin-Sheng Yao, Ikuro Abe, Hao Gao
Sporormielones A–E, novel C–C coupled orsellinic acid derivative dimers containing tricyclic cores with a dimethylcyclopentenone unit, were isolated from Sporormiella sp., and their plausible biosynthetic mechanism was proposed.
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Datum: 18.03.2020


Isolation and characterization of a lithiated pyridine – aggregation in the solid state and in solution

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01355B, Communication
Nadja M. C. Schmidlin, Harald Scherer, Anke Hoffmann, Tobias Böttcher
The synthesis, isolation and characterization of the pyridyllithium compound 4-Li-2,6-Mes2py is reported. The crystal structure determination revealed a dimer in the solid state. In solution the pyridyllithium was identified as a monomer.
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Datum: 18.03.2020


The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00636J, Communication
Xiaoping Ma, Lu Zhang, Chengchao Xu, Qingxin Dong, Richard I. Walton, Zian Li, Honglong Shi, Genfu Chen, Jiangping Hu, Jianqi Li, Huaxin Yang
A new ‘seeding’ approach for the intercalation of protonated 1,10-phenanthroline into layered NiPS3 by using dopants as reaction active sites is proposed.
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Datum: 18.03.2020


Correction: Mitochondria-targeted Ir@AuNRs as bifunctional therapeutic agents for hypoxia imaging and photothermal therapy

Chem. Commun., 2020, 56,3698-3698
DOI: 10.1039/D0CC90121K, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Libing Ke, Cheng Zhang, Xinxing Liao, Kangqiang Qiu, Thomas W. Rees, Yu Chen, Zizhuo Zhao, Liangnian Ji, Hui Chao
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Datum: 18.03.2020


Correction: Thioamide quenching of intrinsic protein fluorescence

Chem. Commun., 2020, 56,3699-3699
DOI: 10.1039/D0CC90120B, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jacob M. Goldberg, Rebecca F. Wissner, Alyssa M. Klein, E. James Petersson
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Datum: 18.03.2020


Perylenediimides as more than just non-fullerene acceptors: versatile components in organic, hybrid and perovskite solar cells

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00337A, Feature Article
Nathalie Zink-Lorre, Enrique Font-Sanchis, Ángela Sastre-Santos, Fernando Fernández-Lázaro
The most recent advances in the incorporation of perylenediimides in photovoltaic devices are highlighted.
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Datum: 18.03.2020


Synthesis of CH2-linked α-galactosylceramide and its glucose analogues through glycosyl radical-mediated direct C-glycosylation

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00785D, Communication
Yu Hidaka, Noriaki Kiya, Makoto Yoritate, Kazuteru Usui, Go Hirai
Direct C-glycosylation of a conformationally constrained and stable C1-sp3 hybridized carbohydrate donor with a carefully designed sphingosine unit afforded the CH2-linked analogue of antitumor-active KRN7000 and its glucose congener.
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Datum: 17.03.2020


Iridium-catalyzed C–H amidation of s-tetrazines

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01647K, Communication
Huan Xiong, Yuang Gu, Shuning Zhang, Fengping Lu, Qun Ji, Lili Liu, Peixiang Ma, Guang Yang, Wei Hou, Hongtao Xu
Synthesis of ortho-amino substituted s-tetrazines by iridium-catalyzed C–H activation for bioconjugation and DNA-encoded library.
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Datum: 17.03.2020


Visible-light-driven dry reforming of methane using a semiconductor-supported catalyst

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00729C, Communication
Yohei Cho, Shusaku Shoji, Akira Yamaguchi, Takuya Hoshina, Takeshi Fujita, Hideki Abe, Masahiro Miyauchi
Dry reforming of methane (CH4 + CO2 → 2H2 + 2CO) was efficiently proceeded using Rh/TaON under visible light at low temperature.
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Datum: 17.03.2020


A halide perovskite as a catalyst to simultaneously achieve efficient photocatalytic CO2 reduction and methanol oxidation

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01176B, Communication
Guang-Xing Dong, Wen Zhang, Yan-Fei Mu, Ke Su, Min Zhang, Tong-Bu Lu
We have firstly demonstrated the photocatalytic utilization of a halide perovskite for combining reduction of CO2 with selective oxidation of methanol.
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Datum: 17.03.2020


Poly(dihydroxybenzoquinone): its high-density and robust charge storage capability in rechargeable acidic polymer–air batteries

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00660B, Communication
Kouki Oka, Shuhei Furukawa, Saki Murao, Tatsuya Oka, Hiroyuki Nishide, Kenichi Oyaizu
A rechargeable acidic polymer–air battery was firstly fabricated, which exhibited a long-lifetime of >500 cycles and high rate capabilities.
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Datum: 17.03.2020


Black phosphorus quantum dots as novel electrogenerated chemiluminescence emitters for the detection of Cu2+

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00661K, Communication
Jun Chen, Qiaoe Wang, Xuejiao Liu, Xu Chen, Lianying Wang, Wensheng Yang
Black phosphorus quantum dots with surface states and bandgap luminescence under NMP passivation are used for the detection of Cu2+.
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Datum: 17.03.2020


Design and synthesis of non-fullerene acceptors based on a quinoxalineimide moiety as the central building block for organic solar cells

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00896F, Communication
Chunguang Zhu, Kang An, Wenkai Zhong, Zhenye Li, Yu Qian, Xiaozhe Su, Lei Ying
The imide-functionalized quinoxaline unit allows for the incorporation of an additional solubilizing group without disturbing the planar structure of the core unit.
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Datum: 17.03.2020


Solid-phase synthesis of DNA-encoded libraries via an “aldehyde explosion” strategy

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01474E, Communication
Nicholas G. Paciaroni, John M. Ndungu, Thomas Kodadek
DNA-compatible conditions are reported for the on-resin transformation of aromatic aldehydes into many different functional groups.
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Datum: 17.03.2020


Cisplatin binds to the MDM2 RING finger domain and inhibits the ubiquitination activity

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00203H, Communication
Kaiming Cao, Xin Ding, Yaping Sheng, Yu Wang, Yangzhong Liu
Cisplatin binds to the RING finger of MDM2, leading to the zinc-release and protein unfolding, resulting in the inhibition of MDM2-mediated ubiquitination.
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Datum: 16.03.2020


A donor–acceptor type macrocycle: toward photolyzable self-assembly

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01350A, Communication
Tian Tian, Tingjuan Qian, Tingting Jiang, Yakui Deng, Xiaopei Li, Wei Yuan, Yulan Chen, Yi-Xuan Wang, Wenping Hu
A donor–acceptor macrocyclic host is reported, which shows efficient photodecomposition with electron-donating guests, yielding photolyzable host–guest complexes or aggregates.
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Datum: 16.03.2020


N–H cleavage vs. Werner complex formation: reactivity of cationic group 14 tetrelenes towards amines

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00875C, Communication
Dinh Cao Huan Do, Andrey V. Protchenko, M. Ángeles Fuentes, Jamie Hicks, Petra Vasko, Simon Aldridge
Two-coordinate cations [(N-nacnac)E]+ (E = Si, Ge, Sn) react differently towards ammonia/amines: simple adduct formation (Ge,Sn) contrasts with N–H activation (Si).
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Datum: 16.03.2020


CH4 conversion over Ni/HZSM-5 catalyst in the absence of oxygen: decomposition or dehydroaromatization?

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01345E, Communication
Yuebing Xu, Mengyao Chen, Bing Liu, Feng Jiang, Xiaohao Liu
Complete CH4 decomposition occurs over Ni clusters supported on HZSM-5 zeolite, while CH4 forms aromatics over Ni-exchanged sites on HZSM-5 with high selectivity, in the absence of O2.
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Datum: 16.03.2020


Synthesis of orthogonally reactive multilayered microcapsules

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00618A, Communication
Angana Borbora, Uttam Manna
An orthogonally chemically reactive microcapsule is derived from a single polymer following a layer-by-layer-deposition process, where a 1,4 conjugate addition reaction provided a basis for sequential deposition of a chemically reactive nanocomplex.
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Datum: 16.03.2020


Copper-catalysed Csp3–Csp cross-couplings between cyclobutanone oxime esters and terminal alkynes induced by visible light

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00988A, Communication
Binlin Zhao, Yixiao Wu, Yu Yuan, Zhuangzhi Shi
A novel transformation for the construction of Csp3–Csp bonds was achieved via a photo-induced copper-catalysed C–C bond cleavage.
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Datum: 14.03.2020


Silver-promoted synthesis of vinyl sulfones from vinyl bromides and sulfonyl hydrazides in water

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00784F, Communication
Ge Zhang, Jian-Guo Fu, Qian Zhao, Gui-Shan Zhang, Meng-Yao Li, Chen-Guo Feng, Guo-Qiang Lin
The synthesis of vinyl sulfones via silver-promoted cross-coupling of vinyl bromides with sulfonyl hydrazides was realized.
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Datum: 13.03.2020


Hierarchical porous and hydrophilic metal–organic frameworks with enhanced enzyme activity

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00748J, Communication
Hui Li, Xuedong Lu, Qiuhao Lu, Yi Liu, Xun Cao, Yuanyuan Lu, Xun He, Kequan Chen, Pingkai Ouyang, Weimin Tan
Metal–organic frameworks (MOFs) for enzyme encapsulation induced biomimetic mineralization are commonly microporous and hydrophobic, which result in a rather high mass transfer resistance of the reactants and restrain the enzyme catalytic activity.
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Datum: 12.03.2020


Hydrothermal synthesis of boron-free Zr-MWW and Sn-MWW zeolites as robust Lewis acid catalysts

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00483A, Communication
Zhiguo Zhu, Yejun Guan, Haikuo Ma, Hao Xu, Jin-gang Jiang, Hongying Lü, Peng Wu
Boron-free Zr-MWW and Sn-MWW metallosilicates were synthesized via dual structure-directing agent-facilitated crystallization, which demonstrated unique catalytic behavior in Meerwein–Pondorf–Verley and Baeyer–Villiger oxidation reactions.
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Datum: 11.03.2020


Water-soluble pH-switchable cobalt complexes for aqueous symmetric redox flow batteries

Chem. Commun., 2020, 56,3605-3608
DOI: 10.1039/D0CC00383B, Communication
Hao Wang, Sayed Youssef Sayed, Yuqiao Zhou, Brian C. Olsen, Erik J. Luber, Jillian M. Buriak
A water soluble cobalt complex with two redox couples that fall within the water splitting window can be applied as both the posolyte and negolyte in an aqueous symmetric redox flow battery.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.03.2020


Interfacial engineering of a polymer–MOF composite by in situ vitrification

Chem. Commun., 2020, 56,3609-3612
DOI: 10.1039/D0CC00664E, Communication
Rijia Lin, Jingwei Hou, Mengran Li, Zhanke Wang, Lei Ge, Shichun Li, Simon Smart, Zhonghua Zhu, Thomas D. Bennett, Vicki Chen
In situ vitrification of MOF within polymer can rigidify the polymer chains and remove interfacial defects, leading to a significantly enhanced membrane selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.03.2020


Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

Chem. Commun., 2020, 56,3681-3684
DOI: 10.1039/C9CC09638H, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
P. T. P. Ryan, P. L. Lalaguna, F. Haag, M. M. Braim, P. Ding, D. J. Payne, J. V. Barth, T.-L. Lee, D. P. Woodruff, F. Allegretti, D. A. Duncan
Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111).
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Datum: 02.03.2020


One-pot synthesis of heterodimeric agonists that activate the canonical Wnt signaling pathway

Chem. Commun., 2020, 56,3685-3688
DOI: 10.1039/D0CC00920B, Communication
Abhirup Mukherjee, Mark E. Stathos, Chad Varner, Ammar Arsiwala, Steven Frey, Yuge Hu, David M. Smalley, David V. Schaffer, Ravi S. Kane
Heterodimers synthesized by conjugating anti-Frizzled and anti-LRP6 Fabs using SpyTag–SpyCatcher chemistry activate the canonical Wnt signaling pathway.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.03.2020


Stepwise approach for sterically hindered Csp3–Csp3 bond formation by dehydrogenative O-alkylation and Lewis acid-catalyzed [1,3]-rearrangement towards the arylalkylcyclopentane skeleton of sesquiterpenes

Chem. Commun., 2020, 56,3621-3624
DOI: 10.1039/D0CC01017K, Communication
Ban Fujitani, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi
A stepwise dehydrogenative cross-coupling method was developed for the formation of sterically hindered Csp3–Csp3 bonds.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.02.2020


π-Conjugated polymeric phthalocyanine for the oxidative coupling of amines

Chem. Commun., 2020, 56,3637-3640
DOI: 10.1039/C9CC09422A, Communication
Haihong Wu, Yanwei Cao, Gangli Zhu, Dehong Zeng, Xiang Zhu, Jimin Du, Lin He
A cross-linked π-conjugated polymeric cobalt phthalocyanine material was prepared, showing high activity for the aerobic oxidative coupling of amines and recyclability.
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Datum: 27.02.2020


Carbon and carbon composites obtained using deep eutectic solvents and aqueous dilutions thereof

Chem. Commun., 2020, 56,3592-3604
DOI: 10.1039/D0CC00681E, Feature Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Gaspar Carrasco-Huertas, Rafael J. Jiménez-Riobóo, María Concepción Gutiérrez, María Luisa Ferrer, Francisco del Monte
Extending the “all-in-one” features of DESs to DES/H2O binary mixtures.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.02.2020


Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing

Chem. Commun., 2020, 56,3689-3692
DOI: 10.1039/D0CC00932F, Communication
Gavin A. Craig, Patrick Larpent, Hinano Urabe, Alexandre Legrand, Mickaele Bonneau, Shinpei Kusaka, Shuhei Furukawa
Cooperative gas uptake in metal–organic cages is tuned using supramolecular chemistry.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.02.2020


Two-photon probes for the endoplasmic reticulum: its detection in a live tissue by two-photon microscopy

Chem. Commun., 2020, 56,3657-3660
DOI: 10.1039/D0CC00236D, Communication
Ji-Woo Choi, Seung-Hye Choi, Seung Taek Hong, Mun Seok Kim, Seong Shick Ryu, Yeo Uk Yoon, Kyu Cheol Paik, Man So Han, Taebo Sim, Bong Rae Cho
BER-blue and FER-green can detect the endoplasmic reticulum in a live tissue by two-photon microscopy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.02.2020


Stabilizing synthetic DNA for long-term data storage with earth alkaline salts

Chem. Commun., 2020, 56,3613-3616
DOI: 10.1039/D0CC00222D, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
A. Xavier Kohll, Philipp L. Antkowiak, Weida D. Chen, Bichlien H. Nguyen, Wendelin J. Stark, Luis Ceze, Karin Strauss, Robert N. Grass
Mimicking fossil bone, a storage system involving earth alkali salts enables the preservation of digital data in DNA.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


Controlled synthesis of sugar-containing poly(ionic liquid)s

Chem. Commun., 2020, 56,3665-3668
DOI: 10.1039/C9CC09858E, Communication
Jing Chen, Die Li, Chunyang Bao, Qiang Zhang
A facile synthetic route is reported toward sugar-containing pyridinium-based poly(ionic liquid)s (PILs) for efficient killing of bacteria.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


‘Click’ conjugated porous polymer nanofilm with a large domain size created by a liquid/liquid interfacial protocol

Chem. Commun., 2020, 56,3677-3680
DOI: 10.1039/D0CC00360C, Communication
Joe Komeda, Ryo Shiotsuki, Amalia Rapakousiou, Ryota Sakamoto, Ryojun Toyoda, Kazuyuki Iwase, Masaki Tsuji, Kazuhide Kamiya, Hiroshi Nishihara
CuAAC between a triangular terminal alkyne and azide monomers at a water/dichloromethane interface generates a triazole-linked polymer nanofilm with a large aspect ratio. The nanofilm resists hydrolysis, and pyrolysis up to 300 °C.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


Ambient electrochemical NH3 synthesis from N2 and water enabled by ZrO2 nanoparticles

Chem. Commun., 2020, 56,3673-3676
DOI: 10.1039/C9CC10087C, Communication
Tong Xu, Dongwei Ma, Chengbo Li, Qian Liu, Siyu Lu, Abdullah M. Asiri, Chun Yang, Xuping Sun
ZrO2 nanoparticles act as an efficient electrocatalyst for ambient N2-to-NH3 fixation. In 0.1 M HCl, it attains a large NH3 yield rate of 24.74 μg h−1 mgcat.−1 with a faradaic efficiency of 5.0% at −0.45 V vs. RHE.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.02.2020


Expanding the BN-embedded PAH family: 4a-aza-12a-borachrysene

Chem. Commun., 2020, 56,3669-3672
DOI: 10.1039/C9CC09998K, Communication
Alberto Abengózar, Isabel Valencia, Guillermo G. Otárola, David Sucunza, Patricia García-García, Adrián Pérez-Redondo, Francisco Mendicuti, Juan J. Vaquero
Previously unknown 4a-aza-12a-borachrysene has been synthesized in only four steps.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 22.02.2020


Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(IV) phosphonate–phosphate material

Chem. Commun., 2020, 56,3653-3656
DOI: 10.1039/C9CC09254D, Communication
Vladimir I. Bakhmutov, Douglas W. Elliott, Gregory P. Wylie, Abraham Clearfield, Aida Contreras-Ramirez, Hong-Cai Zhou
Isotropic and anisotropic motions and molecular states of pyridine-d5, adsorbed on the surface within the pores of a layered Sn(IV) phosphonate–phosphate material (1) have been characterized thermodynamically and kinetically by solid-state NMR.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.02.2020


Sensitive and specific detection of tumour cells based on a multivalent DNA nanocreeper and a multiplexed fluorescence supersandwich

Chem. Commun., 2020, 56,3693-3696
DOI: 10.1039/C9CC08618H, Communication
Lei Luo, Wenshan Li, Dongliu Xiang, Yanyun Ma, Yuan Zhou, Yaqing Xu, Nandi Chen, Qing Wang, Jin Huang, Jianbo Liu, Xiaohai Yang, Kemin Wang
A self-assembled DNA nanostructure with improved binding affinity and fluorescence signal was developed for low abundance target cell detection.
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Datum: 21.02.2020


Near-infrared ratiometric self-assembled theranostic nanoprobe: imaging and tracking cancer chemotherapy

Chem. Commun., 2020, 56,3629-3632
DOI: 10.1039/D0CC00416B, Communication
Xinwei Tian, Zhao Li, Ning Ding, Jiahang Zhang
A novel near-infrared ratiometric fluorescent theranostic nanoprobe is applied for real-time fluorescence tracking and imaging cancer therapy in vivo and in situ.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.02.2020


Fluorinated cryptophane-A and porphyrin-based theranostics for multimodal imaging-guided photodynamic therapy

Chem. Commun., 2020, 56,3617-3620
DOI: 10.1039/D0CC00694G, Communication
Huaibin Zhang, Qiao Yu, Yu Li, Zhigang Yang, Xin Zhou, Shizhen Chen, Zhong-Xing Jiang
Herein, we developed fluorinated nanoemulsions with significantly enhanced in vitro and in vivo129Xe hyper-CEST MRI, 19F MRI and fluorescence imaging signals for selective and sensitive tumor detection and NIR-activated photodynamic therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.02.2020


Fabrication of a multifunctional hydrogel with a robust interface bioinspired by the structure of the dentogingival junction

Chem. Commun., 2020, 56,3633-3636
DOI: 10.1039/D0CC00907E, Communication
Xinyuan Xu, Hui Sun, Yaning Wang, Huijuan Cai, Dongyue Zhang, Hong Tan, Jianshu Li
A multifunctional hydrogel with a robust interface is fabricated with a “perforating fiber” structure bioinspired by the dentogingival junction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.02.2020


The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

Chem. Commun., 2020, 56,3649-3652
DOI: 10.1039/D0CC01195A, Communication
Xu-Ran Chen, Ling Yang, Yu-Ling Tan, Hong Yu, Chun-Yan Ni, Zheng Niu, Jian-Ping Lang
The solvent-induced isomerizations of Ag12 clusters with symmetry transformations were realized by changing the coordinated solvent molecules at room temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.02.2020


An improved fluorescent protein-based expression reporter system that utilizes bioluminescence resonance energy transfer and peptide-assisted complementation

Chem. Commun., 2020, 56,3625-3628
DOI: 10.1039/C9CC08664A, Communication
Taishi Kakizuka, Akira Takai, Keiko Yoshizawa, Yasushi Okada, Tomonobu M Watanabe
A peptide-assisted complementation strategy with screened peptides has succeeded to eliminate maturation delay of a bioluminescence resonant energy transfer reporter for gene expression monitoring.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


Engineering bromodomains with a photoactive amino acid by engaging ‘Privileged’ tRNA synthetases

Chem. Commun., 2020, 56,3641-3644
DOI: 10.1039/C9CC09891G, Communication
Shana Wagner, Babu Sudhamalla, Philip Mannes, Sushma Sappa, Sam Kavoosi, Debasis Dey, Sinan Wang, Kabirul Islam
An improved chemical synthesis, site-specific incorporation and enhanced photo-crosslinking ability of tmdF have been demonstrated in the context of protein–protein interactions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


Bio-inspired assembly in a phospholipid bilayer: effective regulation of electrostatic and hydrophobic interactions for plasma membrane specific probes

Chem. Commun., 2020, 56,3661-3664
DOI: 10.1039/D0CC00679C, Communication
Lei Shi, Kun Li, Yan-Hong Liu, Xin Liu, Qian Zhou, Qi Xu, Shan-Yong Chen, Xiao-Qi Yu
A simple assembly system of phospholipid bilayer and probes via electrostatic and hydrophobic interactions was constructed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.02.2020


An air-stable anionic two-dimensional semiconducting metal-thiolate network and its exfoliation into ultrathin few-layer nanosheets

Chem. Commun., 2020, 56,3645-3648
DOI: 10.1039/C9CC09349D, Communication
Qi Zeng, Lei Wang, Yitao Huang, Sai-Li Zheng, Yonghe He, Jun He, Wei-Ming Liao, Gang Xu, Matthias Zeller, Zhengtao Xu
Metal-thiolate networks are topical electronic materials, but hard to crystallize: this one makes big single crystals, and boasts small band gap, stable radical organic linkers, and facile exfoliation into nanosheets.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.02.2020


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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