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Chemical Communications - Abstracts
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC01457B, Communication
DOI: 10.1039/D2CC01457B, Communication
Bo Wu, Yuanzhi Zhong, Chen Jinmin, Xianmei Pan, Fan Xianglin, Chen Peier, Chenxing Fu, Caiwen Ou, Minsheng Chen
We reported a peptidic dual-targeting drug delivery platform towards the inflamed endothelial cells, which improved the anti-inflammatory ability of the loading drug (i.e., puerarin) in vitro and thus improving the...
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We reported a peptidic dual-targeting drug delivery platform towards the inflamed endothelial cells, which improved the anti-inflammatory ability of the loading drug (i.e., puerarin) in vitro and thus improving the...
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 02.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02635J, Communication
DOI: 10.1039/D2CC02635J, Communication
Keito Matsumoto, Yoshimitsu Tachi, Masatoshi Kozaki
A small fused polycyclic molecule containing a phenothiazine and diazapyrene skeleton as the donor and acceptor, respectively, has a redox potential similar to those of the corresponding donor and acceptor...
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A small fused polycyclic molecule containing a phenothiazine and diazapyrene skeleton as the donor and acceptor, respectively, has a redox potential similar to those of the corresponding donor and acceptor...
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Datum: 02.07.2022
‘Photo-Catalyzed Acetoxysulfoximination of Styrene with Sulfoximidoyl Thianthrenium Salt
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02542F, Communication
DOI: 10.1039/D2CC02542F, Communication
Yu-Ming Yang, Cairong Zhang, Hanlun Yang, Zhen-Yu Tang
We report design and synthesis of a redox-active thianthrenium-containing sulfoximination reagent. Photo-catalyzed acetoxysulfoximination of styrene with various functional groups is described. Preliminary mechanistic studies indicated that sulfoximination reagent (2aa) received...
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We report design and synthesis of a redox-active thianthrenium-containing sulfoximination reagent. Photo-catalyzed acetoxysulfoximination of styrene with various functional groups is described. Preliminary mechanistic studies indicated that sulfoximination reagent (2aa) received...
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Datum: 01.07.2022
Biological Roles of Sulfur Dioxide and Sulfite in regulation of Mitochondria Viscosity
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03420D, Communication
DOI: 10.1039/D2CC03420D, Communication
Weijie Zhang, yunxia lv, hongjun song, Fangjun Huo, Yongbin Zhang, Caixia Yin
Herein, a viscosity-sensitive molecular rotor and positively charged benzopyrylium salt has been developed for the visualization of the cross-talk behavior between mitochondrial viscosity and SO2/SO32-. Results shows that SO32- could...
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Herein, a viscosity-sensitive molecular rotor and positively charged benzopyrylium salt has been developed for the visualization of the cross-talk behavior between mitochondrial viscosity and SO2/SO32-. Results shows that SO32- could...
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Datum: 01.07.2022
Construction of Ni3+-rich nanograss arrays for booting alkaline water oxidation
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02083A, Communication
DOI: 10.1039/D2CC02083A, Communication
Ruirui Zhang, Jingce Bi, Junbiao Wu, Zhuopeng Wang, Xia Zhang, Yide Han
It remains a major challenge that the rational design high-efficiency electrocatalysts are applied to water oxidation in alkaline media. In this paper, Ni3+-rich nanograss-like Mo-doped Ni3S2/NiS/VS arrays grown on a...
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It remains a major challenge that the rational design high-efficiency electrocatalysts are applied to water oxidation in alkaline media. In this paper, Ni3+-rich nanograss-like Mo-doped Ni3S2/NiS/VS arrays grown on a...
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Datum: 01.07.2022
Programming the Self-assembly of Amphiphilic DNA Frameworks for Sequential Boolean Logic Functions
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03150G, Communication
DOI: 10.1039/D2CC03150G, Communication
Jianlei Shen, Chengpin Liang, Jielin Chen, Mingqiang Li, Qian Li, Chunhai Fan, Shihua Luo
Herein we examined the utilization of orthogonal chemical interaction to program the self-assembly of amphiphilic DNA frameworks (am-FNA). By finely controlling the reaction parameters such as ionic strength, the length...
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Herein we examined the utilization of orthogonal chemical interaction to program the self-assembly of amphiphilic DNA frameworks (am-FNA). By finely controlling the reaction parameters such as ionic strength, the length...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02774G, Communication
DOI: 10.1039/D2CC02774G, Communication
Jun Jiang, Xingcui Zhou, Ting Xiong
An efficient gold(I)-catalyzed redox cycloisomerization/nucleophilic addition/reduction reaction of o-nitroalkynes with various H-phosphorus oxides is established. Through the intramolecular redox cyclization of o-nitroalkynes and subsequent intermolecular nucleophilic addition/reduction with no external...
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An efficient gold(I)-catalyzed redox cycloisomerization/nucleophilic addition/reduction reaction of o-nitroalkynes with various H-phosphorus oxides is established. Through the intramolecular redox cyclization of o-nitroalkynes and subsequent intermolecular nucleophilic addition/reduction with no external...
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Datum: 01.07.2022
Genetic Encoding of ε-N-L-lactyllysine for Detecting Delactylase Activity in Living Cells
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02643K, Communication
DOI: 10.1039/D2CC02643K, Communication
Yanan Sun, Yanchi Chen, Yaxin Xu, Yuqing Zhang, Minghao Lu, Manjia Li, Liyan Zhou, Tao Peng
Lysine ε-N-L-lactylation is a newly discovered post-translational modification. Herein we present the genetic encoding of ε-N-L-lactyllysine in bacterial and mammalian cells, allowing preparation of site-specifically ε-N-L-lactylated recombinant proteins and construction...
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Lysine ε-N-L-lactylation is a newly discovered post-translational modification. Herein we present the genetic encoding of ε-N-L-lactyllysine in bacterial and mammalian cells, allowing preparation of site-specifically ε-N-L-lactylated recombinant proteins and construction...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03056J, Communication
DOI: 10.1039/D2CC03056J, Communication
Steven P Nolan, Kristof Van Hecke, Nikolaos V. Tzouras, Alberto Gobbo, Nestor Bracho, Subhrajyoti Bhandary, Georgios C Vougioukalakis, Savvas Chalkidis
Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use of activators to render the common [AuCl(L)] complexes catalytically active. Herein, the H-bonding donor properties...
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Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use of activators to render the common [AuCl(L)] complexes catalytically active. Herein, the H-bonding donor properties...
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Datum: 01.07.2022
Improving the stability of hybrid perovskite FAPbI3 by forming 3D/2D interface with organic spacers
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02396B, Communication
DOI: 10.1039/D2CC02396B, Communication
Yun-Sim Kim, Chol-Hyok Ri, Yun-Hyok Kye, Un-Gi Jong, Chol-Jun Yu
The interfaces composed of three-dimensional (3D) and 2D organic-inorganic hybrid formamidinium lead iodide (FAPbI3) linked by organic spacers (OSs) are studied using first-principles calculations. The OS cations with aromatic rings...
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The interfaces composed of three-dimensional (3D) and 2D organic-inorganic hybrid formamidinium lead iodide (FAPbI3) linked by organic spacers (OSs) are studied using first-principles calculations. The OS cations with aromatic rings...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02961H, Communication
DOI: 10.1039/D2CC02961H, Communication
Qian Wang, Fahui Li, Hekai Yang, Ying Wang, Wenshuo Ding, Fengxu Dai, Liuya Wei, Shuhua Cao, Weiguo Song
Herein, we designed a new nanoplatform for combined PDT/PTT/CDT through simultaneously self-supplying of H2O2 and depleting GSH using one single laser irradiation. The nanoplatform was capable of generating multiple reactive...
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Herein, we designed a new nanoplatform for combined PDT/PTT/CDT through simultaneously self-supplying of H2O2 and depleting GSH using one single laser irradiation. The nanoplatform was capable of generating multiple reactive...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03338K, Communication
DOI: 10.1039/D2CC03338K, Communication
Darío Coto, Iratxe Barbolla, Ruben Vicente
Silylcyclopropenes are employed as precursors of α-silyl vinyl carbenes and trapped with alkenes. Cyclopropylsilanes were obtained in good yields with ample scope and complete regio- and diastereoselectivity. Stereoretentive protodesilylations enabled...
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Silylcyclopropenes are employed as precursors of α-silyl vinyl carbenes and trapped with alkenes. Cyclopropylsilanes were obtained in good yields with ample scope and complete regio- and diastereoselectivity. Stereoretentive protodesilylations enabled...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02784D, Communication
DOI: 10.1039/D2CC02784D, Communication
Minghao Feng, Lea Madegard, Margaux Riomet, Manon Louis, Pier Alexandre Champagne, Gregory Pieters, Davide Audisio, Frederic Taran
Herein, we describe a methodology for iminosydnone chlorination and we demonstrate the high beneficial effect of this modification on the reactivity of these mesoionic dipoles in strain-promoted cycloaddition reactions. Exploiting...
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Herein, we describe a methodology for iminosydnone chlorination and we demonstrate the high beneficial effect of this modification on the reactivity of these mesoionic dipoles in strain-promoted cycloaddition reactions. Exploiting...
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Datum: 01.07.2022
Rapid Approach to Cationic Organic Triflates Based on Flash Electrolysis in Flow
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02344J, Communication
DOI: 10.1039/D2CC02344J, Communication
Masahiro Takumi, Hodaka Sakaue, Daiki Shibasaki, Aiichiro Nagaki
Flash (extremely fast) electrolysis in flow electrochemical reactor realized rapid generation and efficient utilization of highly unstable arylbis(arylthio)sulfonium triflates. This enabled rapid access to various organic triflates such as vinyl...
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Flash (extremely fast) electrolysis in flow electrochemical reactor realized rapid generation and efficient utilization of highly unstable arylbis(arylthio)sulfonium triflates. This enabled rapid access to various organic triflates such as vinyl...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02658A, Feature Article
DOI: 10.1039/D2CC02658A, Feature Article
Hao Ge, Yasutaka Kuwahara, Hiromi Yamashita
The surface plasmon resonance (SPR) of noble metals has been investigated for decades for applications in various catalysis reactions and optical research, but its development has been hampered by inefficient...
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The surface plasmon resonance (SPR) of noble metals has been investigated for decades for applications in various catalysis reactions and optical research, but its development has been hampered by inefficient...
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Datum: 01.07.2022
OaAEP1-mediated PNA-protein conjugation enables erasable imaging of membrane protein
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02153F, Communication
DOI: 10.1039/D2CC02153F, Communication
Zhangwei Lu, Yutong Liu, Yibing Deng, Bin Jia, Xuan Ding, Peng Zheng, Zhe Li
We report the use of a protein ligase to covalently ligate a protein to a peptide nucleic acid (PNA). The rapid ligation demands only an N-terminal GL dipeptide in target...
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We report the use of a protein ligase to covalently ligate a protein to a peptide nucleic acid (PNA). The rapid ligation demands only an N-terminal GL dipeptide in target...
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Datum: 01.07.2022
EPR based in situ enzymatic activity detection of endogenous caspase-3 in apoptosis cell lysates
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02361J, Communication
DOI: 10.1039/D2CC02361J, Communication
Aokun Liu, Jian Kuang, Yemian Zhou, An Xu, Changlin Tian, Lu Yu
Caspase-3 plays vital role in cell apoptosis and related diseases. Detection and characterization of endogenous active caspase-3 are of immense value not only for mechanism studies of apoptosis but also...
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Caspase-3 plays vital role in cell apoptosis and related diseases. Detection and characterization of endogenous active caspase-3 are of immense value not only for mechanism studies of apoptosis but also...
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Datum: 01.07.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03339A, Communication
DOI: 10.1039/D2CC03339A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dean D Roberts, Mark G McLaughlin
The regio and stereoselective hydrosilylation of a variety of homopropargylic scaffolds is described. The reaction is tolerant to a variety of sterically and electronically varied substrates, affording only the E-vinyl...
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The regio and stereoselective hydrosilylation of a variety of homopropargylic scaffolds is described. The reaction is tolerant to a variety of sterically and electronically varied substrates, affording only the E-vinyl...
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Datum: 30.06.2022
An activity-based probe targeting the streptococcal virulence factor C5a peptidase
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01517J, Communication
DOI: 10.1039/D2CC01517J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sankarganesh Krishnamoorthy, Andrea K. Steiger, William C. Nelson, Robert G. Egbert, Aaron T. Wright
A selective activity-based probe for C5a peptidase profiles pathogenic streptococci.
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A selective activity-based probe for C5a peptidase profiles pathogenic streptococci.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Datum: 30.06.2022
Efficient and Reusable Catalysis of Benzylic C-H Oxidation over Layered [Co5(OH)6]4+ Derivatives
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02424A, Communication
DOI: 10.1039/D2CC02424A, Communication
Wen Ma, Chengdong Peng, Xueling Song, Lu Zhang, Honghan Fei
Aerobic oxidation of benzylic C(sp3)-H bonds in a green and heterogeneous manner is a major target in organic catalysis. Herein, we report the synthesis of 3D coordination polymers containing [Co5(OH)6]4+...
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Aerobic oxidation of benzylic C(sp3)-H bonds in a green and heterogeneous manner is a major target in organic catalysis. Herein, we report the synthesis of 3D coordination polymers containing [Co5(OH)6]4+...
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Datum: 30.06.2022
Prediction of pH in multiphase multicomponent systems with ePC-SAFT advanced
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02943J, Communication
DOI: 10.1039/D2CC02943J, Communication
Open Access  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Moreno Ascani, Daniel Pabsch, Marcel Klinksiek, Nicolas Gajardo-Parra, Gabriele Sadowski, Christoph Held
Proton activity, which is usually expressed as pH value, is among the most important properties in the design of chemical and biochemical processes as it determines the dissociation of species...
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Proton activity, which is usually expressed as pH value, is among the most important properties in the design of chemical and biochemical processes as it determines the dissociation of species...
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Datum: 30.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02574D, Communication
DOI: 10.1039/D2CC02574D, Communication
Soumitra Maity, Apurba Samanta, Shyamal Pramanik, Subhashis Mondal
Organic photoredox-catalyzed alkylamination of olefins is performed with alkyl halides and nitrile solvent by blocking the traditional photoredox-ATRA process with Zn(OAc)2. A range of carbon-centered radicals (α-alkylcarbonyl, benzyl, cyanomethyl) are...
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Organic photoredox-catalyzed alkylamination of olefins is performed with alkyl halides and nitrile solvent by blocking the traditional photoredox-ATRA process with Zn(OAc)2. A range of carbon-centered radicals (α-alkylcarbonyl, benzyl, cyanomethyl) are...
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Datum: 30.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03084E, Communication
DOI: 10.1039/D2CC03084E, Communication
Ming-Hao Liu, Wan-tong Yu, Xiao-Yun Yang, Yue-Ying Li, Yan Zhang, Chun-Yang Zhang
We develop a simple and rapid mix-and-read assay for sensitive detection of O6-methylguanine DNA methyltransferase (MGMT) activity based on exonuclease III-assisted signal amplification at absolutely isothermal conditions (37 °C). This...
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We develop a simple and rapid mix-and-read assay for sensitive detection of O6-methylguanine DNA methyltransferase (MGMT) activity based on exonuclease III-assisted signal amplification at absolutely isothermal conditions (37 °C). This...
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Datum: 30.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02354G, Communication
DOI: 10.1039/D2CC02354G, Communication
Shumao Wang, Haodan Guo, Jinpeng Wu, Yan Lei, Xiangrong Li, Yanyan Fang, Yuhua Dai, Wanchun Xiang, Yuan Lin
A high-conductivity thiocyanate ionic liquid (EMIMSCN) was introduced into perovskite solar cells for the first time. The high conductivity of EMIMSCN ensures adequate supply of free SCN- anions and EMIM+...
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A high-conductivity thiocyanate ionic liquid (EMIMSCN) was introduced into perovskite solar cells for the first time. The high conductivity of EMIMSCN ensures adequate supply of free SCN- anions and EMIM+...
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Datum: 30.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC01948E, Communication
DOI: 10.1039/D2CC01948E, Communication
Weinan Zhao, Min Wang, Chen Zhang, Shiguo Sun, Yongqian Xu
Chemotherapy assisted with carbon monoxide (CO) gas therapy is an emerging powerful cancer therapeutic modality. However, the effective delivery and controlled release of CO in tumor cells remain a challenge....
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Chemotherapy assisted with carbon monoxide (CO) gas therapy is an emerging powerful cancer therapeutic modality. However, the effective delivery and controlled release of CO in tumor cells remain a challenge....
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Datum: 30.06.2022
Single Atoms (Pt, Ir and Rh) Anchored on Activated NiCo LDH for Alkaline Hydrogen Evolution Reaction
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02732A, Communication
DOI: 10.1039/D2CC02732A, Communication
Binbin Fan, Haozhi Wang, Xiaopeng Han, Yida Deng, Wenbin Hu
Here, we report the synthesis of activated NiCo LDH to immobilize Pt, Ir and Rh single atoms for hydrogen evolution reaction. The Pt/A-NiCo LDH electrocatalyst exhibits the highest catalytic ability...
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Here, we report the synthesis of activated NiCo LDH to immobilize Pt, Ir and Rh single atoms for hydrogen evolution reaction. The Pt/A-NiCo LDH electrocatalyst exhibits the highest catalytic ability...
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Datum: 30.06.2022
Barrier-free liquid condensates of nanocatalysts as effective concentrators of catalysis
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03111F, Communication
DOI: 10.1039/D2CC03111F, Communication
Silky Bedi, Gaurav Kumar, S M ROSE, Sabyasachi Rakshit, Sharmistha Sinha
Traditional methods of molecular confinement have physicochemical barriers that restricts the free passage of substrates/products. Here, we explored the liquid-liquid phase separation as a method to restrain protein-metal nanocomposites within...
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Traditional methods of molecular confinement have physicochemical barriers that restricts the free passage of substrates/products. Here, we explored the liquid-liquid phase separation as a method to restrain protein-metal nanocomposites within...
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Datum: 29.06.2022
[3]Foldarotaxane-Mediated Synthesis of an Improbable [2]Rotaxane
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03066G, Communication
DOI: 10.1039/D2CC03066G, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Victor Koehler, Maxime Gauthier, Chenhao Yao, Karine Fournel-Marotte, Philip Waeles, Brice Kauffmann, Ivan Huc, Frédéric Coutrot, Yann Ferrand
The wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane enforced the sliding and the sequestration of the surrounding macrocycle around a part of the axle for which...
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The wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane enforced the sliding and the sequestration of the surrounding macrocycle around a part of the axle for which...
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Datum: 29.06.2022
Iron ore production by using a new Gemini surfactant at 273K
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02705D, Communication
DOI: 10.1039/D2CC02705D, Communication
Zhiqiang Huang, Wenyuan Li, Shuyi Shuai, Shiyong Zhang, Hongling Wang, Rukuan Liu, Cheng Chen, Xinyang Yu, Guichun He, Weng Fu
Herein we present a Gemini surfactant can efficiently separate magnetite from quartz by reverse froth flotation to produce iron ore at 273 K. Achieving the obviously superior flotation performance (TFe...
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Herein we present a Gemini surfactant can efficiently separate magnetite from quartz by reverse froth flotation to produce iron ore at 273 K. Achieving the obviously superior flotation performance (TFe...
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Datum: 29.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02469A, Communication
DOI: 10.1039/D2CC02469A, Communication
Kang Zhao, Hongli Wang, Xinzhi Wang, Xinjiang Cui, Feng Shi
A biphosphine copolymer catalyst with in situ encapsulated single-site Rh was developed and applied in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity.
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A biphosphine copolymer catalyst with in situ encapsulated single-site Rh was developed and applied in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Datum: 29.06.2022
High performance transition metal-based electrocatalysts for green hydrogen production
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02423C, Feature Article
DOI: 10.1039/D2CC02423C, Feature Article
Hee Ryeong Kwon, Hoonkee Park, Sang Eon Jun, Sungkyun Choi, Ho Won Jang
Focusing on catalysts based on metal alloys, LDH, TMDs, and SACs, researches about high-efficiency hydrogen production will be introduced.
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Focusing on catalysts based on metal alloys, LDH, TMDs, and SACs, researches about high-efficiency hydrogen production will be introduced.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Datum: 29.06.2022
Probing the Self-assembly Process of Amphiphilic Tetrahedral DNA Frameworks
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03451D, Communication
DOI: 10.1039/D2CC03451D, Communication
Jianlei Shen, Chengpin Liang, Jielin Chen, Mingqiang Li, Zhilei Ge, Chunhai Fan
Herein we utilized the thermal hysteresis method to directly probe the self-assembly process of amphiphilic DNA nanostructures, with the use of amphiphilic tetrahedral DNA framework (am-TDF) as a model system....
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Herein we utilized the thermal hysteresis method to directly probe the self-assembly process of amphiphilic DNA nanostructures, with the use of amphiphilic tetrahedral DNA framework (am-TDF) as a model system....
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Datum: 29.06.2022
Configurational ligand isomerism in conjoined-cages
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02837A, Communication
DOI: 10.1039/D2CC02837A, Communication
Hareesha Dasary, Moumita Sarkar, Dillip Kumar Chand
Double-decker shaped conjoined-cages of Pd3L4 formulation are prepared via self-assembly of Pd(II) with a set of three regioisomeric tridentate ligands. Alongside the targeted double-decker cage, unprecedented hour-glass shaped conjoined-cages of...
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Double-decker shaped conjoined-cages of Pd3L4 formulation are prepared via self-assembly of Pd(II) with a set of three regioisomeric tridentate ligands. Alongside the targeted double-decker cage, unprecedented hour-glass shaped conjoined-cages of...
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Datum: 29.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02852B, Communication
DOI: 10.1039/D2CC02852B, Communication
Hairong Lyu, Zuowei Xie
A unique approach to vertex‐selective catalytic B−H amination at either B(3)‐ or B(4)‐position in o-carboranes has been developed. Using different transition metal catalysts, dehydrogenative BH/NH cross-coupling of o-carboranes and free...
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A unique approach to vertex‐selective catalytic B−H amination at either B(3)‐ or B(4)‐position in o-carboranes has been developed. Using different transition metal catalysts, dehydrogenative BH/NH cross-coupling of o-carboranes and free...
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Datum: 29.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02846H, Communication
DOI: 10.1039/D2CC02846H, Communication
Xinghua Liu, Yujing Shen, Cheng Lu, Yongchan Jian, Shuangshuang Xia, Zhaoliang Gao, Yihan Zheng, Yuanyuan An, Yubin Wang
A photo-induced transition-metal-free regioselective hydroborylation of α,β-unsaturated carbonyl compounds is developed. The PhSSPh reagent was employed as the photocatalyst, and NHC-BH3 was used as the boron source. This transformation shows...
The content of this RSS Feed (c) The Royal Society of Chemistry
A photo-induced transition-metal-free regioselective hydroborylation of α,β-unsaturated carbonyl compounds is developed. The PhSSPh reagent was employed as the photocatalyst, and NHC-BH3 was used as the boron source. This transformation shows...
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Datum: 29.06.2022
Photoresponsive proton conduction in Zr-based metal-organic frameworks using the photothermal effect
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02470E, Communication
DOI: 10.1039/D2CC02470E, Communication
Mingfeng Qin, Chang-Yu Wang, Song-Song Bao, Li-Min Zheng
A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10-3 S·cm-1 at 25 °C and 95% RH,...
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A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10-3 S·cm-1 at 25 °C and 95% RH,...
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Datum: 28.06.2022
Dynamic Combinatorial Libraries of a Dimercapto-Pillar[5]arene
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02752F, Communication
DOI: 10.1039/D2CC02752F, Communication
Jinwen Luo, Yunlong Guo, Ping Li, Andrew C.-H. Sue, Chuyang Cheng
We report the synthesis and dynamic covalent chemistry (DCvC) of an A1/A2-dimercapto-functionalized pillar[5]arene (Di-SH-P5). The introduction of thiol moieties into this macrocyclic host makes it an effective building block for...
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We report the synthesis and dynamic covalent chemistry (DCvC) of an A1/A2-dimercapto-functionalized pillar[5]arene (Di-SH-P5). The introduction of thiol moieties into this macrocyclic host makes it an effective building block for...
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Datum: 28.06.2022
Effects of Sidechain Isomerism on Polymer-based Non-Covalent Protein Delivery
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02343A, Communication
DOI: 10.1039/D2CC02343A, Communication
Alfonso Barrios, Mario Milan Diaz, Elianny Perezo, Md Lokman Hossen, Prem Chapagain, Joong Ho Moon
We present the importance of functional group isomerism on intracellular protein delivery using polymers containing different isomeric side chains. While the physical properties of polymer/protein complexes are relatively similar, different...
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We present the importance of functional group isomerism on intracellular protein delivery using polymers containing different isomeric side chains. While the physical properties of polymer/protein complexes are relatively similar, different...
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Datum: 28.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02303B, Communication
DOI: 10.1039/D2CC02303B, Communication
Riccardo Pedrazzani, Emanuele Pinosa, Giulio Bertuzzi, MAGDA MONARI, Samuel Lauzon, Thierry Ollevier, Marco Bandini
A new [Au(I)] catalyzed intramolecular hydrocarboxylation of allenes is presented as a valuable synthetic route to oxazino-indolones. The employment of 3,5-(CF3)2-C6H3-ImPyAuSbF6 as the optimal catalyst (5 mol%) was necessary to...
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A new [Au(I)] catalyzed intramolecular hydrocarboxylation of allenes is presented as a valuable synthetic route to oxazino-indolones. The employment of 3,5-(CF3)2-C6H3-ImPyAuSbF6 as the optimal catalyst (5 mol%) was necessary to...
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Datum: 28.06.2022
Unveiling two antiaromatic s-indacenodicarbazole isomers with tuneable paratropicity
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02318K, Communication
DOI: 10.1039/D2CC02318K, Communication
Hemonta Kumar Saha, Dibyendu Mallick, Soumyajit Das
Linear and curved antiaromatic s-indacenodicarbazole isomers were synthesized and characterized to show tuneable strength of s-indacene paratropicity, as analyzed by NICS(1)zz and ACID (ring-current) calculations. The curved isomer showed a...
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Linear and curved antiaromatic s-indacenodicarbazole isomers were synthesized and characterized to show tuneable strength of s-indacene paratropicity, as analyzed by NICS(1)zz and ACID (ring-current) calculations. The curved isomer showed a...
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Datum: 28.06.2022
Near-Infrared Photothermally Activated DNA nanotweezers for Imaging ATP in Living Cells
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02791G, Communication
DOI: 10.1039/D2CC02791G, Communication
Xiao-Qiong Li, Dan Luo, Juan Song, Yi-Lei Jia, Juan Song, Hong-Yuan Chen, Jing-Juan Xu
By assembling nanotweezers with ATP-splitting aptamers on gold nanorods (AuT123L), we constructed a near-infrared-activated ATP sensing device that could time-controllably imaging ATP levels in living cells. By replacing the aptamers...
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By assembling nanotweezers with ATP-splitting aptamers on gold nanorods (AuT123L), we constructed a near-infrared-activated ATP sensing device that could time-controllably imaging ATP levels in living cells. By replacing the aptamers...
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Datum: 28.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02214A, Communication
DOI: 10.1039/D2CC02214A, Communication
Di Yuan, Ziwei Xu, Bingling Zhang, Xiong Yin, Jiqing Ye, Xiaole Zhou, Leyu Wang
We designed a novel ratiometric fluorescent probe P1-Leu with donor-acceptor-donor fluorophore for detection of Leucine aminopeptidase in lysosomes. P1-Leu exhibits lower detection limit than the ratiometric donor-π-acceptor probe, due to...
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We designed a novel ratiometric fluorescent probe P1-Leu with donor-acceptor-donor fluorophore for detection of Leucine aminopeptidase in lysosomes. P1-Leu exhibits lower detection limit than the ratiometric donor-π-acceptor probe, due to...
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Datum: 28.06.2022
Stereoselective Insertion of Cyclopropenes into Mg–Mg Bonds
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02931F, Communication
DOI: 10.1039/D2CC02931F, Communication
Open Access  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Feriel Rekhroukh, Linxing Zhang, Richard Y Kong, Andrew J P White, Mark Richard Crimmin
The reaction of cyclopropenes with compounds containing Mg–Mg bonds is reported. 1,2-Dimagnesiation occurs exclusively by syn-addition to the least hindered face of the alkene forming a single diastereomeric product. DFT...
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The reaction of cyclopropenes with compounds containing Mg–Mg bonds is reported. 1,2-Dimagnesiation occurs exclusively by syn-addition to the least hindered face of the alkene forming a single diastereomeric product. DFT...
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Datum: 28.06.2022
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02384A, Communication
DOI: 10.1039/D2CC02384A, Communication
Sayan Halder, Susmita Roy, Mudit Dixit, Chanchal Chakraborty
The carboxylic acid-containing terpyridine-based hydrogelator (TPPCA) is synthesized to afford self-assembly induced TPPCA hydrogel which was used as all-in-one electrochrome in electrochromic devices (ECDs) to demonstrate reversible transparent-to-black electrochromism with...
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The carboxylic acid-containing terpyridine-based hydrogelator (TPPCA) is synthesized to afford self-assembly induced TPPCA hydrogel which was used as all-in-one electrochrome in electrochromic devices (ECDs) to demonstrate reversible transparent-to-black electrochromism with...
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Datum: 28.06.2022
Polymerization-Like Mechanism for Fixation of CO2 with Epoxides by Multifunctional Organocatalysts
Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03409C, Communication
DOI: 10.1039/D2CC03409C, Communication
Mingan Chen, Hui Yang, Ming Wah Wong
The commonly accepted mechanism of CO2 fixation of epoxides to cyclic carbonates catalyzed by multifunctional non-halide organocatalysts is challenged by our computational DFT-D3 study, which revealed a new polymerization-like mechanism...
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The commonly accepted mechanism of CO2 fixation of epoxides to cyclic carbonates catalyzed by multifunctional non-halide organocatalysts is challenged by our computational DFT-D3 study, which revealed a new polymerization-like mechanism...
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Datum: 28.06.2022
La(III)-Catalysed degradation of polyesters to monomers via transesterifications
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02448A, Communication
DOI: 10.1039/D2CC02448A, Communication
Ryota Abe, Nobuyuki Komine, Kotohiro Nomura, Masafumi Hirano
Tris(acetylacetonato)lanthanum(III) (1 mol%) catalyses the degradation of poly(butylene succinate) (Mw = 90 700) by transesterification in MeOH at 90 °C for 4 h, thus affording dimethyl succinate (>99% yield) and 1,4-butanediol (98% yield).
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Tris(acetylacetonato)lanthanum(III) (1 mol%) catalyses the degradation of poly(butylene succinate) (Mw = 90 700) by transesterification in MeOH at 90 °C for 4 h, thus affording dimethyl succinate (>99% yield) and 1,4-butanediol (98% yield).
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Datum: 27.06.2022
The key role of concentrated Zn(OTF)2 electrolyte in the performance of aqueous Zn–S batteries
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02075K, Communication
DOI: 10.1039/D2CC02075K, Communication
Zhao Xu, Yan Zhang, Wenshan Gou, Mengmeng Liu, Yifei Sun, Xuguang Han, Wei Sun, Changming Li
In this communication, the electrolyte chemistry in aqueous Zn–S batteries was illustrated systematically.
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In this communication, the electrolyte chemistry in aqueous Zn–S batteries was illustrated systematically.
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Datum: 26.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02544B, Communication
DOI: 10.1039/D2CC02544B, Communication
Yanbin Sun, Kaixuan Yang, Zhiguo Zhu, Ting Su, Wanzhong Ren, Hongying Lü
A method for selective aerobic oxidation of HMF to FFCA over an Anderson-type POM (NH4)3H6CoMo6O24 catalyst in DESs was developed, which exhibited outstanding catalytic performance.
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A method for selective aerobic oxidation of HMF to FFCA over an Anderson-type POM (NH4)3H6CoMo6O24 catalyst in DESs was developed, which exhibited outstanding catalytic performance.
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Datum: 25.06.2022
Multi-functional metal–organic frameworks for detection and removal of water pollutions
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02738K, Feature Article
DOI: 10.1039/D2CC02738K, Feature Article
Yang Li, Jiandong Pang, Xian-He Bu
This feature article reviews the recent achievements in metal–organic frameworks (MOFs) as versatile advanced materials for multifunctional water treatment and prospects the current challenges and the future research trends.
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This feature article reviews the recent achievements in metal–organic frameworks (MOFs) as versatile advanced materials for multifunctional water treatment and prospects the current challenges and the future research trends.
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Datum: 24.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02017C, Communication
DOI: 10.1039/D2CC02017C, Communication
Takuma Umeda, Takeshi Kurome, Ayumu Sakatmoto, Kazuyuki Kubo, Tsutomu Mizuta, Seung Uk Son, Shoko Kume
Cu2O nanocubes were wrapped with an extremely uniform layer through self-controlled growth on their surface, improving their CO2 reduction selectivity.
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Cu2O nanocubes were wrapped with an extremely uniform layer through self-controlled growth on their surface, improving their CO2 reduction selectivity.
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Datum: 23.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03295C, Communication
DOI: 10.1039/D2CC03295C, Communication
Xinjian Deng, Ju Huang, Guangming Wang, Jiuyang Li, Xun Li, Chuanhu Lei, Kaka Zhang
Intermolecular charge transfer in organic dopant-matrix systems significantly facilitates intersystem crossing and consequently boosts room-temperature phosphorescence.
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Intermolecular charge transfer in organic dopant-matrix systems significantly facilitates intersystem crossing and consequently boosts room-temperature phosphorescence.
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Datum: 23.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02795J, Communication
DOI: 10.1039/D2CC02795J, Communication
Takahiro Ikeda, Tomiko M. Suzuki, Takeo Arai, Takeshi Morikawa
Ni-modified β-FeOOH nanorod cocatalysts efficiently utilised the N 2p holes in N-doped TiO2 upon visible light irradiation.
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Ni-modified β-FeOOH nanorod cocatalysts efficiently utilised the N 2p holes in N-doped TiO2 upon visible light irradiation.
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Datum: 23.06.2022
High entropy metal chalcogenides: synthesis, properties, applications and future directions
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01796B, Feature Article
DOI: 10.1039/D2CC01796B, Feature Article
Open Access  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mark A. Buckingham, Brendan Ward-O’Brien, Weichen Xiao, Yi Li, Jie Qu, David J. Lewis
In this perspective we assess the current status of high entropy metal chalcogenides, the synthetic techniques for them, the currently obtained properties and demonstrated applications and a discussion on the possible future directions.
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In this perspective we assess the current status of high entropy metal chalcogenides, the synthetic techniques for them, the currently obtained properties and demonstrated applications and a discussion on the possible future directions.
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Datum: 23.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02240K, Communication
DOI: 10.1039/D2CC02240K, Communication
Wenjun Han, Fan Fang, Yaqian Zhang, Xue Li, Tao Wang, Zhiyuan Su, Kun Chang
Transition metal ions facilitate the separation and transfer of holes, thereby enhancing the PEC performance of BiVO4.
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Transition metal ions facilitate the separation and transfer of holes, thereby enhancing the PEC performance of BiVO4.
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Datum: 22.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03009H, Communication
DOI: 10.1039/D2CC03009H, Communication
Dimitris Kalaitzakis, Ioannis Kampouropoulos, Manolis Sofiadis, Tamsyn Montagnon, Georgios Vassilikogiannakis
By harnessing an energy transfer process, new photocatalyzed [2 + 2]-cycloadditions occurring between γ-alkylidene–γ-lactams and unsaturated substrates have been developed.
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By harnessing an energy transfer process, new photocatalyzed [2 + 2]-cycloadditions occurring between γ-alkylidene–γ-lactams and unsaturated substrates have been developed.
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Datum: 22.06.2022
A flexible self-healing Zn3V2O7(OH)2·2H2O-based Zn-ion battery under continuous folding and twisting
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02561B, Communication
DOI: 10.1039/D2CC02561B, Communication
Yajun Zhu, Xirong Lin, Xin Jin, Tianli Han, Huigang Zhang, Jinyun Liu
A flexible self-healing Zn-ion battery composed of a Zn3V2O7(OH)2·2H2O nanosheet cathode working with a hydrogel electrolyte is developed, which displays a stable performance in different working conditions.
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A flexible self-healing Zn-ion battery composed of a Zn3V2O7(OH)2·2H2O nanosheet cathode working with a hydrogel electrolyte is developed, which displays a stable performance in different working conditions.
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Datum: 22.06.2022
Twisted push–pull disilenes obtained by direct 1,2-hydro/chloroborylation of a silylone
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02160A, Communication
DOI: 10.1039/D2CC02160A, Communication
Taichi Koike, Takeaki Iwamoto
Twisted 1-amino-2-boryl disilenes which feature highly polarized SiSi bonds were synthesized by the direct hydro/chloroborylation of a silylene-stabilized monatomic silicon complex.
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Twisted 1-amino-2-boryl disilenes which feature highly polarized SiSi bonds were synthesized by the direct hydro/chloroborylation of a silylene-stabilized monatomic silicon complex.
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Datum: 22.06.2022
Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02869G, Communication
DOI: 10.1039/D2CC02869G, Communication
Rubén Vicente, Eva Tudela, Miguel A. Rodríguez, Ángel L. Suárez-Sobrino, Alfredo Ballesteros
The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes.
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The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes.
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Datum: 22.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02383K, Communication
DOI: 10.1039/D2CC02383K, Communication
Hai-Long Qian, Zi-Han Wang, Jing Yang, Xiu-Ping Yan
The first amino-based 3D COF and its covalently bonded capillary were prepared via building-block exchange for GC separation of isomers.
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The first amino-based 3D COF and its covalently bonded capillary were prepared via building-block exchange for GC separation of isomers.
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Datum: 22.06.2022
Giant N-heterocyclic carbene-containing macrocycles for cobalt-catalysed hydroboration of alkynes
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02815H, Communication
DOI: 10.1039/D2CC02815H, Communication
Guoqi Zhang
Giant N-heterocyclic carbene-containing macrocycles larger than “Texas-sized” molecular boxes have been synthesized and applied to cobalt-catalysed syn-selective hydroboration of alkynes with good stereo- and regioselectivity.
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Giant N-heterocyclic carbene-containing macrocycles larger than “Texas-sized” molecular boxes have been synthesized and applied to cobalt-catalysed syn-selective hydroboration of alkynes with good stereo- and regioselectivity.
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Datum: 22.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03019E, Communication
DOI: 10.1039/D2CC03019E, Communication
Wen-jing Liu, Xinyi Zhang, Juan Hu, Chun-yang Zhang
We develop a label-free and self-circulated fluorescent biosensor to sensitively detect ten-eleven translocation 1 (TET1) activity in cancer cells.
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We develop a label-free and self-circulated fluorescent biosensor to sensitively detect ten-eleven translocation 1 (TET1) activity in cancer cells.
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Datum: 21.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01260J, Communication
DOI: 10.1039/D2CC01260J, Communication
Logan S. Breton, Gregory Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans-Conrad zur Loye
Single crystals of LnBS3 (Ln = La–Nd) were synthesized by the combined boron–chalcogen mixture and molten flux growth methods. SHG measurements confirmed the expectation that LaBS3 would exhibit a strong SHG response, measured at 1.5 × KDP.
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Single crystals of LnBS3 (Ln = La–Nd) were synthesized by the combined boron–chalcogen mixture and molten flux growth methods. SHG measurements confirmed the expectation that LaBS3 would exhibit a strong SHG response, measured at 1.5 × KDP.
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Datum: 21.06.2022
Integrating single Co sites into crystalline covalent triazine frameworks for photoreduction of CO2
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02481K, Communication
DOI: 10.1039/D2CC02481K, Communication
Xunliang Hu, Lirong Zheng, Shengyao Wang, Xiaoyan Wang, Bien Tan
Crystalline covalent triazine frameworks loaded with single Co sites show high activity for photocatalytic CO2 reduction.
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Crystalline covalent triazine frameworks loaded with single Co sites show high activity for photocatalytic CO2 reduction.
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Datum: 21.06.2022
Catalytic machinery in motion: controlling catalysis via speed
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02555H, Communication
DOI: 10.1039/D2CC02555H, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Emad Elramadi, Amit Ghosh, Isa Valiyev, Pronay Kumar Biswas, Thomas Paululat, Michael Schmittel
The speed and catalytic activity (with regard to a click reaction) of slider-on-deck systems, in which a biped exchanges between three copper(I) centres, is regulated by addition of brake stones.
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The speed and catalytic activity (with regard to a click reaction) of slider-on-deck systems, in which a biped exchanges between three copper(I) centres, is regulated by addition of brake stones.
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Datum: 21.06.2022
Efficient water splitting over a hybrid photocatalyst with (002) active facets and heterostructure
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02445D, Communication
DOI: 10.1039/D2CC02445D, Communication
Yinjuan Dong, Mengxue Chen, Xiaohu Li, Yu Feng, Bonan Li, Pengfei Feng, Congzhao Dong, Yong Ding
P-CdS@P-NiWOx photocatalyst was constructed using polyoxometalates as precursors via a pyrolysis–phosphidation strategy. The synergistic action of heterostructure and facet effect over P-CdS@P-NiWOx affords the good performance of the visible-light-driven water splitting.
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P-CdS@P-NiWOx photocatalyst was constructed using polyoxometalates as precursors via a pyrolysis–phosphidation strategy. The synergistic action of heterostructure and facet effect over P-CdS@P-NiWOx affords the good performance of the visible-light-driven water splitting.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 20.06.2022
Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02882D, Communication
DOI: 10.1039/D2CC02882D, Communication
Ziyang Dong, Meng-Yao Ma, Jiaxi Xu, Zhanhui Yang
As masked S-electrophilic thia-1,3-dipoles, 1,2,3-thiadiazoles undergo denitrogenative (3 + 2) umpolung transannulations with aryl isothiocyanates, regio- and stereoselectively.
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As masked S-electrophilic thia-1,3-dipoles, 1,2,3-thiadiazoles undergo denitrogenative (3 + 2) umpolung transannulations with aryl isothiocyanates, regio- and stereoselectively.
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Datum: 20.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02114E, Communication
DOI: 10.1039/D2CC02114E, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saly Hawila, Ahmad Abdallah, Jean-Luc Rukemampunzi, Alexandra Fateeva, Gilles Ledoux, Régis Debord, Stéphane Paihlès, Nathalie Guillou, Florian Massuyeau, Romain Gautier, Adel Mesbah, Aude Demessence
A neutral coordination polymer made of Ag(I) and 1,3-benzenedithiolate, [Ag2(1,3-BDT)]n, displays both photoluminescence properties and a second harmonic generation signal.
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A neutral coordination polymer made of Ag(I) and 1,3-benzenedithiolate, [Ag2(1,3-BDT)]n, displays both photoluminescence properties and a second harmonic generation signal.
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Datum: 20.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03002K, Communication
DOI: 10.1039/D2CC03002K, Communication
Jing Xiang, Jiang Zhu, Miaomiao Zhou, Lu-Lu Liu, Li-Xin Wang, Min Peng, Bi-Shun Hou, Shek-Man Yiu, Wai-Pong To, Chi-Ming Che, Kai-Chung Lau, Tai-Chu Lau
The photoreactions of OsN and dihydroxybenzenes lead to C–O bond cleavage of H2Q/H2Cat, accompanied by the conversion of the coordinated CN− into CO.
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The photoreactions of OsN and dihydroxybenzenes lead to C–O bond cleavage of H2Q/H2Cat, accompanied by the conversion of the coordinated CN− into CO.
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Datum: 20.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02671F, Communication
DOI: 10.1039/D2CC02671F, Communication
Fei Gao, Annai Liu, Wei Tan, Bing Hu, Ruihan Gong, Xing Cheng, Fudong Liu, Ge Chen, Lin Dong
We report that Pt single atoms embedded on a disordered TiO2 surface have a weaker affinity for CO than those supported on a perfect TiO2 surface, thus generating much better CO oxidation activity.
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We report that Pt single atoms embedded on a disordered TiO2 surface have a weaker affinity for CO than those supported on a perfect TiO2 surface, thus generating much better CO oxidation activity.
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Datum: 20.06.2022
Substitution at boron in BODIPYs
Chem. Commun., 2022, 58,7351-7359
DOI: 10.1039/D2CC02362H, Feature Article
DOI: 10.1039/D2CC02362H, Feature Article
Rosinah Liandrah Gapare, Alison Thompson
BODIPYs provide tunable electronic properties key to many applications. This article highlights structural modification at boron.
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BODIPYs provide tunable electronic properties key to many applications. This article highlights structural modification at boron.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 20.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01864K, Communication
DOI: 10.1039/D2CC01864K, Communication
Shangshang Zhang, Shengkai Li, Haiyan Zhang, Daofeng Wen, Shuqi Zhang, Lun Li, Zhenjiang Liu
Phosphate-doped amorphous vanadium oxide cathode materials with a low energy barrier are more conducive to Zn2+ insertion/extraction.
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Phosphate-doped amorphous vanadium oxide cathode materials with a low energy barrier are more conducive to Zn2+ insertion/extraction.
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Datum: 18.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02276A, Communication
DOI: 10.1039/D2CC02276A, Communication
Chinmay K. Jena, Nagendra K. Sharma
Cinnamic acid, a benzenoid scaffold, is a building block of various natural products.
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Cinnamic acid, a benzenoid scaffold, is a building block of various natural products.
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Datum: 17.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02974J, Communication
DOI: 10.1039/D2CC02974J, Communication
Zhihao Su, Jionghao Huang, Runhao Wang, Yufei Zhang, Zili Liu, Haosen Fan
Nickel and manganese co-substitution in a hollow Prussian blue nanocubes has been successfully carried out via utilizing a high-concentration polymer template, with an ultrahigh capacity of 138.4 mA h g−1 at 0.05 A g−1 in an aqueous zinc-ion battery.
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Nickel and manganese co-substitution in a hollow Prussian blue nanocubes has been successfully carried out via utilizing a high-concentration polymer template, with an ultrahigh capacity of 138.4 mA h g−1 at 0.05 A g−1 in an aqueous zinc-ion battery.
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Datum: 17.06.2022
Photodegradation of carbonic anhydrase IX via a binding-enhanced ruthenium-based photosensitizer
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02337G, Communication
DOI: 10.1039/D2CC02337G, Communication
Liang Hao, Jie Wang, Zheng-Yin Pan, Zong-Wan Mao, Cai-Ping Tan
A binding-enhanced ruthenium-based photosensitizer is reported for photodegradation of carbonic anhydrase IX.
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A binding-enhanced ruthenium-based photosensitizer is reported for photodegradation of carbonic anhydrase IX.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 16.06.2022
Strategies toward anode stabilization in nonaqueous alkali metal–oxygen batteries
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02501A, Highlight
DOI: 10.1039/D2CC02501A, Highlight
Congcong Zhou, Kangkang Lu, Shiyu Zhou, Yihao Liu, Weiwei Fang, Yuyang Hou, Jilei Ye, Lijun Fu, Yuhui Chen, Lili Liu, Yuping Wu
This highlight demonstrates the challenges and latest progress in stabilizing the metal anode in nonaqueous alkali metal–oxygen batteries.
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This highlight demonstrates the challenges and latest progress in stabilizing the metal anode in nonaqueous alkali metal–oxygen batteries.
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Datum: 16.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02463B, Communication
DOI: 10.1039/D2CC02463B, Communication
Ge Meng, Tianran Wei, Weijia Liu, Wenbo Li, Shusheng Zhang, Wenxian Liu, Qian Liu, Haihong Bao, Jun Luo, Xijun Liu
A NiFe layered double hydroxide nanosheet array is designed as an efficient NORR catalyst for NH3 electrosynthesis with a maximal FE of 82% and the highest yield rate of 1586.7 μg h−1 mgcat.−1, exceeding most recently reported results.
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A NiFe layered double hydroxide nanosheet array is designed as an efficient NORR catalyst for NH3 electrosynthesis with a maximal FE of 82% and the highest yield rate of 1586.7 μg h−1 mgcat.−1, exceeding most recently reported results.
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Datum: 16.06.2022
A new access to diazaphospholes via cycloaddition–cycloreversion reactions on triazaphospholes
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02269A, Communication
DOI: 10.1039/D2CC02269A, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lea Dettling, Martin Papke, Julian A. W. Sklorz, Dániel Buzsáki, Zsolt Kelemen, Manuela Weber, László Nyulászi, Christian Müller
The [4+2] cycloaddition of a triazaphosphole with hexafluoro-2-butyne, followed by a cycloreversion reaction under elimination of pivaloyl nitrile, affords selectively a novel bis-CF3-substituted diazaphosphole in high yield.
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The [4+2] cycloaddition of a triazaphosphole with hexafluoro-2-butyne, followed by a cycloreversion reaction under elimination of pivaloyl nitrile, affords selectively a novel bis-CF3-substituted diazaphosphole in high yield.
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Datum: 15.06.2022
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01611G, Highlight
DOI: 10.1039/D2CC01611G, Highlight
Arti Ramani, Bhargav Desai, Bharatkumar Z. Dholakiya, Togati Naveen
Olefins and akynes are synthetically important building blocks in modern organic synthesis. This review highlights the recent developments in the direct functionalization of olefins and alkynes via photoinduced copper-based catalysis.
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Olefins and akynes are synthetically important building blocks in modern organic synthesis. This review highlights the recent developments in the direct functionalization of olefins and alkynes via photoinduced copper-based catalysis.
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Datum: 15.06.2022
A five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane
Chem. Commun., 2022, 58,7360-7363
DOI: 10.1039/D2CC02516G, Communication
DOI: 10.1039/D2CC02516G, Communication
Leonel Griego, Toby J. Woods, Liviu M. Mirica
We report the synthesis and characterization of an uncommon five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane.
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We report the synthesis and characterization of an uncommon five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane.
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Datum: 14.06.2022
Site-selective iodine atom transfer in fluorinated alkyl iodides via 1,5-hydrogen atom transfer
Chem. Commun., 2022, 58,7416-7418
DOI: 10.1039/D2CC02803D, Communication
DOI: 10.1039/D2CC02803D, Communication
Masahiro Abe, Yuka Yokoi, Aoi Hirata, Yumeno Matsuoka, Tetsutaro Kimachi, Kiyofumi Inamoto
The direct and selective functionalization of inert C–H bonds via intramolecular hydrogen atom transfer (HAT) is a powerful tool in organic synthesis. Herein, we designed an efficient iodine atom transfer in fluorinated alkyl iodides via 1,5-HAT.
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The direct and selective functionalization of inert C–H bonds via intramolecular hydrogen atom transfer (HAT) is a powerful tool in organic synthesis. Herein, we designed an efficient iodine atom transfer in fluorinated alkyl iodides via 1,5-HAT.
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Datum: 13.06.2022
Chem. Commun., 2022, 58,7368-7371
DOI: 10.1039/D2CC02159E, Communication
DOI: 10.1039/D2CC02159E, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Miyuki Tabata, Chattarika Khamhanglit, Sayo Kotaki, Yuji Miyahara
Detection concept of HER2 via an enzyme reaction using an ISFET pH sensor.
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Detection concept of HER2 via an enzyme reaction using an ISFET pH sensor.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 10.06.2022
Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions
Chem. Commun., 2022, 58,7431-7434
DOI: 10.1039/D2CC02068H, Communication
DOI: 10.1039/D2CC02068H, Communication
Niels A. Bonde, Markus Appel, Jacques Ollivier, Høgni Weihe, Jesper Bendix
Crystal field and hyperfine inhomogeneities from high-resolution inelastic neutron scattering spectroscopy.
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Crystal field and hyperfine inhomogeneities from high-resolution inelastic neutron scattering spectroscopy.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 10.06.2022
Mixed-metal calix[8]arene complexes: structure, and ring opening polymerisation studies
Chem. Commun., 2022, 58,7427-7430
DOI: 10.1039/D2CC02236B, Communication
DOI: 10.1039/D2CC02236B, Communication
Open Access  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tian Xing, Max Derbyshire, Mark R. J. Elsegood, Carl Redshaw
Combinations of group V alkoxides or tungsten oxyalkoxide salts with p-tert-butylcalix[8]areneH8 afford mixed-metal calixarenes capable of the ROP of ε-caprolactone.
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Combinations of group V alkoxides or tungsten oxyalkoxide salts with p-tert-butylcalix[8]areneH8 afford mixed-metal calixarenes capable of the ROP of ε-caprolactone.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 08.06.2022
Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography
Chem. Commun., 2022, 58,7380-7383
DOI: 10.1039/D2CC02438A, Communication
DOI: 10.1039/D2CC02438A, Communication
Open Access  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hosung Ki, Tae Wu Kim, Jiwon Moon, Jungmin Kim, Yunbeom Lee, Jun Heo, Kyung Hwan Kim, Qingyu Kong, Dmitry Khakhulin, Gemma Newby, Joonghan Kim, Jeongho Kim, Michael Wulff, Hyotcherl Ihee
Photoactivation mechanism of triosmium dodecacarbonyl is elucidated via time-resolved X-ray liquidography, identifying two pathways, vibrational relaxation and ligand dissociation.
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Photoactivation mechanism of triosmium dodecacarbonyl is elucidated via time-resolved X-ray liquidography, identifying two pathways, vibrational relaxation and ligand dissociation.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 08.06.2022
Chemoselective and enantioselective fluorescent identification of specific amino acid enantiomers
Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02363F, Feature Article
DOI: 10.1039/D2CC02363F, Feature Article
Lin Pu
Chiral fluorescent probes have been developed for chemoselective as well as enantioselective recognition of specific amino acid enantiomers including glutamic acid, aspartic acid, serine, histidine, lysine and tryptophan.
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Chiral fluorescent probes have been developed for chemoselective as well as enantioselective recognition of specific amino acid enantiomers including glutamic acid, aspartic acid, serine, histidine, lysine and tryptophan.
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Datum: 07.06.2022
Chem. Commun., 2022, 58,7423-7426
DOI: 10.1039/D2CC02775E, Communication
DOI: 10.1039/D2CC02775E, Communication
Qi Wang, Aijian Wang, Yuqin Dou, Xiaoliang Shen, M. Shire Sudi, Long Zhao, Weihua Zhu, Longhua Li
The prepared tin porphyrin axially-coordinated 2D covalent organic polymer exhibits excellent HER activity due to its unique structural properties, ranking among the best records reported recently.
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The prepared tin porphyrin axially-coordinated 2D covalent organic polymer exhibits excellent HER activity due to its unique structural properties, ranking among the best records reported recently.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 07.06.2022
CO2 capture by 1,2,3-triazole-based deep eutectic solvents: the unexpected role of hydrogen bonds
Chem. Commun., 2022, 58,7376-7379
DOI: 10.1039/D2CC02503E, Communication
DOI: 10.1039/D2CC02503E, Communication
Zonghua Wang, Congyi Wu, Ze Wang, Shaoze Zhang, Dezhong Yang
Hydrogen bonding is found to be a switch for the reaction between CO2 and the 1,2,3-triazole-based deep eutectic solvents.
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Hydrogen bonding is found to be a switch for the reaction between CO2 and the 1,2,3-triazole-based deep eutectic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 06.06.2022
Chem. Commun., 2022, 58,7400-7403
DOI: 10.1039/D2CC01207C, Communication
DOI: 10.1039/D2CC01207C, Communication
Guangzhao Yang, Xi Zhang, Shan Zhou, Wen Zhou, Chao Yin, Chen Xie, Quli Fan, Wei Huang
A multifunctional semiconducting nanoagonist with high photothermic conversion efficiency and radical generation ability was developed, which showed an excellent anticancer effect through NIR-II light-triggered combinational therapy.
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A multifunctional semiconducting nanoagonist with high photothermic conversion efficiency and radical generation ability was developed, which showed an excellent anticancer effect through NIR-II light-triggered combinational therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 06.06.2022
Enzyme-responsive hybrid prodrug of nitric oxide and hydrogen sulfide for heart failure therapy
Chem. Commun., 2022, 58,7396-7399
DOI: 10.1039/D2CC02267B, Communication
DOI: 10.1039/D2CC02267B, Communication
Qi Liu, Guangbo Ji, Yushu Chu, Tian Hao, Meng Qian, Qiang Zhao
Codelivery of nitric oxide and hydrogen sulfide from an enzyme-responsive hybrid prodrug provides potent therapeutic efficacy for heart failure.
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Codelivery of nitric oxide and hydrogen sulfide from an enzyme-responsive hybrid prodrug provides potent therapeutic efficacy for heart failure.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 06.06.2022
Post-translational site-specific protein azidolation with an azido pyridoxal derivative
Chem. Commun., 2022, 58,7408-7411
DOI: 10.1039/D2CC03051A, Communication
DOI: 10.1039/D2CC03051A, Communication
Baochuan Wang, Xun Li, Yiwan Wang, Xianxian Mao, Xiaojian Wang
An azido pyridoxal derivative was developed for post-translational site-specific protein azidolation.
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An azido pyridoxal derivative was developed for post-translational site-specific protein azidolation.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 06.06.2022
Albumin-mediated extracellular zinc speciation drives cellular zinc uptake
Chem. Commun., 2022, 58,7384-7387
DOI: 10.1039/D2CC02278H, Communication
DOI: 10.1039/D2CC02278H, Communication
Open Access  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.James P. C. Coverdale, Hugo A. van den Berg, Siavash Khazaipoul, Hannah E. Bridgewater, Alan J. Stewart, Claudia A. Blindauer
Fatty acids alter zinc speciation in plasma, increasing zinc influx into endothelial cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
Fatty acids alter zinc speciation in plasma, increasing zinc influx into endothelial cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 02.06.2022
A convenient and versatile SNAr-decarboxylation protocol for the construction of C(sp2)–C(sp3) bonds
Chem. Commun., 2022, 58,7435-7438
DOI: 10.1039/D2CC01551J, Communication
DOI: 10.1039/D2CC01551J, Communication
Alexander Burtea, Jacob DeForest, Neil Baldwin, Carolyn Leverett, Gary M. Gallego
A versatile and operationally simple one-pot procedure for the construction of C(sp2)-C(sp3) bonds via a nucleophilic aromatic substitution-decarboxylation sequence is described.
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A versatile and operationally simple one-pot procedure for the construction of C(sp2)-C(sp3) bonds via a nucleophilic aromatic substitution-decarboxylation sequence is described.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 02.06.2022
Enantioselective synthesis of acyclic monohydrosilanes by steric hindrance assisted C–H silylation
Chem. Commun., 2022, 58,7388-7391
DOI: 10.1039/D2CC02307E, Communication
DOI: 10.1039/D2CC02307E, Communication
Delong Mu, Shuqiong Pan, Xiaoyu Wang, Xiaoyun Liao, Yong Huang, Jiean Chen
Herein, a rhodium-catalyzed desymmetrization of dihydrosilanes with heterocyclic compounds via intermolecular dehydrogenative C–H silylation is developed.
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Herein, a rhodium-catalyzed desymmetrization of dihydrosilanes with heterocyclic compounds via intermolecular dehydrogenative C–H silylation is developed.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 02.06.2022
Chem. Commun., 2022, 58,7404-7407
DOI: 10.1039/D2CC02253B, Communication
DOI: 10.1039/D2CC02253B, Communication
Jin Zhang, Tao Li, Xue Li, Gaopeng Zhang, Shuai Fang, Wenxuan Yan, Xiangyang Li, Xiufang Yang, Yangmin Ma, Michal Szostak
We report palladium–BIAN–NHC chloro dimer complex, [Pd(BIAN–IPr)(μ-Cl)Cl]2. This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(μ-Cl)Cl]2, with the attractive structural features of the BIAN framework.
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We report palladium–BIAN–NHC chloro dimer complex, [Pd(BIAN–IPr)(μ-Cl)Cl]2. This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(μ-Cl)Cl]2, with the attractive structural features of the BIAN framework.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 02.06.2022
Designed graphite with an activated edge for fast-charging lithium-ion storage properties
Chem. Commun., 2022, 58,7372-7375
DOI: 10.1039/D2CC01927B, Communication
DOI: 10.1039/D2CC01927B, Communication
Peng Du, Bao Zhang, Liang Cao, Xing Ou
The special edge of graphite with the coexistence of extra channels and expanded layers is carefully designed to meet the standards of fast charging, and the material exhibits excellent rate performance and long-term cycling performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
The special edge of graphite with the coexistence of extra channels and expanded layers is carefully designed to meet the standards of fast charging, and the material exhibits excellent rate performance and long-term cycling performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 01.06.2022
Chem. Commun., 2022, 58,7419-7422
DOI: 10.1039/D2CC01757A, Communication
DOI: 10.1039/D2CC01757A, Communication
Marcos A. R. da Silva, Jéssica C. Gil, Nadezda V. Tarakina, Gelson T. S. T. Silva, José B. G. Filho, Klaus Krambrock, Markus Antonietti, Caue Ribeiro, Ivo F. Teixeira
Here we report a new record of the selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitride, it displayed a remarkable methanol production (2900 μmol g−1) in 4 hours.
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Here we report a new record of the selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitride, it displayed a remarkable methanol production (2900 μmol g−1) in 4 hours.
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Datum: 31.05.2022
MXenes in photomedicine: advances and prospects
Chem. Commun., 2022, 58,7336-7350
DOI: 10.1039/D2CC01694J, Highlight
DOI: 10.1039/D2CC01694J, Highlight
Siavash Iravani, Rajender S. Varma
The potentials of MXenes in photomedicine are deliberated, encompassing important challenges and future directions.
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The potentials of MXenes in photomedicine are deliberated, encompassing important challenges and future directions.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 30.05.2022
Chem. Commun., 2022, 58,7392-7395
DOI: 10.1039/D2CC01963A, Communication
DOI: 10.1039/D2CC01963A, Communication
Jian Song, Wen-Hua Zheng
A highly enantioselective kinetic resolution of racemic 1,3-amino alcohols via O-Acylation was achieved using a chiral organotin as the catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry
A highly enantioselective kinetic resolution of racemic 1,3-amino alcohols via O-Acylation was achieved using a chiral organotin as the catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 30.05.2022
Engineering the CuO–HfO2 interface toward enhanced CO2 electroreduction to C2H4
Chem. Commun., 2022, 58,7412-7415
DOI: 10.1039/D2CC01776H, Communication
DOI: 10.1039/D2CC01776H, Communication
Xin Li, Lifen Li, Lijun Wang, Qineng Xia, Leiduan Hao, Xinyu Zhan, Alex W. Robertson, Zhenyu Sun
We demonstrate tuning of the CuOx@HfO2 interface for greatly enhanced electrocatalytic CO2 reduction to produce C2H4.
The content of this RSS Feed (c) The Royal Society of Chemistry
We demonstrate tuning of the CuOx@HfO2 interface for greatly enhanced electrocatalytic CO2 reduction to produce C2H4.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 25.05.2022
Chem. Commun., 2022, 58,7364-7367
DOI: 10.1039/D2CC00560C, Communication
DOI: 10.1039/D2CC00560C, Communication
Mateusz Pawlak, Maciej Bagiński, Pablo Llombart, Dominik Beutel, Guillermo González-Rubio, Ewa Górecka, Carsten Rockstuhl, Józef Mieczkowski, Damian Pociecha, Wiktor Lewandowski
Liquid crystalline (LC) dimers formed helical nanofilaments depending on the parity of the alkyl linker, revealing an unusual odd–even effect. Doping LC with Au nanoparticles evidenced that helical pitch was regulated by the length of the linker.
The content of this RSS Feed (c) The Royal Society of Chemistry
Liquid crystalline (LC) dimers formed helical nanofilaments depending on the parity of the alkyl linker, revealing an unusual odd–even effect. Doping LC with Au nanoparticles evidenced that helical pitch was regulated by the length of the linker.
The content of this RSS Feed (c) The Royal Society of Chemistry
Datum: 05.05.2022
Category: Current Chemistry Research
Last update: 28.03.2018.
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