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Chemical Communications

Current research reports and chronological list of recent articles..




The international scientific journal Chemical Communicationsoffers urgent high quality communications from across the chemical sciences.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

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Additional research articles in the field of general chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Angewandte Chemie International Edition,

 - Chemical Monthly,

 - The Chemical Record,

 - Chemistry Central Journal,

 - Chemistry Letters,

 - Journal of the American Chemical Society,

 - Nature Chemistry.



Chemical Communications - Abstracts



A Dual-targeting Peptide Facilitates Targeting Anti-inflammation to Attenuate Atherosclerosis in ApoE-/- Mice

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC01457B, Communication
Bo Wu, Yuanzhi Zhong, Chen Jinmin, Xianmei Pan, Fan Xianglin, Chen Peier, Chenxing Fu, Caiwen Ou, Minsheng Chen
We reported a peptidic dual-targeting drug delivery platform towards the inflamed endothelial cells, which improved the anti-inflammatory ability of the loading drug (i.e., puerarin) in vitro and thus improving the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.07.2022


Fused Polycyclic Compound Containing Phenothiazine and Diazapyrene Skeletons with Weak D-A interactions

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02635J, Communication
Keito Matsumoto, Yoshimitsu Tachi, Masatoshi Kozaki
A small fused polycyclic molecule containing a phenothiazine and diazapyrene skeleton as the donor and acceptor, respectively, has a redox potential similar to those of the corresponding donor and acceptor...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.07.2022


‘Photo-Catalyzed Acetoxysulfoximination of Styrene with Sulfoximidoyl Thianthrenium Salt

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02542F, Communication
Yu-Ming Yang, Cairong Zhang, Hanlun Yang, Zhen-Yu Tang
We report design and synthesis of a redox-active thianthrenium-containing sulfoximination reagent. Photo-catalyzed acetoxysulfoximination of styrene with various functional groups is described. Preliminary mechanistic studies indicated that sulfoximination reagent (2aa) received...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Biological Roles of Sulfur Dioxide and Sulfite in regulation of Mitochondria Viscosity

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03420D, Communication
Weijie Zhang, yunxia lv, hongjun song, Fangjun Huo, Yongbin Zhang, Caixia Yin
Herein, a viscosity-sensitive molecular rotor and positively charged benzopyrylium salt has been developed for the visualization of the cross-talk behavior between mitochondrial viscosity and SO2/SO32-. Results shows that SO32- could...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Construction of Ni3+-rich nanograss arrays for booting alkaline water oxidation

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02083A, Communication
Ruirui Zhang, Jingce Bi, Junbiao Wu, Zhuopeng Wang, Xia Zhang, Yide Han
It remains a major challenge that the rational design high-efficiency electrocatalysts are applied to water oxidation in alkaline media. In this paper, Ni3+-rich nanograss-like Mo-doped Ni3S2/NiS/VS arrays grown on a...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Programming the Self-assembly of Amphiphilic DNA Frameworks for Sequential Boolean Logic Functions

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03150G, Communication
Jianlei Shen, Chengpin Liang, Jielin Chen, Mingqiang Li, Qian Li, Chunhai Fan, Shihua Luo
Herein we examined the utilization of orthogonal chemical interaction to program the self-assembly of amphiphilic DNA frameworks (am-FNA). By finely controlling the reaction parameters such as ionic strength, the length...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Gold-catalyzed redox cycloisomerization/nucleophilic addition/reduction: direct access to 2-phosphoryl indolin-3-ones

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02774G, Communication
Jun Jiang, Xingcui Zhou, Ting Xiong
An efficient gold(I)-catalyzed redox cycloisomerization/nucleophilic addition/reduction reaction of o-nitroalkynes with various H-phosphorus oxides is established. Through the intramolecular redox cyclization of o-nitroalkynes and subsequent intermolecular nucleophilic addition/reduction with no external...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Genetic Encoding of ε-N-L-lactyllysine for Detecting Delactylase Activity in Living Cells

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02643K, Communication
Yanan Sun, Yanchi Chen, Yaxin Xu, Yuqing Zhang, Minghao Lu, Manjia Li, Liyan Zhou, Tao Peng
Lysine ε-N-L-lactylation is a newly discovered post-translational modification. Herein we present the genetic encoding of ε-N-L-lactyllysine in bacterial and mammalian cells, allowing preparation of site-specifically ε-N-L-lactylated recombinant proteins and construction...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Hydrogen bonding-enabled gold catalysis: Ligand effects in gold-catalyzed cycloisomerizations in hexafluoroisopropanol (HFIP)

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03056J, Communication
Steven P Nolan, Kristof Van Hecke, Nikolaos V. Tzouras, Alberto Gobbo, Nestor Bracho, Subhrajyoti Bhandary, Georgios C Vougioukalakis, Savvas Chalkidis
Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use of activators to render the common [AuCl(L)] complexes catalytically active. Herein, the H-bonding donor properties...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Improving the stability of hybrid perovskite FAPbI3 by forming 3D/2D interface with organic spacers

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02396B, Communication
Yun-Sim Kim, Chol-Hyok Ri, Yun-Hyok Kye, Un-Gi Jong, Chol-Jun Yu
The interfaces composed of three-dimensional (3D) and 2D organic-inorganic hybrid formamidinium lead iodide (FAPbI3) linked by organic spacers (OSs) are studied using first-principles calculations. The OS cations with aromatic rings...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Simultaneously Self-supply of H2O2 and GSH-depleted Intracellular Oxidative Stress for Enhanced Photodynamic /Photothermal /Chemodynamic Therapy

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02961H, Communication
Qian Wang, Fahui Li, Hekai Yang, Ying Wang, Wenshuo Ding, Fengxu Dai, Liuya Wei, Shuhua Cao, Weiguo Song
Herein, we designed a new nanoplatform for combined PDT/PTT/CDT through simultaneously self-supplying of H2O2 and depleting GSH using one single laser irradiation. The nanoplatform was capable of generating multiple reactive...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Catalytic Cyclopropanation Reactions with α-Silyl-, Germanyl- and Stannyl Carbenes Generated from Cyclopropenes

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03338K, Communication
Darío Coto, Iratxe Barbolla, Ruben Vicente
Silylcyclopropenes are employed as precursors of α-silyl vinyl carbenes and trapped with alkenes. Cyclopropylsilanes were obtained in good yields with ample scope and complete regio- and diastereoselectivity. Stereoretentive protodesilylations enabled...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Selective Chlorination of Iminosydnones for Fast Release of Amide, Sulfonamide and Urea-Containing Drugs

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02784D, Communication
Minghao Feng, Lea Madegard, Margaux Riomet, Manon Louis, Pier Alexandre Champagne, Gregory Pieters, Davide Audisio, Frederic Taran
Herein, we describe a methodology for iminosydnone chlorination and we demonstrate the high beneficial effect of this modification on the reactivity of these mesoionic dipoles in strain-promoted cycloaddition reactions. Exploiting...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Rapid Approach to Cationic Organic Triflates Based on Flash Electrolysis in Flow

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02344J, Communication
Masahiro Takumi, Hodaka Sakaue, Daiki Shibasaki, Aiichiro Nagaki
Flash (extremely fast) electrolysis in flow electrochemical reactor realized rapid generation and efficient utilization of highly unstable arylbis(arylthio)sulfonium triflates. This enabled rapid access to various organic triflates such as vinyl...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Development of Defective Molybdenum Oxides for Photocatalysis, Thermal Catalysis, and Photothermal Catalysis

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02658A, Feature Article
Hao Ge, Yasutaka Kuwahara, Hiromi Yamashita
The surface plasmon resonance (SPR) of noble metals has been investigated for decades for applications in various catalysis reactions and optical research, but its development has been hampered by inefficient...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


OaAEP1-mediated PNA-protein conjugation enables erasable imaging of membrane protein

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02153F, Communication
Zhangwei Lu, Yutong Liu, Yibing Deng, Bin Jia, Xuan Ding, Peng Zheng, Zhe Li
We report the use of a protein ligase to covalently ligate a protein to a peptide nucleic acid (PNA). The rapid ligation demands only an N-terminal GL dipeptide in target...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


EPR based in situ enzymatic activity detection of endogenous caspase-3 in apoptosis cell lysates

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02361J, Communication
Aokun Liu, Jian Kuang, Yemian Zhou, An Xu, Changlin Tian, Lu Yu
Caspase-3 plays vital role in cell apoptosis and related diseases. Detection and characterization of endogenous active caspase-3 are of immense value not only for mechanism studies of apoptosis but also...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.07.2022


Diastereoselective Access to Substituted Oxetanes via Hydrosilylation-Iodocyclisation of Homopropargylic Alcohols

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03339A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Dean D Roberts, Mark G McLaughlin
The regio and stereoselective hydrosilylation of a variety of homopropargylic scaffolds is described. The reaction is tolerant to a variety of sterically and electronically varied substrates, affording only the E-vinyl...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


An activity-based probe targeting the streptococcal virulence factor C5a peptidase

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01517J, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sankarganesh Krishnamoorthy, Andrea K. Steiger, William C. Nelson, Robert G. Egbert, Aaron T. Wright
A selective activity-based probe for C5a peptidase profiles pathogenic streptococci.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Efficient and Reusable Catalysis of Benzylic C-H Oxidation over Layered [Co5(OH)6]4+ Derivatives

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02424A, Communication
Wen Ma, Chengdong Peng, Xueling Song, Lu Zhang, Honghan Fei
Aerobic oxidation of benzylic C(sp3)-H bonds in a green and heterogeneous manner is a major target in organic catalysis. Herein, we report the synthesis of 3D coordination polymers containing [Co5(OH)6]4+...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Prediction of pH in multiphase multicomponent systems with ePC-SAFT advanced

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02943J, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moreno Ascani, Daniel Pabsch, Marcel Klinksiek, Nicolas Gajardo-Parra, Gabriele Sadowski, Christoph Held
Proton activity, which is usually expressed as pH value, is among the most important properties in the design of chemical and biochemical processes as it determines the dissociation of species...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Zinc Acetate-Promoted Blocking of ATRA Process with Alkyl Halides Enabling Photochemical Alkylamination of Olefins

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02574D, Communication
Soumitra Maity, Apurba Samanta, Shyamal Pramanik, Subhashis Mondal
Organic photoredox-catalyzed alkylamination of olefins is performed with alkyl halides and nitrile solvent by blocking the traditional photoredox-ATRA process with Zn(OAc)2. A range of carbon-centered radicals (α-alkylcarbonyl, benzyl, cyanomethyl) are...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


A simple and rapid mix-and-read assay for sensitive detection of O6-methylguanine DNA methyltransferase

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03084E, Communication
Ming-Hao Liu, Wan-tong Yu, Xiao-Yun Yang, Yue-Ying Li, Yan Zhang, Chun-Yang Zhang
We develop a simple and rapid mix-and-read assay for sensitive detection of O6-methylguanine DNA methyltransferase (MGMT) activity based on exonuclease III-assisted signal amplification at absolutely isothermal conditions (37 °C). This...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


High-conductivity Thiocyanate Ionic Liquid Interface Engineering for Efficient and stable Perovskite Solar Cell

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02354G, Communication
Shumao Wang, Haodan Guo, Jinpeng Wu, Yan Lei, Xiangrong Li, Yanyan Fang, Yuhua Dai, Wanchun Xiang, Yuan Lin
A high-conductivity thiocyanate ionic liquid (EMIMSCN) was introduced into perovskite solar cells for the first time. The high conductivity of EMIMSCN ensures adequate supply of free SCN- anions and EMIM+...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Cancer cell membrane targeting and red light-triggered carbon monoxide (CO) release for enhanced chemotherapy

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC01948E, Communication
Weinan Zhao, Min Wang, Chen Zhang, Shiguo Sun, Yongqian Xu
Chemotherapy assisted with carbon monoxide (CO) gas therapy is an emerging powerful cancer therapeutic modality. However, the effective delivery and controlled release of CO in tumor cells remain a challenge....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Single Atoms (Pt, Ir and Rh) Anchored on Activated NiCo LDH for Alkaline Hydrogen Evolution Reaction

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02732A, Communication
Binbin Fan, Haozhi Wang, Xiaopeng Han, Yida Deng, Wenbin Hu
Here, we report the synthesis of activated NiCo LDH to immobilize Pt, Ir and Rh single atoms for hydrogen evolution reaction. The Pt/A-NiCo LDH electrocatalyst exhibits the highest catalytic ability...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.06.2022


Barrier-free liquid condensates of nanocatalysts as effective concentrators of catalysis

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03111F, Communication
Silky Bedi, Gaurav Kumar, S M ROSE, Sabyasachi Rakshit, Sharmistha Sinha
Traditional methods of molecular confinement have physicochemical barriers that restricts the free passage of substrates/products. Here, we explored the liquid-liquid phase separation as a method to restrain protein-metal nanocomposites within...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


[3]Foldarotaxane-Mediated Synthesis of an Improbable [2]Rotaxane

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03066G, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Victor Koehler, Maxime Gauthier, Chenhao Yao, Karine Fournel-Marotte, Philip Waeles, Brice Kauffmann, Ivan Huc, Frédéric Coutrot, Yann Ferrand
The wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane enforced the sliding and the sequestration of the surrounding macrocycle around a part of the axle for which...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Iron ore production by using a new Gemini surfactant at 273K

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02705D, Communication
Zhiqiang Huang, Wenyuan Li, Shuyi Shuai, Shiyong Zhang, Hongling Wang, Rukuan Liu, Cheng Chen, Xinyang Yu, Guichun He, Weng Fu
Herein we present a Gemini surfactant can efficiently separate magnetite from quartz by reverse froth flotation to produce iron ore at 273 K. Achieving the obviously superior flotation performance (TFe...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


A biphosphine copolymer encapsulated single-site Rh catalyst for heterogeneous regioselective hydroaminomethylation of alkenes

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02469A, Communication
Kang Zhao, Hongli Wang, Xinzhi Wang, Xinjiang Cui, Feng Shi
A biphosphine copolymer catalyst with in situ encapsulated single-site Rh was developed and applied in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


High performance transition metal-based electrocatalysts for green hydrogen production

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02423C, Feature Article
Hee Ryeong Kwon, Hoonkee Park, Sang Eon Jun, Sungkyun Choi, Ho Won Jang
Focusing on catalysts based on metal alloys, LDH, TMDs, and SACs, researches about high-efficiency hydrogen production will be introduced.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Probing the Self-assembly Process of Amphiphilic Tetrahedral DNA Frameworks

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03451D, Communication
Jianlei Shen, Chengpin Liang, Jielin Chen, Mingqiang Li, Zhilei Ge, Chunhai Fan
Herein we utilized the thermal hysteresis method to directly probe the self-assembly process of amphiphilic DNA nanostructures, with the use of amphiphilic tetrahedral DNA framework (am-TDF) as a model system....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Configurational ligand isomerism in conjoined-cages

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02837A, Communication
Hareesha Dasary, Moumita Sarkar, Dillip Kumar Chand
Double-decker shaped conjoined-cages of Pd3L4 formulation are prepared via self-assembly of Pd(II) with a set of three regioisomeric tridentate ligands. Alongside the targeted double-decker cage, unprecedented hour-glass shaped conjoined-cages of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Transition Metal Catalyzed Selective B(3)-H or B(4)-H Amination of o-Carboranes via Dehydrogenative BH/NH Cross-Coupling

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02852B, Communication
Hairong Lyu, Zuowei Xie
A unique approach to vertex‐selective catalytic B−H amination at either B(3)‐ or B(4)‐position in o-carboranes has been developed. Using different transition metal catalysts, dehydrogenative BH/NH cross-coupling of o-carboranes and free...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.06.2022


Visible-light-driven PhSSPh-catalysed regioselective hydroborylation of α,β-unsaturated carbonyl compounds with NHC-boranes

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02846H, Communication
Xinghua Liu, Yujing Shen, Cheng Lu, Yongchan Jian, Shuangshuang Xia, Zhaoliang Gao, Yihan Zheng, Yuanyuan An, Yubin Wang
A photo-induced transition-metal-free regioselective hydroborylation of α,β-unsaturated carbonyl compounds is developed. The PhSSPh reagent was employed as the photocatalyst, and NHC-BH3 was used as the boron source. This transformation shows...
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Datum: 29.06.2022


Photoresponsive proton conduction in Zr-based metal-organic frameworks using the photothermal effect

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02470E, Communication
Mingfeng Qin, Chang-Yu Wang, Song-Song Bao, Li-Min Zheng
A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10-3 S·cm-1 at 25 °C and 95% RH,...
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Datum: 28.06.2022


Dynamic Combinatorial Libraries of a Dimercapto-Pillar[5]arene

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02752F, Communication
Jinwen Luo, Yunlong Guo, Ping Li, Andrew C.-H. Sue, Chuyang Cheng
We report the synthesis and dynamic covalent chemistry (DCvC) of an A1/A2-dimercapto-functionalized pillar[5]arene (Di-SH-P5). The introduction of thiol moieties into this macrocyclic host makes it an effective building block for...
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Datum: 28.06.2022


Effects of Sidechain Isomerism on Polymer-based Non-Covalent Protein Delivery

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02343A, Communication
Alfonso Barrios, Mario Milan Diaz, Elianny Perezo, Md Lokman Hossen, Prem Chapagain, Joong Ho Moon
We present the importance of functional group isomerism on intracellular protein delivery using polymers containing different isomeric side chains. While the physical properties of polymer/protein complexes are relatively similar, different...
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Datum: 28.06.2022


Convenient synthesis of tricyclic N(1)-C(2)-fused oxazino-indolones via [Au(I)] catalyzed hydrocarboxylation of allenes

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02303B, Communication
Riccardo Pedrazzani, Emanuele Pinosa, Giulio Bertuzzi, MAGDA MONARI, Samuel Lauzon, Thierry Ollevier, Marco Bandini
A new [Au(I)] catalyzed intramolecular hydrocarboxylation of allenes is presented as a valuable synthetic route to oxazino-indolones. The employment of 3,5-(CF3)2-C6H3-ImPyAuSbF6 as the optimal catalyst (5 mol%) was necessary to...
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Datum: 28.06.2022


Unveiling two antiaromatic s-indacenodicarbazole isomers with tuneable paratropicity

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02318K, Communication
Hemonta Kumar Saha, Dibyendu Mallick, Soumyajit Das
Linear and curved antiaromatic s-indacenodicarbazole isomers were synthesized and characterized to show tuneable strength of s-indacene paratropicity, as analyzed by NICS(1)zz and ACID (ring-current) calculations. The curved isomer showed a...
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Datum: 28.06.2022


Near-Infrared Photothermally Activated DNA nanotweezers for Imaging ATP in Living Cells

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02791G, Communication
Xiao-Qiong Li, Dan Luo, Juan Song, Yi-Lei Jia, Juan Song, Hong-Yuan Chen, Jing-Juan Xu
By assembling nanotweezers with ATP-splitting aptamers on gold nanorods (AuT123L), we constructed a near-infrared-activated ATP sensing device that could time-controllably imaging ATP levels in living cells. By replacing the aptamers...
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Datum: 28.06.2022


Ratiometric Fluorescence Probe for Selective and Sensitive Detection of Leucine Aminopeptidase in Lysosome

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02214A, Communication
Di Yuan, Ziwei Xu, Bingling Zhang, Xiong Yin, Jiqing Ye, Xiaole Zhou, Leyu Wang
We designed a novel ratiometric fluorescent probe P1-Leu with donor-acceptor-donor fluorophore for detection of Leucine aminopeptidase in lysosomes. P1-Leu exhibits lower detection limit than the ratiometric donor-π-acceptor probe, due to...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.06.2022


Stereoselective Insertion of Cyclopropenes into Mg–Mg Bonds

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02931F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feriel Rekhroukh, Linxing Zhang, Richard Y Kong, Andrew J P White, Mark Richard Crimmin
The reaction of cyclopropenes with compounds containing Mg–Mg bonds is reported. 1,2-Dimagnesiation occurs exclusively by syn-addition to the least hindered face of the alkene forming a single diastereomeric product. DFT...
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Datum: 28.06.2022


A terpyridine-based hydrogel system for reversible transmissive-to-dark electrochromism and bright-to-quenched electrofluorochromism

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC02384A, Communication
Sayan Halder, Susmita Roy, Mudit Dixit, Chanchal Chakraborty
The carboxylic acid-containing terpyridine-based hydrogelator (TPPCA) is synthesized to afford self-assembly induced TPPCA hydrogel which was used as all-in-one electrochrome in electrochromic devices (ECDs) to demonstrate reversible transparent-to-black electrochromism with...
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Datum: 28.06.2022


Polymerization-Like Mechanism for Fixation of CO2 with Epoxides by Multifunctional Organocatalysts

Chem. Commun., 2022, Accepted Manuscript
DOI: 10.1039/D2CC03409C, Communication
Mingan Chen, Hui Yang, Ming Wah Wong
The commonly accepted mechanism of CO2 fixation of epoxides to cyclic carbonates catalyzed by multifunctional non-halide organocatalysts is challenged by our computational DFT-D3 study, which revealed a new polymerization-like mechanism...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.06.2022


La(III)-Catalysed degradation of polyesters to monomers via transesterifications

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02448A, Communication
Ryota Abe, Nobuyuki Komine, Kotohiro Nomura, Masafumi Hirano
Tris(acetylacetonato)lanthanum(III) (1 mol%) catalyses the degradation of poly(butylene succinate) (Mw = 90 700) by transesterification in MeOH at 90 °C for 4 h, thus affording dimethyl succinate (>99% yield) and 1,4-butanediol (98% yield).
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Datum: 27.06.2022


The key role of concentrated Zn(OTF)2 electrolyte in the performance of aqueous Zn–S batteries

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02075K, Communication
Zhao Xu, Yan Zhang, Wenshan Gou, Mengmeng Liu, Yifei Sun, Xuguang Han, Wei Sun, Changming Li
In this communication, the electrolyte chemistry in aqueous Zn–S batteries was illustrated systematically.
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Datum: 26.06.2022


Deep eutectic solvents coupled with (NH4)3H6CoMo6O24 trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02544B, Communication
Yanbin Sun, Kaixuan Yang, Zhiguo Zhu, Ting Su, Wanzhong Ren, Hongying Lü
A method for selective aerobic oxidation of HMF to FFCA over an Anderson-type POM (NH4)3H6CoMo6O24 catalyst in DESs was developed, which exhibited outstanding catalytic performance.
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Datum: 25.06.2022


Multi-functional metal–organic frameworks for detection and removal of water pollutions

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02738K, Feature Article
Yang Li, Jiandong Pang, Xian-He Bu
This feature article reviews the recent achievements in metal–organic frameworks (MOFs) as versatile advanced materials for multifunctional water treatment and prospects the current challenges and the future research trends.
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Datum: 24.06.2022


Uniform wrapping of copper(I) oxide nanocubes by self-controlled copper-catalyzed azide–alkyne cycloaddition toward selective carbon dioxide electrocatalysis

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02017C, Communication
Takuma Umeda, Takeshi Kurome, Ayumu Sakatmoto, Kazuyuki Kubo, Tsutomu Mizuta, Seung Uk Son, Shoko Kume
Cu2O nanocubes were wrapped with an extremely uniform layer through self-controlled growth on their surface, improving their CO2 reduction selectivity.
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Datum: 23.06.2022


Enhancing room-temperature phosphorescence via intermolecular charge transfer in dopant-matrix systems

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03295C, Communication
Xinjian Deng, Ju Huang, Guangming Wang, Jiuyang Li, Xun Li, Chuanhu Lei, Kaka Zhang
Intermolecular charge transfer in organic dopant-matrix systems significantly facilitates intersystem crossing and consequently boosts room-temperature phosphorescence.
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Datum: 23.06.2022


Ni-modified β-FeOOH nanorod cocatalysts for oxygen evolution utilising photoexcited holes on a N 2p level in a N-doped TiO2 electrode

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02795J, Communication
Takahiro Ikeda, Tomiko M. Suzuki, Takeo Arai, Takeshi Morikawa
Ni-modified β-FeOOH nanorod cocatalysts efficiently utilised the N 2p holes in N-doped TiO2 upon visible light irradiation.
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Datum: 23.06.2022


High entropy metal chalcogenides: synthesis, properties, applications and future directions

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01796B, Feature Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mark A. Buckingham, Brendan Ward-O’Brien, Weichen Xiao, Yi Li, Jie Qu, David J. Lewis
In this perspective we assess the current status of high entropy metal chalcogenides, the synthetic techniques for them, the currently obtained properties and demonstrated applications and a discussion on the possible future directions.
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Datum: 23.06.2022


Enhancement of metal ion-induced hole transfer on the water oxidation performance of a BiVO4 photoanode

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02240K, Communication
Wenjun Han, Fan Fang, Yaqian Zhang, Xue Li, Tao Wang, Zhiyuan Su, Kun Chang
Transition metal ions facilitate the separation and transfer of holes, thereby enhancing the PEC performance of BiVO4.
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Datum: 22.06.2022


Access to high value sp3-rich frameworks using photocatalyzed [2 + 2]-cycloadditions of γ-alkylidene–γ-lactams

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03009H, Communication
Dimitris Kalaitzakis, Ioannis Kampouropoulos, Manolis Sofiadis, Tamsyn Montagnon, Georgios Vassilikogiannakis
By harnessing an energy transfer process, new photocatalyzed [2 + 2]-cycloadditions occurring between γ-alkylidene–γ-lactams and unsaturated substrates have been developed.
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Datum: 22.06.2022


A flexible self-healing Zn3V2O7(OH)2·2H2O-based Zn-ion battery under continuous folding and twisting

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02561B, Communication
Yajun Zhu, Xirong Lin, Xin Jin, Tianli Han, Huigang Zhang, Jinyun Liu
A flexible self-healing Zn-ion battery composed of a Zn3V2O7(OH)2·2H2O nanosheet cathode working with a hydrogel electrolyte is developed, which displays a stable performance in different working conditions.
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Datum: 22.06.2022


Twisted push–pull disilenes obtained by direct 1,2-hydro/chloroborylation of a silylone

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02160A, Communication
Taichi Koike, Takeaki Iwamoto
Twisted 1-amino-2-boryl disilenes which feature highly polarized SiSi bonds were synthesized by the direct hydro/chloroborylation of a silylene-stabilized monatomic silicon complex.
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Datum: 22.06.2022


Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02869G, Communication
Rubén Vicente, Eva Tudela, Miguel A. Rodríguez, Ángel L. Suárez-Sobrino, Alfredo Ballesteros
The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes.
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Datum: 22.06.2022


Building-block exchange synthesis of amino-based three-dimensional covalent organic frameworks for gas chromatographic separation of isomers

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02383K, Communication
Hai-Long Qian, Zi-Han Wang, Jing Yang, Xiu-Ping Yan
The first amino-based 3D COF and its covalently bonded capillary were prepared via building-block exchange for GC separation of isomers.
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Datum: 22.06.2022


Giant N-heterocyclic carbene-containing macrocycles for cobalt-catalysed hydroboration of alkynes

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02815H, Communication
Guoqi Zhang
Giant N-heterocyclic carbene-containing macrocycles larger than “Texas-sized” molecular boxes have been synthesized and applied to cobalt-catalysed syn-selective hydroboration of alkynes with good stereo- and regioselectivity.
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Datum: 22.06.2022


A label-free and self-circulated fluorescent biosensor for sensitive detection of ten-eleven translocation 1 in cancer cells

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03019E, Communication
Wen-jing Liu, Xinyi Zhang, Juan Hu, Chun-yang Zhang
We develop a label-free and self-circulated fluorescent biosensor to sensitively detect ten-eleven translocation 1 (TET1) activity in cancer cells.
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Datum: 21.06.2022


Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01260J, Communication
Logan S. Breton, Gregory Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans-Conrad zur Loye
Single crystals of LnBS3 (Ln = La–Nd) were synthesized by the combined boron–chalcogen mixture and molten flux growth methods. SHG measurements confirmed the expectation that LaBS3 would exhibit a strong SHG response, measured at 1.5 × KDP.
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Datum: 21.06.2022


Integrating single Co sites into crystalline covalent triazine frameworks for photoreduction of CO2

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02481K, Communication
Xunliang Hu, Lirong Zheng, Shengyao Wang, Xiaoyan Wang, Bien Tan
Crystalline covalent triazine frameworks loaded with single Co sites show high activity for photocatalytic CO2 reduction.
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Datum: 21.06.2022


Catalytic machinery in motion: controlling catalysis via speed

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02555H, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Emad Elramadi, Amit Ghosh, Isa Valiyev, Pronay Kumar Biswas, Thomas Paululat, Michael Schmittel
The speed and catalytic activity (with regard to a click reaction) of slider-on-deck systems, in which a biped exchanges between three copper(I) centres, is regulated by addition of brake stones.
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Datum: 21.06.2022


Efficient water splitting over a hybrid photocatalyst with (002) active facets and heterostructure

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02445D, Communication
Yinjuan Dong, Mengxue Chen, Xiaohu Li, Yu Feng, Bonan Li, Pengfei Feng, Congzhao Dong, Yong Ding
P-CdS@P-NiWOx photocatalyst was constructed using polyoxometalates as precursors via a pyrolysis–phosphidation strategy. The synergistic action of heterostructure and facet effect over P-CdS@P-NiWOx affords the good performance of the visible-light-driven water splitting.
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Datum: 20.06.2022


Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02882D, Communication
Ziyang Dong, Meng-Yao Ma, Jiaxi Xu, Zhanhui Yang
As masked S-electrophilic thia-1,3-dipoles, 1,2,3-thiadiazoles undergo denitrogenative (3 + 2) umpolung transannulations with aryl isothiocyanates, regio- and stereoselectively.
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Datum: 20.06.2022


A chiral 3D silver(I)–benzenedithiolate coordination polymer exhibiting photoemission and non-linear optical response

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02114E, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Saly Hawila, Ahmad Abdallah, Jean-Luc Rukemampunzi, Alexandra Fateeva, Gilles Ledoux, Régis Debord, Stéphane Paihlès, Nathalie Guillou, Florian Massuyeau, Romain Gautier, Adel Mesbah, Aude Demessence
A neutral coordination polymer made of Ag(I) and 1,3-benzenedithiolate, [Ag2(1,3-BDT)]n, displays both photoluminescence properties and a second harmonic generation signal.
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Datum: 20.06.2022


Oxidative C–O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(VI) cyanonitrido complex

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC03002K, Communication
Jing Xiang, Jiang Zhu, Miaomiao Zhou, Lu-Lu Liu, Li-Xin Wang, Min Peng, Bi-Shun Hou, Shek-Man Yiu, Wai-Pong To, Chi-Ming Che, Kai-Chung Lau, Tai-Chu Lau
The photoreactions of OsN and dihydroxybenzenes lead to C–O bond cleavage of H2Q/H2Cat, accompanied by the conversion of the coordinated CN into CO.
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Datum: 20.06.2022


Boosting the catalytic performance of single-atom catalysts by tuning surface lattice expanding confinement

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02671F, Communication
Fei Gao, Annai Liu, Wei Tan, Bing Hu, Ruihan Gong, Xing Cheng, Fudong Liu, Ge Chen, Lin Dong
We report that Pt single atoms embedded on a disordered TiO2 surface have a weaker affinity for CO than those supported on a perfect TiO2 surface, thus generating much better CO oxidation activity.
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Datum: 20.06.2022


Substitution at boron in BODIPYs

Chem. Commun., 2022, 58,7351-7359
DOI: 10.1039/D2CC02362H, Feature Article
Rosinah Liandrah Gapare, Alison Thompson
BODIPYs provide tunable electronic properties key to many applications. This article highlights structural modification at boron.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.06.2022


Phosphate interphase reinforced amorphous vanadium oxide cathode materials for aqueous zinc ion batteries

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01864K, Communication
Shangshang Zhang, Shengkai Li, Haiyan Zhang, Daofeng Wen, Shuqi Zhang, Lun Li, Zhenjiang Liu
Phosphate-doped amorphous vanadium oxide cathode materials with a low energy barrier are more conducive to Zn2+ insertion/extraction.
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Datum: 18.06.2022


Novel cinnamic acid analogues: synthesis of aminotroponyl acrylates by Pd(II)-catalysed C(sp2)–H olefination

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02276A, Communication
Chinmay K. Jena, Nagendra K. Sharma
Cinnamic acid, a benzenoid scaffold, is a building block of various natural products.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.06.2022


Co-substitution in a Prussian blue analog with a hollow heterostructure for ultrahigh capacity and rate capability aqueous Zn2+ batteries

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02974J, Communication
Zhihao Su, Jionghao Huang, Runhao Wang, Yufei Zhang, Zili Liu, Haosen Fan
Nickel and manganese co-substitution in a hollow Prussian blue nanocubes has been successfully carried out via utilizing a high-concentration polymer template, with an ultrahigh capacity of 138.4 mA h g−1 at 0.05 A g−1 in an aqueous zinc-ion battery.
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Datum: 17.06.2022


Photodegradation of carbonic anhydrase IX via a binding-enhanced ruthenium-based photosensitizer

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02337G, Communication
Liang Hao, Jie Wang, Zheng-Yin Pan, Zong-Wan Mao, Cai-Ping Tan
A binding-enhanced ruthenium-based photosensitizer is reported for photodegradation of carbonic anhydrase IX.
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Datum: 16.06.2022


Strategies toward anode stabilization in nonaqueous alkali metal–oxygen batteries

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02501A, Highlight
Congcong Zhou, Kangkang Lu, Shiyu Zhou, Yihao Liu, Weiwei Fang, Yuyang Hou, Jilei Ye, Lijun Fu, Yuhui Chen, Lili Liu, Yuping Wu
This highlight demonstrates the challenges and latest progress in stabilizing the metal anode in nonaqueous alkali metal–oxygen batteries.
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Datum: 16.06.2022


NiFe layered double hydroxide nanosheet array for high-efficiency electrocatalytic reduction of nitric oxide to ammonia

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02463B, Communication
Ge Meng, Tianran Wei, Weijia Liu, Wenbo Li, Shusheng Zhang, Wenxian Liu, Qian Liu, Haihong Bao, Jun Luo, Xijun Liu
A NiFe layered double hydroxide nanosheet array is designed as an efficient NORR catalyst for NH3 electrosynthesis with a maximal FE of 82% and the highest yield rate of 1586.7 μg h−1 mgcat.−1, exceeding most recently reported results.
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Datum: 16.06.2022


A new access to diazaphospholes via cycloaddition–cycloreversion reactions on triazaphospholes

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02269A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Lea Dettling, Martin Papke, Julian A. W. Sklorz, Dániel Buzsáki, Zsolt Kelemen, Manuela Weber, László Nyulászi, Christian Müller
The [4+2] cycloaddition of a triazaphosphole with hexafluoro-2-butyne, followed by a cycloreversion reaction under elimination of pivaloyl nitrile, affords selectively a novel bis-CF3-substituted diazaphosphole in high yield.
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Datum: 15.06.2022


Recent advances in visible-light-mediated functionalization of olefins and alkynes using copper catalysts

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC01611G, Highlight
Arti Ramani, Bhargav Desai, Bharatkumar Z. Dholakiya, Togati Naveen
Olefins and akynes are synthetically important building blocks in modern organic synthesis. This review highlights the recent developments in the direct functionalization of olefins and alkynes via photoinduced copper-based catalysis.
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Datum: 15.06.2022


A five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

Chem. Commun., 2022, 58,7360-7363
DOI: 10.1039/D2CC02516G, Communication
Leonel Griego, Toby J. Woods, Liviu M. Mirica
We report the synthesis and characterization of an uncommon five-coordinate Ni(I) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.06.2022


Site-selective iodine atom transfer in fluorinated alkyl iodides via 1,5-hydrogen atom transfer

Chem. Commun., 2022, 58,7416-7418
DOI: 10.1039/D2CC02803D, Communication
Masahiro Abe, Yuka Yokoi, Aoi Hirata, Yumeno Matsuoka, Tetsutaro Kimachi, Kiyofumi Inamoto
The direct and selective functionalization of inert C–H bonds via intramolecular hydrogen atom transfer (HAT) is a powerful tool in organic synthesis. Herein, we designed an efficient iodine atom transfer in fluorinated alkyl iodides via 1,5-HAT.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.06.2022


Detection of cell membrane proteins using ion-sensitive field effect transistors combined with chemical signal amplification

Chem. Commun., 2022, 58,7368-7371
DOI: 10.1039/D2CC02159E, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Miyuki Tabata, Chattarika Khamhanglit, Sayo Kotaki, Yuji Miyahara
Detection concept of HER2 via an enzyme reaction using an ISFET pH sensor.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.06.2022


Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions

Chem. Commun., 2022, 58,7431-7434
DOI: 10.1039/D2CC02068H, Communication
Niels A. Bonde, Markus Appel, Jacques Ollivier, Høgni Weihe, Jesper Bendix
Crystal field and hyperfine inhomogeneities from high-resolution inelastic neutron scattering spectroscopy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.06.2022


Mixed-metal calix[8]arene complexes: structure, and ring opening polymerisation studies

Chem. Commun., 2022, 58,7427-7430
DOI: 10.1039/D2CC02236B, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tian Xing, Max Derbyshire, Mark R. J. Elsegood, Carl Redshaw
Combinations of group V alkoxides or tungsten oxyalkoxide salts with p-tert-butylcalix[8]areneH8 afford mixed-metal calixarenes capable of the ROP of ε-caprolactone.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.06.2022


Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Chem. Commun., 2022, 58,7380-7383
DOI: 10.1039/D2CC02438A, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Hosung Ki, Tae Wu Kim, Jiwon Moon, Jungmin Kim, Yunbeom Lee, Jun Heo, Kyung Hwan Kim, Qingyu Kong, Dmitry Khakhulin, Gemma Newby, Joonghan Kim, Jeongho Kim, Michael Wulff, Hyotcherl Ihee
Photoactivation mechanism of triosmium dodecacarbonyl is elucidated via time-resolved X-ray liquidography, identifying two pathways, vibrational relaxation and ligand dissociation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.06.2022


Chemoselective and enantioselective fluorescent identification of specific amino acid enantiomers

Chem. Commun., 2022, Advance Article
DOI: 10.1039/D2CC02363F, Feature Article
Lin Pu
Chiral fluorescent probes have been developed for chemoselective as well as enantioselective recognition of specific amino acid enantiomers including glutamic acid, aspartic acid, serine, histidine, lysine and tryptophan.
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Datum: 07.06.2022


A tin porphyrin axially-coordinated two-dimensional covalent organic polymer for efficient hydrogen evolution

Chem. Commun., 2022, 58,7423-7426
DOI: 10.1039/D2CC02775E, Communication
Qi Wang, Aijian Wang, Yuqin Dou, Xiaoliang Shen, M. Shire Sudi, Long Zhao, Weihua Zhu, Longhua Li
The prepared tin porphyrin axially-coordinated 2D covalent organic polymer exhibits excellent HER activity due to its unique structural properties, ranking among the best records reported recently.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 07.06.2022


CO2 capture by 1,2,3-triazole-based deep eutectic solvents: the unexpected role of hydrogen bonds

Chem. Commun., 2022, 58,7376-7379
DOI: 10.1039/D2CC02503E, Communication
Zonghua Wang, Congyi Wu, Ze Wang, Shaoze Zhang, Dezhong Yang
Hydrogen bonding is found to be a switch for the reaction between CO2 and the 1,2,3-triazole-based deep eutectic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


An AIPH-decorated semiconducting nanoagonist for NIR-II light-triggered photothermic/thermodynamic combinational therapy

Chem. Commun., 2022, 58,7400-7403
DOI: 10.1039/D2CC01207C, Communication
Guangzhao Yang, Xi Zhang, Shan Zhou, Wen Zhou, Chao Yin, Chen Xie, Quli Fan, Wei Huang
A multifunctional semiconducting nanoagonist with high photothermic conversion efficiency and radical generation ability was developed, which showed an excellent anticancer effect through NIR-II light-triggered combinational therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Enzyme-responsive hybrid prodrug of nitric oxide and hydrogen sulfide for heart failure therapy

Chem. Commun., 2022, 58,7396-7399
DOI: 10.1039/D2CC02267B, Communication
Qi Liu, Guangbo Ji, Yushu Chu, Tian Hao, Meng Qian, Qiang Zhao
Codelivery of nitric oxide and hydrogen sulfide from an enzyme-responsive hybrid prodrug provides potent therapeutic efficacy for heart failure.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Post-translational site-specific protein azidolation with an azido pyridoxal derivative

Chem. Commun., 2022, 58,7408-7411
DOI: 10.1039/D2CC03051A, Communication
Baochuan Wang, Xun Li, Yiwan Wang, Xianxian Mao, Xiaojian Wang
An azido pyridoxal derivative was developed for post-translational site-specific protein azidolation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2022


Albumin-mediated extracellular zinc speciation drives cellular zinc uptake

Chem. Commun., 2022, 58,7384-7387
DOI: 10.1039/D2CC02278H, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
James P. C. Coverdale, Hugo A. van den Berg, Siavash Khazaipoul, Hannah E. Bridgewater, Alan J. Stewart, Claudia A. Blindauer
Fatty acids alter zinc speciation in plasma, increasing zinc influx into endothelial cells.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.06.2022


A convenient and versatile SNAr-decarboxylation protocol for the construction of C(sp2)–C(sp3) bonds

Chem. Commun., 2022, 58,7435-7438
DOI: 10.1039/D2CC01551J, Communication
Alexander Burtea, Jacob DeForest, Neil Baldwin, Carolyn Leverett, Gary M. Gallego
A versatile and operationally simple one-pot procedure for the construction of C(sp2)-C(sp3) bonds via a nucleophilic aromatic substitution-decarboxylation sequence is described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.06.2022


Enantioselective synthesis of acyclic monohydrosilanes by steric hindrance assisted C–H silylation

Chem. Commun., 2022, 58,7388-7391
DOI: 10.1039/D2CC02307E, Communication
Delong Mu, Shuqiong Pan, Xiaoyu Wang, Xiaoyun Liao, Yong Huang, Jiean Chen
Herein, a rhodium-catalyzed desymmetrization of dihydrosilanes with heterocyclic compounds via intermolecular dehydrogenative C–H silylation is developed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.06.2022


An air-stable, well-defined palladium–BIAN–NHC chloro dimer: a fast-activating, highly efficient catalyst for cross-coupling

Chem. Commun., 2022, 58,7404-7407
DOI: 10.1039/D2CC02253B, Communication
Jin Zhang, Tao Li, Xue Li, Gaopeng Zhang, Shuai Fang, Wenxuan Yan, Xiangyang Li, Xiufang Yang, Yangmin Ma, Michal Szostak
We report palladium–BIAN–NHC chloro dimer complex, [Pd(BIAN–IPr)(μ-Cl)Cl]2. This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(μ-Cl)Cl]2, with the attractive structural features of the BIAN framework.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.06.2022


Designed graphite with an activated edge for fast-charging lithium-ion storage properties

Chem. Commun., 2022, 58,7372-7375
DOI: 10.1039/D2CC01927B, Communication
Peng Du, Bao Zhang, Liang Cao, Xing Ou
The special edge of graphite with the coexistence of extra channels and expanded layers is carefully designed to meet the standards of fast charging, and the material exhibits excellent rate performance and long-term cycling performance.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2022


Selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitrides

Chem. Commun., 2022, 58,7419-7422
DOI: 10.1039/D2CC01757A, Communication
Marcos A. R. da Silva, Jéssica C. Gil, Nadezda V. Tarakina, Gelson T. S. T. Silva, José B. G. Filho, Klaus Krambrock, Markus Antonietti, Caue Ribeiro, Ivo F. Teixeira
Here we report a new record of the selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitride, it displayed a remarkable methanol production (2900 μmol g−1) in 4 hours.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 31.05.2022


MXenes in photomedicine: advances and prospects

Chem. Commun., 2022, 58,7336-7350
DOI: 10.1039/D2CC01694J, Highlight
Siavash Iravani, Rajender S. Varma
The potentials of MXenes in photomedicine are deliberated, encompassing important challenges and future directions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2022


A highly enantioselective approach towards optically active γ-amino alcohols by tin-catalyzed kinetic resolution of 1,3-amino alcohols

Chem. Commun., 2022, 58,7392-7395
DOI: 10.1039/D2CC01963A, Communication
Jian Song, Wen-Hua Zheng
A highly enantioselective kinetic resolution of racemic 1,3-amino alcohols via O-Acylation was achieved using a chiral organotin as the catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2022


Engineering the CuO–HfO2 interface toward enhanced CO2 electroreduction to C2H4

Chem. Commun., 2022, 58,7412-7415
DOI: 10.1039/D2CC01776H, Communication
Xin Li, Lifen Li, Lijun Wang, Qineng Xia, Leiduan Hao, Xinyu Zhan, Alex W. Robertson, Zhenyu Sun
We demonstrate tuning of the CuOx@HfO2 interface for greatly enhanced electrocatalytic CO2 reduction to produce C2H4.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.05.2022


Tuneable helices of plasmonic nanoparticles using liquid crystal templates: molecular dynamics investigation of an unusual odd–even effect in liquid crystalline dimers

Chem. Commun., 2022, 58,7364-7367
DOI: 10.1039/D2CC00560C, Communication
Mateusz Pawlak, Maciej Bagiński, Pablo Llombart, Dominik Beutel, Guillermo González-Rubio, Ewa Górecka, Carsten Rockstuhl, Józef Mieczkowski, Damian Pociecha, Wiktor Lewandowski
Liquid crystalline (LC) dimers formed helical nanofilaments depending on the parity of the alkyl linker, revealing an unusual odd–even effect. Doping LC with Au nanoparticles evidenced that helical pitch was regulated by the length of the linker.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 05.05.2022


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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