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Chemical Communications

Current research reports and chronological list of recent articles..




The international scientific journal Chemical Communicationsoffers urgent high quality communications from across the chemical sciences.

The publisher is the Royal Society of Chemistry, UK. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

To search this web page for specific words type "Ctrl" + "F" on your keyboard (Command + "F" on a Mac). Then: type the word you are searching for in the window that pops up!

Additional research articles in the field of general chemistry, see Current Chemistry Research Articles. Magazines with similar content:

 - Angewandte Chemie International Edition,

 - Chemical Monthly,

 - The Chemical Record,

 - Chemistry Central Journal,

 - Chemistry Letters,

 - Journal of the American Chemical Society,

 - Nature Chemistry.



Chemical Communications - Abstracts



An azobenzene-based heteromeric prodrug for hypoxia-activated chemotherapy by regulating subcellular localization

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03430C, Communication
Shiying Li, Xueyan Jiang, Rongrong Zheng, Shengjia zuo, Linping Zhao, Guiling Fan, Jinghao Fan, Yonghua Liao, Xiyong Xu, Hong Cheng
An azobenzene-based heteromeric prodrug (hNDP) was prepared for targeted chemotherapy against hypoxic tumor. hNDP could divert the parent drug from nucleus to cytoplasm with lower toxicity. While the azoreduction of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.06.2018


Sensitized Photon Upconversion in Anthracene-based Zirconium Metal Organic Frameworks

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC01893F, Communication
Jennifer M Rowe, Jie Zhu, Erin M Soderstrom, Wenqian Xu, Andrey Yakovenko, Amanda J Morris
Sensitized upconversion is explored in three metal-organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Unsupported Metal Silyl Ether Coordination

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04517H, Communication
Juergen Pahl, Holger Elsen, Alexander Friedrich, Sjoerd Harder
Simple silyl ethers like O(SiMe3)2 are in contrast to normal ethers inert to metal bonding, however, a "naked", highly Lewis-acidic, cationic Mg species enforces complexation. DFT calculations indicate that agostic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Steric vs. Electronic Stereocontrol in Syndio- or Iso-selective ROP of Functional Chiral [small beta]-Lactones Mediated by Achiral Yttrium-Bisphenolate Complexes

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03842B, Feature Article
Romain Ligny, Mikko Hanninen, Sophie M Guillaume, Jean-Francois Carpentier
Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium complexes, resulting in the formation of highly heterotactic polylactide, and highly syndiotactic or, more uniquely, highly...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Pd/C-Catalyzed Dehydrogenation of 2-Cinamoylbenzoic Acids to 3-Benzylidene-3H-isochroman-1,4-diones

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03402H, Communication
Renhua Liu, Dejun Yang, Xuan Ji, Jie Zhang, Chenyang Zhang, Mingfei Li, Jin Li
Pd/C, a widely accepted hydrogenation catalyst, is found to catalytically dehydrogenate 2-cinnamoylbenzoic acids to 3-benzylidene-3-H-isochroman-1,4-diones with H2 as the only byproduct. The synthetic reaction proceeds without oxidants and hydrogen acceptors,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Correction: Topology meets MOF chemistry for pore-aperture fine tuning: ftw-MOF platform for energy-efficient separations via adsorption kinetics or molecular sieving

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC90270D, Correction
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dong-Xu Xue, Amandine Cadiau, Lukasz J. Weselinski, Hao Jiang, Prashant M. Bhatt, Aleksander Shkurenko, Lukasz Wojtas, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Mohamed Eddaoudi
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Catalytic Allylic Cation-induced Intermolecular Allylation-Semipinacol Rearrangement

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04285C, Communication
Ming-Hui Xu, Kun Long Dai, Yong Qiang Tu, Xiao-Ming Zhang, Fu-Min Zhang, Shao-Hua Wang
A catalytic intermolecular semipinacol rearrangement induced by allylic-carbocations has been realized. This tandem reaction is highly efficient under the catalysis of ZnBr2, generating a wide range of ɑ-homoallyl substituted ketones...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as hydrogen source

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03431A, Communication
Huan Liu, Da Yang, dongliang wang, Peng Wang, Yong Lu, Vo Thanh Giang, Ye Liu
Hydroaminomethylation of olefins with H2O as hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


The efficiency of 18F labelling of prostate specific membrane antigen ligand via strain-promoted azide-alkyne reaction: reaction speed versus hydrophilicity

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03999B, Communication
Mengzhe Wang, Christopher McNitt, Hui Wang, Xiaofen Ma, Scarry M Sarah, Zhanhong Wu, VLADIMIR POPIK, Zibo Li
Here we report the 18F labeling of prostate specific membrane antigen ligand (PSMA) via strain promoted oxa-dibenzocyclooctyne (ODIBO)- or bicyclo[6.1.0]nonyne (BCN)-azide reaction. Although ODIBO reacts with azide 20 fold faster...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Fe-doped CoP nanosheets array: an efficient bifunctional catalyst for zinc-air battery

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03902J, Communication
Xin Qin, Zao Wang, Jingrui Han, Yonglan Luo, Fengyu Xie, Guanwei Cui, Xiao-Dong Guo, Xuping Sun
It is highly desired to design and develop low-cost and efficient bifunctional electrocatalysts for zinc-air batteries (ZABs). In this communication, we report that Fe-doped CoP nanosheets array on nickel foam...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Effect of the metal-support interaction on the activity and selectivity of methanol oxidation over Au supported on mesoporous oxides

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04295K, Communication
Sunyoung Oh, You Kyung Kim, Chan Ho Jung, Won Hui DOH, Jeong Y. Park
To elucidate the factors affecting the catalytic properties of supported Au catalysts depending on the metal oxide support, we investigated Au NPs deposited on crystallized mesoporous transition-metal oxides (m-oxides: Co3O4,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Quantitative synthesis of protein-DNA conjugates with 1 : 1 stoichiometry

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03268H, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Xiaowen Yan, Hongquan Zhang, Zhixin Wang, Hanyong Peng, Jeffrey Tao, Xing-Fang Li, X. Chris Le
We describe here a binding-facilitated reaction strategy, enabling quantitative conjugation of DNA to native proteins with a desirable 1 : 1 stoichiometry.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


Rhodium-catalyzed oxidative C-H/C-H cross-coupling of aniline with heteroarene: N-nitroso group enabled mild conditions

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04027C, Communication
Shuang He, Guangying Tan, Anping Luo, Jingsong You
The development of transition metal-catalyzed oxidative C-H/C-H cross-coupling between two (hetero)arenes to forge aryl-heteroaryl motifs under mild conditions is an appealing, yet challenging task. Herein, we disclose a rhodium-catalyzed oxidative...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 19.06.2018


A[small beta] under stress: the effects of acidosis, Cu2+-binding, and oxidation on amyloid [small beta]-peptide dimers

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC02263A, Communication
Qinghua Liao, Michael C. Owen, Sofia Bali, Bogdan Barz, Birgit Strodel
In light of the high affinity of Cu2+ for Alzheimer's A[small beta]1-42 and its ability to subsequently catalyze the formation of radicals, we examine the effects of Cu2+ binding, A[small beta] oxidation,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


CO2-triggered Microreactions in Liquid Marbles

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC01786G, Communication
Xinjie Luo, Hongyao Yin, Xian'e Li, Xin Su, Yujun Feng
On-demand initiation of dual-, and multi-component microreactions inside liquid marbles (LMs) was developed by coalescing contacting patchy LMs that carried separate reagents through CO2-induced wetting transition of the interface between...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Frustrated Lewis Pairs in Ionic Liquids and Molecular Solvents - Neutron Scattering and NMR Study of Encounter Complexes

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03794A, Communication
Lucy Christobel Brown, James Hogg, Mark Gilmore, Leila Moura, Silvia Imberti, Sabrina Gartner, H. Q. Nimal Gunaratne, Ruairi O'Donnell, Nancy Artioli, John D. Holbrey, Malgorzata Swadzba-Kwasny
The presence of the weakly-associated encounter complex in the model frustrated Lewis pair solution (FLP): tris(tert-butyl)phosphine (P(tBu)3) and tris(pentafluorophenyl)borane (BCF) in benzene, was confirmed via P[middle dot][middle dot][middle dot]B correlation analysis from neutron...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Catalytic, Metal-free Alkylheteroarylation of Alkenes via Distal Heteroaryl ipso-Migration

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03911A, Communication
Yonghui He, Yaqi Wang, Jun Gao, Liang Zeng, Shusheng Li, Wei wang, Xiaohui Zheng, Shengyong Zhang, Lijun Gu, Gan-Peng Li
A new direct alkylheteroarylation of alkenes with simple alkylnitriles via distal heteroaryl ipso-migration has been accomplished under metal-free conditions, in which inexpensive alkylnitriles served as radical precursors together with ease...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Surfactant-free Synthesis of Cu2O Yolk-shell Cubes Decorated with Pt Nanoparticles for Enhanced H2O2 Detection

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03742F, Communication
Jian Lv, Chuncai Kong, Ke Liu, Lu Yin, Bo Ma, Xiaojing Zhang, Sen Yang, Zhimao Yang
Pt decorated yolk-shell Cu2O cubes are obtained by a surfactant-free and multiple-step method. Porous yolk-shell cubic structures, together with synergistic effect between Pt and Cu2O endow the yolk-shell Pt-Cu2O based...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Three-stage pH-Switchable Organic Chromophores with Large Nonlinear Optical Responses and Switching Contrasts

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03495H, Communication
Stein van Bezouw, Min-Jeong Koo, Seung-Chul Lee, Seung-Heon Lee, Jochen Campo, O-Pil Kwon, Wim Wenseleers
Three-stage pH-switchable organic second-order nonlinear optical (SO NLO) chromophores are synthesized and characterized by wavelength-dependent linear and nonlinear spectroscopy. The chromophores exhibit huge SO NLO responses in their "on" stages,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Allosteric Cooperativity in Ternary Complexes with Low Symmetry

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04195D, Communication
Hongxin Chai, Liu-Pan Yang, Hua Ke, Xin-Yu Pang, Wei Jiang
Two new naphthotubes with ester linkers were synthesized and characterized. With the syn isomers of ester naphthotube and ether naphthotube, strong positive allosteric cooperativity in a ternary complex with two...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Atomic Layer Deposition of TiO2 Shells on MoO3 Nanobelts Allowing Enhanced Lithium Storage Performance

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04282A, Communication
Sanmu Xie, Daxian Cao, Yiyi She, Hongkang Wang, Jian-Wen Shi, Michael K.H. Leung, Chunming Niu
Atomic layer deposition (ALD) of TiO2 shells on MoO3 nanobelts (denote as TiO2@MoO3) is realized using a home-made ALD system, which allows controllable hydrolysis reaction of TiCl¬4-H2O in atomic scale....
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


MRI and luminescence detection of Zn2+ with a lanthanide complex-zinc finger peptide conjugate

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC04366C, Communication
Manon Isaac, Agnes Pallier, Frederic Szeremeta, Pierre-Alain Bayle, Laurent Barantin, Celia S. Bonnet, Olivier Seneque
A zinc finger peptide provides an excellent scaffold for the design of lanthanide-based luminescent and MRI Zn2+-responsive probes
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Enabling Multi-Electron Reaction of [varepsilon]-VOPO4 to Reach Theoretical Capacity for Lithium-ion Batteries

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC02386G, Communication
Carrie Siu, Ieuan Seymour , Sylvia Britto, Hanlei Zhang, Jatinkumar Rana, Jun Feng, Frederick O. Omenya, Hui Zhou, Natasha Chernova, Guangwen Zhou, Louis F.J. Piper, Clare P. Grey, stanley Whittingham
By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, [varepsilon]-VOPO4, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mAh/g...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Cu(II)-tBu-PHOX Catalyzed Enantioselective Malonate Addition onto 3-Hydroxy 2-Oxindoles: Application in the Synthesis of Dimeric Pyrroloindoline Alkaloids

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04338H, Communication
K Naresh Babu, Lakshmana K. Kinthada, Partha Pratim Das, Alakesh Bisai
An efficient Cu(II)-PHOX-catalyzed malonate addition onto 3-hydroxy 3-indolyl-2-oxindoles is envisioned to afford excellent enantioselectivities (up to >99% ee) in high chemical yields. A detailed characterization data including X-ray, NMR, CV...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Stereoselective Synthesis of 3-Spiropiperidino Indolenines via SN2-Type Ring Opening of Activated Aziridines with 1H-Indoles/Pd-Catalyzed Spirocyclization with Propargyl Carbonates

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC04249G, Communication
Sajan Pradhan, Chandan Kumar Shahi, Aditya Bhattacharyya, Manas K. Ghorai
3-Spiropiperidino indolenines have been synthesized via a novel Lewis acid-catalyzed SN2-type ring opening of activated aziridines with 1H-indoles followed by Pd-catalyzed dearomative spirocyclization with propargyl carbonates in up to 90%...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Nanoporous sulfur-bridged hexaazatrinaphthylene framework as organic cathode for lithium ion battery with well-balanced electrochemical performance

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC03801E, Communication
Jinquan Wang, Yuhang Lee, Kaize Tee, Siti Nurhanna Riduan, Yugen Zhang
Some inherent drawbacks of organic cathode materials include low conductivity and high solubility in electrolyte which lead to low rate capability and low cycling stability. Herein, a novel nanoporous sulfur-bridged...
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 18.06.2018


Contributors to the Emerging Investigators Issue 2018

Chem. Commun., 2018, 54,6442-6457
DOI: 10.1039/C8CC90258E, Profile

The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.06.2018


Platination of cysteine by an epidermal growth factor receptor kinase-targeted hybrid agent

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC04251A, Communication
Mu Yang, Hanzhi Wu, Julie Chu, Lucas A. Gabriel, Y. Kim, Karen S. Anderson, Cristina M. Furdui, Ulrich Bierbach
Platinum-modified tyrosine kinase inhibitors show strong and selective EGFR kinase binding and form adducts with a pharmacologically relevant cysteine residue.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.06.2018


Py A-cluster system for the detection and imaging of miRNAs in living cells through double-three-way junction formation

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03982H, Communication
Jong Jin Ro, Ha Jung Lee, Byeang Hyean Kim
Herein, we describe an extended version of a fluorescence probe for detecting miRNAs through the novel application of a PyA-cluster system.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.06.2018


Pd(II)-Catalyzed gamma-C(sp3)-H alkynylation of amides: selective functionalization of R chains of amides R1C(O)NHR

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03445A, Communication
Vinod G. Landge, Ayisha Parveen, Avanashiappan Nandakumar, Ekambaram Balaraman
The first example of palladium(II)-catalyzed alkynylation of an unactivated gamma C(sp3)-H bond of alkyl amides (cyclic, linear, and amino acids) is reported.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.06.2018


Novel hemagglutinin-binding sulfated oligofucosides and their effect on influenza virus infection

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03865A, Communication
Shuhei Kosono, Akihiro Kasai, Sumika Komaba, Teruhiko Matsubara, Toshinori Sato, Daisuke Takahashi, Kazunobu Toshima
A purpose-designed trimer 10 possessing three sulfated oligofucoside moieties of 5 effectively bound to hemagglutinins and inhibited influenza virus infection.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.06.2018


Redox neutral [4+2] benzannulation of dienals and tertiary enaminones for benzaldehyde synthesis

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03514H, Communication
Lu Yang, Li Wei, Jie-Ping Wan
The [4+2] benzannulation reactions between tertiary enaminones and dienals have been developed for the synthesis of polyfunctionalized benzaldehydes, providing a new access to benzaldehydes alongside the classical formylation strategy.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 07.06.2018


Aggregation-induced emission of luminol: a novel strategy for fluorescence ratiometric detection of ALP and As(V) with high sensitivity and selectivity

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C8CC03725F, Communication
Yuan-Jun Tong, Lu-Dan Yu, Lu-Lu Wu, Shu-Ping Cao, Ru-Ping Liang, Li Zhang, Xing-Hua Xia, Jian-Ding Qiu
Luminol is introduced as a ligand for Tb3+ which, combined with GMP, leads to a sensor which is more robust, sensitive, and efficient.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.06.2018


The effect of crystal structure on the electromechanical properties of piezoelectric Nylon-11 nanowires

Chem. Commun., 2018, 54,6863-6866
DOI: 10.1039/C8CC02530D, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yeon Sik Choi, Sung Kyun Kim, Findlay Williams, Yonatan Calahorra, James A. Elliott, Sohini Kar-Narayan
Mechanical and piezoelectric properties of Nylon-11 nanowires strongly depend on their crystal structure, which can be precisely controlled by template-assisted growth methods.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2018


A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels

Chem. Commun., 2018, 54,6943-6946
DOI: 10.1039/C8CC02478B, Communication
Andreas J. D. Kruger, Jens Kohler, Stefan Cichosz, Jonas C. Rose, David B. Gehlen, Tamas Haraszti, Martin Moller, Laura De Laporte
Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers are end-modified with amine and epoxy groups to produce anisometric microgels with adaptable mechanical and (bio)chemical properties and self-assembly behaviour.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.06.2018


Transition-metal-free C-H amidation and chlorination: synthesis of N/N[prime or minute]-mono-substituted imidazopyridin-2-ones from N-pyridyl-N-hydroxylamine intermediates

Chem. Commun., 2018, 54,6935-6938
DOI: 10.1039/C8CC02425A, Communication
Katarzyna N. Lee, Dominique N. Spiegowski, Johnny W. Lee, Sanghyun Lim, Fuhua Zhao, Ming-Yu Ngai
Transition-metal-free C-H amidation and chlorination for the synthesis of N/N[prime or minute]-mono-substituted imidazopyridin-2-ones from versatile N-pyridyl-N-hydroxylamine intermediates at room temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 31.05.2018


Framework vs. side-chain amphidynamic behaviour in oligo-(ethylene oxide) functionalised covalent-organic frameworks

Chem. Commun., 2018, 54,6947-6950
DOI: 10.1039/C8CC04292F, Communication
Demetrius A. Vazquez-Molina, Giovanna M. Pope, Andrew A. Ezazi, Jose L. Mendoza-Cortes, James K. Harper, Fernando J. Uribe-Romo
We designed and synthesized crystalline covalent-organic frameworks that exhibit both slow and fast molecular motions in their structure.
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Datum: 31.05.2018


Bead-based screening in chemical biology and drug discovery

Chem. Commun., 2018, 54,6759-6771
DOI: 10.1039/C8CC02486C, Feature Article
Vitaly V. Komnatnyy, Thomas E. Nielsen, Katrine Qvortrup
High-throughput screening is an important component of the drug discovery process.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.05.2018


Total syntheses of spirocyclic PKS-NRPS-based fungal metabolites

Chem. Commun., 2018, 54,6750-6758
DOI: 10.1039/C8CC02315H, Feature Article
Deokhee Jo, Sunkyu Han
We present the isolations, the biosynthetic studies, the biological activities, and the comprehensive description of all reported total syntheses of spirocyclic PKS-NRPS-based fungal natural products.
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Datum: 30.05.2018


High-resolution mapping and recognition of lipid domains using AFM with toxin-derivatized probes

Chem. Commun., 2018, 54,6903-6906
DOI: 10.1039/C8CC02201A, Communication
Andra C. Dumitru, Louise Conrard, Cristina Lo Giudice, Patrick Henriet, Maria Veiga-da-Cunha, Sylvie Derclaye, Donatienne Tyteca, David Alsteens
Specific mapping using AFM tips derivatized with toxin fragments targeting specific lipids as a novel approach to evidence lateral lipid heterogeneities at high-resolution.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.05.2018


Design of functionalized cyclic peptides through orthogonal click reactions for cell culture and targeting applications

Chem. Commun., 2018, 54,6923-6926
DOI: 10.1039/C8CC03218A, Communication
Paige J. LeValley, Elisa M. Ovadia, Christopher A. Bresette, Lisa A. Sawicki, Emanual Maverakis, Shi Bai, April M. Kloxin
An approach for the design of functionalized cyclic peptides is established for use in 3D cell culture and in cell targeting.
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Datum: 29.05.2018


Synthesis of unsymmetrical Si-rhodamine fluorophores and application to a far-red to near-infrared fluorescence probe for hypoxia

Chem. Commun., 2018, 54,6939-6942
DOI: 10.1039/C8CC02451K, Communication
Kenjiro Hanaoka, Yu Kagami, Wen Piao, Takuya Myochin, Koji Numasawa, Yugo Kuriki, Takayuki Ikeno, Tasuku Ueno, Toru Komatsu, Takuya Terai, Tetsuo Nagano, Yasuteru Urano
A versatile synthesis of unsymmetrical Si-rhodamines was established and applied for development of a hypoxia-sensing far-red to NIR fluorescence probe.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 28.05.2018


Ambiphilic geometrically constrained phosphenium cation

Chem. Commun., 2018, 54,6931-6934
DOI: 10.1039/C8CC02423E, Communication
Solomon Volodarsky, Roman Dobrovetsky
Geometrically constrained phosphenium cation was synthesized, and in contrast to previously reported phosphenium cations, it is ambiphilic and reactive towards small molecules.
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Datum: 28.05.2018


Divergent synthesis of CF3-substituted polycyclic skeletons based on control of activation site of acid catalysts

Chem. Commun., 2018, 54,6927-6930
DOI: 10.1039/C8CC02377H, Communication
Kazuma Yokoo, Keiji Mori
We report a divergent synthesis of CF3-substituted fused skeletons based on precise control of the activation site through the selection of acid catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.05.2018


A [small pi]-conjugated inorganic polymer constructed from boron difluoride formazanates and platinum(II) diynes

Chem. Commun., 2018, 54,6899-6902
DOI: 10.1039/C8CC02424C, Communication
Jasveer S. Dhindsa, Ryan R. Maar, Stephanie M. Barbon, Maria Olivia Aviles, Zachary K. Powell, Francois Lagugne-Labarthet, Joe B. Gilroy
A [small pi]-conjugated inorganic polymer comprised of boron difluoride formazanate and platinum(II) diyne repeat units with unusual redox properties and a narrow optical band gap of ca. 1.4 eV is introduced.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.05.2018


Standing, lying, and sitting: translating building principles of the cell membrane to synthetic 2D material interfaces

Chem. Commun., 2018, 54,6681-6691
DOI: 10.1039/C8CC02596G, Feature Article
S. A. Claridge
Lessons can be drawn from cell membranes in controlling noncovalent functionalization of 2D materials to optimize interactions with the environment.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.05.2018


Oligoalanine helical callipers for cell penetration

Chem. Commun., 2018, 54,6919-6922
DOI: 10.1039/C8CC02304B, Communication
Marta Pazo, Marisa Juanes, Irene Lostale-Seijo, Javier Montenegro
Even for short peptides that are enriched in basic amino acids, the large chemical space that can be spanned by combinations of natural amino acids hinders the rational design of cell penetrating peptides.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2018


Low-overpotential CO2 reduction by a phosphine-substituted Ru(II) polypyridyl complex

Chem. Commun., 2018, 54,6915-6918
DOI: 10.1039/C8CC02150C, Communication
Sze Koon Lee, Mio Kondo, Go Nakamura, Masaya Okamura, Shigeyuki Masaoka
Low-overpotential electrochemical CO2 reduction by a Ru(II) polypyridyl complex can be achieved by the simple substitution of pyridine with a phosphine ligand.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2018


Improving metabolome coverage and data quality: advancing metabolomics and lipidomics for biomarker discovery

Chem. Commun., 2018, 54,6728-6749
DOI: 10.1039/C8CC02592D, Feature Article
Dajana Vuckovic
Separation and analytical sciences can help to advance metabolomics by improving metabolite coverage, accuracy of quantitation and data quality.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2018


Describing inorganic nanoparticles in the context of surface reactivity and catalysis

Chem. Commun., 2018, 54,6719-6727
DOI: 10.1039/C8CC03030H, Feature Article
S. Carenco
Surface and core of inorganic nanoparticles may undergo profound transformations in their environment of use. Accurate description is key to understand and control surface reactivity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 23.05.2018


Gold-catalyzed [5+2] cycloaddition of quinolinium zwitterions and allenamides as an efficient route to fused 1,4-diazepines

Chem. Commun., 2018, 54,6911-6914
DOI: 10.1039/C8CC02570C, Communication
Nirupam De, Choong Eui Song, Do Hyun Ryu, Eun Jeong Yoo
Herein, we demonstrate a new catalytic cycloaddition of quinolinium zwitterions involving a gold-bound allylic cation intermediate.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.05.2018


Conformationally-flexible and moderately electron-donating units-installed D-A-D triad enabling multicolor-changing mechanochromic luminescence, TADF and room-temperature phosphorescence

Chem. Commun., 2018, 54,6847-6850
DOI: 10.1039/C8CC02365D, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Youhei Takeda, Takahito Kaihara, Masato Okazaki, Heather Higginbotham, Przemyslaw Data, Norimitsu Tohnai, Satoshi Minakata
A novel multi-color-changing MCL compound has been developed that also shows TADF and RTP.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.05.2018


An electrolyte-gated polythiophene transistor for the detection of biogenic amines in water

Chem. Commun., 2018, 54,6907-6910
DOI: 10.1039/C8CC02462F, Communication
Tsukuru Minamiki, Yuki Hashima, Yui Sasaki, Tsuyoshi Minami
An ultra-low voltage operatable thin-film transistor based on a polythiophene pendant with a carboxy sidechain can detect biogenic amines in water.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.05.2018


Homologation chemistry with nucleophilic [small alpha]-substituted organometallic reagents: chemocontrol, new concepts and (solved) challenges

Chem. Commun., 2018, 54,6692-6704
DOI: 10.1039/C8CC02499E, Feature Article
Laura Castoldi, Serena Monticelli, Raffaele Senatore, Laura Ielo, Vittorio Pace
The transfer of a reactive nucleophilic CH2X unit into a preformed bond enables the introduction of a fragment featuring the exact and desired degree of functionalization through a single synthetic operation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.05.2018


Oxidative nitrene transfer from azides to alkynes via Ti(II)/Ti(IV) redox catalysis: formal [2+2+1] synthesis of pyrroles

Chem. Commun., 2018, 54,6891-6894
DOI: 10.1039/C8CC02623H, Communication
Adam J. Pearce, Xin Yi See, Ian A. Tonks
Catalytic oxidative nitrene transfer from azides with the early transition metals is rare, and has not been observed without the support of redox noninnocent spectator ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.05.2018


Synthesis of distorted nanographenes containing seven- and eight-membered carbocycles

Chem. Commun., 2018, 54,6705-6718
DOI: 10.1039/C8CC02325E, Feature Article
Irene R. Marquez, Silvia Castro-Fernandez, Alba Millan, Araceli G. Campana
We highlight recent progress in bottom-up synthesis of well-defined distorted polyaromatic hydrocarbons with saddle shapes containing heptagonal and octagonal carbocycles.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.05.2018


Suppression of dendritic lithium growth in lithium metal-based batteries

Chem. Commun., 2018, 54,6648-6661
DOI: 10.1039/C8CC02280A, Feature Article
Linlin Li, Siyuan Li, Yingying Lu
We describe the challenges of high-energy lithium-metal batteries and outline the future directions that are expected to drive their progress.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.05.2018


Cobalt complex catalyzed atom-economical synthesis of quinoxaline, quinoline and 2-alkylaminoquinoline derivatives

Chem. Commun., 2018, 54,6883-6886
DOI: 10.1039/C8CC02366B, Communication
Sujan Shee, Kasturi Ganguli, Kalipada Jana, Sabuj Kundu
A new phosphine-free Co(II) complex-catalyzed sustainable synthesis of quinoxalines, quinolines and 2-alkylaminoquinolines is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.05.2018


Application of lanthanide luminescence in probing enzyme activity

Chem. Commun., 2018, 54,6635-6647
DOI: 10.1039/C8CC02824A, Feature Article
Sarah H. Hewitt, Stephen J. Butler
Assays to monitor enzyme reactions are vital for studying enzyme mechanism, function and inhibition. We focus on recent progress in the development of enzyme activity assays using lanthanide(III) luminescence, covering Ln(III)-labelled biomolecules, Ln(III) ion encapsulation within peptide sequences, reactivity-based Ln(III) probes and discrete Ln(III) complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 15.05.2018


Production of solar chemicals: gaining selectivity with hybrid molecule/semiconductor assemblies

Chem. Commun., 2018, 54,6662-6680
DOI: 10.1039/C8CC02487A, Feature Article
Sean Hennessey, Pau Farras
This feature article highlights the use of hybrid molecule/semiconductor devices for the selective production of solar chemicals.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 15.05.2018


Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications

Chem. Commun., 2018, 54,6503-6519
DOI: 10.1039/C8CC02179A, Feature Article
Eleni Nestoros, Mihaiela C. Stuparu
The chemistry, properties and applications of corannulene are discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.05.2018


Role of conformational dynamics in the evolution of novel enzyme function

Chem. Commun., 2018, 54,6622-6634
DOI: 10.1039/C8CC02426J, Feature Article
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Miguel A. Maria-Solano, Eila Serrano-Hervas, Adrian Romero-Rivera, Javier Iglesias-Fernandez, Silvia Osuna
Enzymes exist as a dynamic ensemble of conformations, each potentially playing a key role in substrate binding, the chemical transformation, or product release. We discuss recent advances in the evaluation of the enzyme conformational dynamics and its evolution towards new functions or substrate preferences.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.05.2018


Room-temperature film formation of metal halide perovskites on n-type metal oxides: the catalysis of ZnO on perovskite crystallization

Chem. Commun., 2018, 54,6887-6890
DOI: 10.1039/C8CC02482K, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhongcheng Yuan, Sai Bai, Zhibo Yan, Jun-Ming Liu, Feng Gao
The ZnO/perovskite interface can efficiently catalyse the perovskite crystallization process even without thermal annealing.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.05.2018


PET-RAFT polymerisation: towards green and precision polymer manufacturing

Chem. Commun., 2018, 54,6591-6606
DOI: 10.1039/C8CC02783H, Feature Article
Jamie Phommalysack-Lovan, Yingying Chu, Cyrille Boyer, Jiangtao Xu
Photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) process has opened up a new way of precision polymer manufacturing to satisfy the concept of green chemistry.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 10.05.2018


Regioselective C-H alkenylation of imidazoles and its application to the synthesis of unsymmetrically substituted benzimidazoles

Chem. Commun., 2018, 54,6879-6882
DOI: 10.1039/C8CC02405G, Communication
Hyeongwoo Kim, Ye Ji Hwang, Inhyuk Han, Jung Min Joo
A palladium-catalyzed C5-selective alkenylation of imidazoles has been developed and applied to the synthesis of alkenyl imidazoles and multi-substituted benzimidazoles.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.05.2018


Tuning the molecular weight of polymeric amphiphiles as a tool to access micelles with a wide range of enzymatic degradation rates

Chem. Commun., 2018, 54,6875-6878
DOI: 10.1039/C8CC02415D, Communication
Gadi Slor, Nitsan Papo, Uri Hananel, Roey J. Amir
Tuning the molecular weight of polymeric amphiphiles allows access to polymeric micelles with extremely diverse enzymatic degradation and disassembly rates.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.05.2018


Redox-active, pyrene-based pristine porous organic polymers for efficient energy storage with exceptional cyclic stability

Chem. Commun., 2018, 54,6796-6799
DOI: 10.1039/C8CC02477D, Communication
Sujoy Bandyopadhyay, Chanderpratap Singh, Priyajit Jash, MD. Waseem Hussain, Amit Paul, Abhijit Patra
A pristine porous organic polymer with a polyaromatic core of pyrene and redox-active functionalities exhibits remarkable supercapacitor performance with long-term cyclic stability.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.05.2018


Catalytic asymmetric synthesis of spirooxindoles: recent developments

Chem. Commun., 2018, 54,6607-6621
DOI: 10.1039/C8CC02364F, Feature Article
Guang-Jian Mei, Feng Shi
The past four years have witnessed significant developments in the field of the catalytic asymmetric synthesis of spirooxindoles, and this feature article outlines the recent progress in this area, including the contributions of our group. This article is divided into sections according to the size and type of the generated spiro-ring fused at the C3-position of the oxindole core.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.05.2018


Rechargeable aqueous zinc-iodine batteries: pore confining mechanism and flexible device application

Chem. Commun., 2018, 54,6792-6795
DOI: 10.1039/C8CC02616E, Communication
Yixin Li, Luojia Liu, Haixia Li, Fangyi Cheng, Jun Chen
Confining iodine in the micropores of carbon cloth suppresses unfavorable triiodide intermediates and enables superior performance of assembled flexible zinc-iodine batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 04.05.2018


Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous n-alkanes through a highly sensitive solvent-dependent helix inversion

Chem. Commun., 2018, 54,6867-6870
DOI: 10.1039/C8CC02836B, Communication
Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome
Abnormal sergeants-and-soldiers enabled the discrimination of a single methylene group.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.05.2018


Proton and ammonia intercalation into layered iron chalcogenides

Chem. Commun., 2018, 54,6895-6898
DOI: 10.1039/C8CC02436G, Communication
Xiuquan Zhou, Brandon Wilfong, Sz-Chian Liou, Halyna Hodovanets, Craig M. Brown, Efrain E. Rodriguez
Hydrothermal synthesis of ammonia-intercalated iron chalcogenides using an alkali-free route.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.05.2018


Tandem cyclization of o-alkynylanilines with isocyanides triggered by intramolecular nucleopalladation: access to heterocyclic fused 2-aminoquinolines

Chem. Commun., 2018, 54,6855-6858
DOI: 10.1039/C8CC02028K, Communication
Wanqing Wu, Meng Li, Jia Zheng, Weigao Hu, Chunsheng Li, Huanfeng Jiang
A novel strategy for the synthesis of heterocyclic fused 2-aminoquinolines via palladium-catalyzed tandem cyclization of o-alkynylanilines and isocyanides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 02.05.2018


The role of mid-gap states in all-inorganic CsPbBr3 nanoparticle one photon up-conversion

Chem. Commun., 2018, 54,6851-6854
DOI: 10.1039/C8CC02430H, Communication
Benjamin J. Roman, Matthew Sheldon
CsPbBr3 nanoparticles that have been treated with NH4SCN to produce essentially trap-free surfaces show an increase of one photon up-conversion quantum yield with little change to the up-conversion energy of activation, as estimated using an Arrhenius analysis.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.05.2018


Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H+ conductivity

Chem. Commun., 2018, 54,6859-6862
DOI: 10.1039/C8CC02399A, Communication
Yuki Ohara, Akira Hinokimoto, Wenqian Chen, Takashi Kitao, Yusuke Nishiyama, You-lee Hong, Susumu Kitagawa, Satoshi Horike
Metal ion-dependent glass formation of coordination polymer crystals and direct molecular doping for the glass are studied with H+ conductivity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.05.2018


Improved radical stability of viologen anolytes in aqueous organic redox flow batteries

Chem. Commun., 2018, 54,6871-6874
DOI: 10.1039/C8CC02336K, Communication
Bo Hu, Yijie Tang, Jian Luo, Grant Grove, Yisong Guo, T. Leo Liu
A 1.38 V aqueous organic redox flow battery demonstrated 97.48% capacity retention for 500 cycles and 128 mW cm-2 power density.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.05.2018


Metal coordination and metal activation abilities of commonly unreactive chloromethanes toward metal-organic frameworks

Chem. Commun., 2018, 54,6458-6471
DOI: 10.1039/C8CC02348D, Feature Article
Jinhee Bae, Eun Ji Lee, Nak Cheon Jeong
The commonly inert chloromethanes, dichloromethane and trichloromethane, can exchange other solvents bonded at open coordination sites in metal-organic frameworks, providing a new route to activate the open coordination sites for subsequent use in applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.05.2018


The journey of tin chalcogenides towards high-performance thermoelectrics and topological materials

Chem. Commun., 2018, 54,6573-6590
DOI: 10.1039/C8CC02230E, Feature Article
Ananya Banik, Subhajit Roychowdhury, Kanishka Biswas
Sn-Chalcogenides are recognized as high performance thermoelectrics and topological insulators due to their unique crystal and electronic structures and lattice dynamics.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 01.05.2018


Cooperative bond activation reactions with carbene complexes

Chem. Commun., 2018, 54,6540-6553
DOI: 10.1039/C8CC02198H, Feature Article
Kai-Stephan Feichtner, Viktoria H. Gessner
This review highlights the recent advances in the application of carbene complexes in bond activation reactions via metal-ligand cooperation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.04.2018


Artificial photosynthesis by light absorption, charge separation, and multielectron catalysis

Chem. Commun., 2018, 54,6554-6572
DOI: 10.1039/C8CC02156B, Feature Article
Milos Dokic, Han Sen Soo
We highlight recent novel approaches in the field of artificial photosynthesis. We emphasize the potential of a highly modular plug-and-play concept that we hope will persuade the community to explore a more inclusive variety of multielectron redox catalysis to complement the proton reduction and water oxidation half-reactions in traditional solar water splitting systems.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 30.04.2018


cat-ELCCA: catalyzing drug discovery through click chemistry

Chem. Commun., 2018, 54,6531-6539
DOI: 10.1039/C8CC02332H, Feature Article
Amanda L. Garner
Click chemistry-based amplification assays provide enabling tools for chemical probe and drug discovery.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 25.04.2018


Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones

Chem. Commun., 2018, 54,6843-6846
DOI: 10.1039/C8CC02314J, Communication
Milan Kumar Bisai, Tamal Das, Kumar Vanka, Sakya S. Sen
Simple and readily accessible lithium compounds are found to be efficient single site catalysts for cyanosilylation and hydroboration of a range of aldehydes and ketones under ambient conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 24.04.2018


Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate-alkoxide clusters

Chem. Commun., 2018, 54,6839-6842
DOI: 10.1039/C8CC01517A, Communication
L. E. VanGelder, P. L. Forrestel, W. W. Brennessel, E. M. Matson
Syntheses and site differentiated reactivity for titanium-functionalized polyoxovanadate-alkoxide clusters are presented. We present insights into the mechanism and electronic consequences metal oxide halogenation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.04.2018


Expanding the limit of Pd-catalyzed decarboxylative benzylations

Chem. Commun., 2018, 54,6835-6838
DOI: 10.1039/C8CC02380H, Communication
Duanyang Kong, Patrick J. Moon, Wenyu Qian, Rylan J. Lundgren
The Pd-catalyzed decarboxylative benzylation of aryl bromides using a diverse range of electron-deficient aryl acetates is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.04.2018


Bioinspired synthesis of pentalene-based chromophores from an oligoketone chain

Chem. Commun., 2018, 54,6788-6791
DOI: 10.1039/C8CC02379D, Communication
Yuki Saito, Masayuki Higuchi, Shota Yoshioka, Hisanori Senboku, Yasuhide Inokuma
Inspired by natural polyketide synthesis, pentalene-based, cross-conjugated chromophores were synthesized from an aliphatic oligoketone chain.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 17.04.2018


Liquid-phase oxidation of alkanes with molecular oxygen catalyzed by high valent iron-based perovskite

Chem. Commun., 2018, 54,6772-6775
DOI: 10.1039/C8CC02185F, Communication
Satomi Shibata, Kosei Sugahara, Keigo Kamata, Michikazu Hara
A hexagonal BaFeO3-[small delta] perovskite catalyst containing high valent iron species exhibits high catalytic performance for the aerobic oxidation of alkanes without the need for additives.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 16.04.2018


Well defined difluorogold(III) complexes supported by N-ligands

Chem. Commun., 2018, 54,6832-6834
DOI: 10.1039/C8CC02535E, Communication
Mohammad Albayer, Robert Corbo, Jason L. Dutton
Rare difluorogold(III) complexes supported by N-ligands can be synthesized simply either from Au(I) precursors using XeF2 or Au(III) using KF.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 12.04.2018


Translating MOF chemistry into supramolecular chemistry: soluble coordination nanofibers showing efficient photon upconversion

Chem. Commun., 2018, 54,6828-6831
DOI: 10.1039/C8CC01594E, Communication
Masanori Hosoyamada, Nobuhiro Yanai, Keisuke Okumura, Takayuki Uchihashi, Nobuo Kimizuka
Photon upconverting coordination nanofibers are constructed by extracting the structural motifs of metal-organic frameworks (MOFs).
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 11.04.2018


Three cooperative diffusion coefficients describing dynamics of polymer gels

Chem. Commun., 2018, 54,6784-6787
DOI: 10.1039/C8CC01357H, Communication
Takeshi Fujiyabu, Felicia Toni, Xiang Li, Ung-il Chung, Takamasa Sakai
We measured three cooperative diffusion coefficients describing the dynamics of polymer gels, and provided the experimental evidence to fundamentally understand it.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 03.04.2018


An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

Chem. Commun., 2018, 54,6824-6827
DOI: 10.1039/C8CC01399C, Communication
Youngsuk Kim, Eunsung Lee
The presented N-heterocyclic carbene iminoxyl borate radical zwitterion shows remarkable stability toward air, moisture, and silica gel.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 27.03.2018


Lanthanide-based near-infrared emitting metal-organic frameworks with tunable excitation wavelengths and high quantum yields

Chem. Commun., 2018, 54,6816-6819
DOI: 10.1039/C8CC01294F, Communication
Tu N. Nguyen, Gloria Capano, Andrzej Gladysiak, Fatmah Mish Ebrahim, Svetlana V. Eliseeva, Arunraj Chidambaram, Bardiya Valizadeh, Stephane Petoud, Berend Smit, Kyriakos C. Stylianou
The introduction of -NH2 group in SION-100 allows the visible light absorption, and both SION-100 and SION-100-NH2 luminesce NIR light with long lifetimes and high quantum yields.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 26.03.2018


A microfluidic photoreactor enables 2-methylbenzophenone light-driven reactions with superior performance

Chem. Commun., 2018, 54,6820-6823
DOI: 10.1039/C8CC01373J, Communication
Javier Mateos, Alessio Cherubini-Celli, Tommaso Carofiglio, Marcella Bonchio, Nadia Marino, Xavier Companyo, Luca Dell'Amico
A general and scalable microfluidic photoreactor for light-driven reaction of 2-methylbenzophenones was successfully developed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 21.03.2018


Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitriles

Chem. Commun., 2018, 54,6812-6815
DOI: 10.1039/C8CC01189C, Communication
Meishan Ji, Jiajia Yu, Chen Zhu
Herein a novel, elusive cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes by means of intramolecular distal cyano migration is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 20.03.2018


Integrated nanozymes: facile preparation and biomedical applications

Chem. Commun., 2018, 54,6520-6530
DOI: 10.1039/C8CC01202D, Feature Article
Jiangjiexing Wu, Sirong Li, Hui Wei
Attributed to nanoscale proximity effects, integrated nanozymes with superior activities, specificity, and stability will be a hot topic in the future.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 13.03.2018


Ordered meso- and macroporous perovskite oxide catalysts for emerging applications

Chem. Commun., 2018, 54,6484-6502
DOI: 10.1039/C8CC01239C, Feature Article
Hamidreza Arandiyan, Yuan Wang, Hongyu Sun, Mehran Rezaei, Hongxing Dai
Hierarchically ordered perovskite materials which have potential applications in chemistry, energy and materials science.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.03.2018


Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

Chem. Commun., 2018, 54,6808-6811
DOI: 10.1039/C8CC01529E, Communication
Sam Yruegas, Jesse J. Martinez, Caleb D. Martin
The reactions of 9-borafluorenes with organic azides result in either the insertion of the [small alpha]-nitrogen and elimination of N2 or the insertion of the [gamma]-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 09.03.2018


Orthogonality in main group compounds: a direct one-step synthesis of air- and moisture-stable cyclophosphazanes by mechanochemistry

Chem. Commun., 2018, 54,6800-6803
DOI: 10.1039/C8CC01043A, Communication
Ying Sim, Davin Tan, Rakesh Ganguly, Yongxin Li, Felipe Garcia
Mechanochemistry has been established to be an environmentally-friendly way of conducting reactions in a solvent-free manner.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 08.03.2018


A chiral aluminum solvating agent (CASA) for 1H NMR chiral analysis of alcohols at low temperature

Chem. Commun., 2018, 54,6804-6807
DOI: 10.1039/C8CC00574E, Communication
Min-Seob Seo, Sumin Jang, Hyunwoo Kim
A chiral aluminum solvating agent (CASA) was demonstrated to be a general and efficient reagent for 1H NMR chiral analysis of alcohols.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.03.2018


Synergistic palladium/copper-catalyzed Csp3-Csp2 cross-couplings using aldehydes as latent [small alpha]-alkoxyalkyl anion equivalents

Chem. Commun., 2018, 54,6776-6779
DOI: 10.1039/C8CC01055B, Communication
Mitsutaka Takeda, Kenya Yabushita, Shigeo Yasuda, Hirohisa Ohmiya
The first Csp3-Csp2 cross-coupling using aldehydes as latent [small alpha]-alkoxyalkyl anion equivalents has been achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 14.02.2018


Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

Chem. Commun., 2018, 54,6472-6483
DOI: 10.1039/C7CC09780H, Feature Article
Ekaterina A. Dolgopolova, Allison M. Rice, Natalia B. Shustova
In this review, we highlight how recent advances in the field of actinide structural chemistry of metal-organic frameworks (MOFs) could be utilized towards investigations relative to efficient nuclear waste administration, driven by the interest towards development of novel actinide-containing architectures as well as concerns regarding environmental pollution and nuclear waste storage.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 06.02.2018


Visible light-driven photocatalytic generation of sulfonamidyl radicals for alkene hydroamination of unsaturated sulfonamides

Chem. Commun., 2018, 54,6780-6783
DOI: 10.1039/C7CC09871E, Communication
Jun Chen, Hong-Mei Guo, Quan-Qing Zhao, Jia-Rong Chen, Wen-Jing Xiao
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished.
The content of this RSS Feed (c) The Royal Society of Chemistry

Datum: 29.01.2018


 


Category: Current Chemistry Research

Last update: 28.03.2018.






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