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Journal of Organic Chemistry - Current Research Articles



Current research articles: Organic Chemistry

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Journal of Organic Chemistry - Editor: American Chemical Society, ACS

JOC welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry.




Current articles of the journal:



Theoretical Investigations on the Mechanism of Dual 1,3-Dipolar Cycloaddition of CO2 with Isocyanides and Alkynes

TOC Graphic

The Journal of Organic Chemistry
DOI: 10.1021/jo5017053

Posted on 31 October 2014 | 2:21 pm


Synthesis of Multisubstituted Pyrroles from Doubly Activated Cyclopropanes Using an Iron-Mediated Oxidation Domino Reaction

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018487

Posted on 31 October 2014 | 1:35 pm


Magnetic Superbasic Proton Sponges Are Readily Removed and Permit Direct Product Isolation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501913z

Posted on 31 October 2014 | 5:11 am


Dehydrative C–H/N–OH Functionalizations in H2O by Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight

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The Journal of Organic Chemistry
DOI: 10.1021/jo501884v

Posted on 30 October 2014 | 8:59 pm


Organocatalytic Diversity-Oriented Asymmetric Synthesis of Tricyclic Chroman Derivatives

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The Journal of Organic Chemistry
DOI: 10.1021/jo501560m

Posted on 30 October 2014 | 8:40 pm


Asymmetric Syntheses of (?)-3-epi-Fagomine, (2R,3S,4R)-Dihydroxypipecolic Acid, and Several Polyhydroxylated Homopipecolic Acids

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The Journal of Organic Chemistry
DOI: 10.1021/jo501952t

Posted on 30 October 2014 | 6:55 pm


Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates

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The Journal of Organic Chemistry
DOI: 10.1021/jo502260x

Posted on 30 October 2014 | 6:37 pm


Dynamic Combinatorial Libraries of 2,5-Diformylfuran-Derived Macrocycles

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The Journal of Organic Chemistry
DOI: 10.1021/jo501966q

Posted on 30 October 2014 | 12:54 pm


N,N?-Dioxide–Scandium(III)-Catalyzed Asymmetric Aza-Friedel–Crafts Reaction of Sesamol with Aldimines

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The Journal of Organic Chemistry
DOI: 10.1021/jo5020036

Posted on 29 October 2014 | 3:21 pm


Diastereoselective Synthesis of Functionalized Spirocyclopropyl Oxindoles via P(NMe2)3-Mediated Reductive Cyclopropanation

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The Journal of Organic Chemistry
DOI: 10.1021/jo502106c

Posted on 29 October 2014 | 2:25 pm


Copper-Mediated Direct Alkoxylation of Arenes Using an N,O-Bidentate Directing System

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The Journal of Organic Chemistry
DOI: 10.1021/jo502005j

Posted on 29 October 2014 | 2:15 pm


Synthesis of N-Oxyamide-Linked Neoglycolipids

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The Journal of Organic Chemistry
DOI: 10.1021/jo502128h

Posted on 28 October 2014 | 9:34 pm


Iodine-Mediated Thiolation of Substituted Naphthols/Naphthylamines and Arylsulfonyl Hydrazides via C(sp2)–H Bond Functionalization

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The Journal of Organic Chemistry
DOI: 10.1021/jo501778h

Posted on 28 October 2014 | 9:33 pm


Homologation of Boronic Esters with Organolithium Compounds: A Computational Assessment of Mechanism

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The Journal of Organic Chemistry
DOI: 10.1021/jo502020e

Posted on 28 October 2014 | 8:53 pm


Synthesis by Direct Arylation of Thiazole–Derivatives: Regioisomer Configurations–Optical Properties Relationship Investigation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501685t

Posted on 27 October 2014 | 9:06 pm


Regio- and Stereoselective Monoepoxidation of Dienes using Methyltrioxorhenium: Synthesis of Allylic Epoxides

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The Journal of Organic Chemistry
DOI: 10.1021/jo501958d

Posted on 27 October 2014 | 3:43 pm


Palladium- and Nickel-Catalyzed Kumada Cross-Coupling Reactions of gem-Difluoroalkenes and Monofluoroalkenes with Grignard Reagents

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The Journal of Organic Chemistry
DOI: 10.1021/jo5022234

Posted on 27 October 2014 | 2:27 pm


Reduction of N-Allylamides by LiAlH4: Unexpected Attack of the Double Bond with Mechanistic Studies of Product and Byproduct Formation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501907v

Posted on 27 October 2014 | 2:27 pm


Access to 4-Alkylaminopyridazine Derivatives via Nitrogen-Assisted Regioselective Pd-Catalyzed Reactions

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The Journal of Organic Chemistry
DOI: 10.1021/jo501930s

Posted on 27 October 2014 | 2:27 pm


The Toolbox of Synthetic Reactions: A Key to Unlock the Design of Structure for Function

The Journal of Organic Chemistry
DOI: 10.1021/jo502354a

Posted on 27 October 2014 | 1:12 pm


Kondrat’eva Ligation: Diels–Alder-Based Irreversible Reaction for Bioconjugation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501972m

Posted on 27 October 2014 | 11:27 am


Divergent Total Synthesis of Triptolide, Triptonide, Tripdiolide, 16-Hydroxytriptolide, and Their Analogues

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The Journal of Organic Chemistry
DOI: 10.1021/jo501744j

Posted on 24 October 2014 | 7:13 pm


4,4?,4?-Trimethyl-2,2?:6?,2?-terpyridine by Oxidative Coupling of 4-Picoline

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The Journal of Organic Chemistry
DOI: 10.1021/jo501925s

Posted on 24 October 2014 | 4:54 pm


?-Alkylation of Ketones with Primary Alcohols Catalyzed by a Cp*Ir Complex Bearing a Functional Bipyridonate Ligand

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The Journal of Organic Chemistry
DOI: 10.1021/jo502051d

Posted on 23 October 2014 | 9:02 pm


Redox and Lewis Acid Relay Catalysis: A Titanocene/Zinc Catalytic Platform in the Development of Multicomponent Coupling Reactions

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The Journal of Organic Chemistry
DOI: 10.1021/jo501890z

Posted on 23 October 2014 | 9:01 pm


Insights into the ?-Sultam Ring Formation in the Sulfa-Staudinger Cycloadditions

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The Journal of Organic Chemistry
DOI: 10.1021/jo5020933

Posted on 23 October 2014 | 5:07 pm


Origin of Inversion versus Retention in the Oxidative Addition of 3-Chloro-cyclopentene to Pd(0)Ln

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The Journal of Organic Chemistry
DOI: 10.1021/jo5020068

Posted on 23 October 2014 | 3:26 pm


Asymmetric Intramolecular Carbolithiation of Achiral Substrates: Synthesis of Enantioenriched (R)-(+)-Cuparene and (R)-(+)-Herbertene

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The Journal of Organic Chemistry
DOI: 10.1021/jo502139m

Posted on 23 October 2014 | 12:40 pm


Variants of the Prins Cyclization for the Synthesis of Terpenoid Spiroethers and Oxabicyclo[3.3.1]Nonane Derivatives

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The Journal of Organic Chemistry
DOI: 10.1021/jo501755x

Posted on 23 October 2014 | 12:40 pm


Organocatalytic Arylation of 3-Indolylmethanols via Chemo- and Regiospecific C6-Functionalization of Indoles

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The Journal of Organic Chemistry
DOI: 10.1021/jo501989x

Posted on 22 October 2014 | 4:49 pm


Electronic Effects of Ring Fusion and Alkyne Substitution on Acene Properties and Reactivity

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The Journal of Organic Chemistry
DOI: 10.1021/jo501696d

Posted on 22 October 2014 | 4:48 pm


Regioselective Synthesis of 3-Aminoimidazo[1,2-a]-pyrimidines under Continuous Flow Conditions

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The Journal of Organic Chemistry
DOI: 10.1021/jo501861g

Posted on 22 October 2014 | 4:24 pm


Stereocontrolled Disruption of the Ugi Reaction toward the Production of Chiral Piperazinones: Substrate Scope and Process Development

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018316

Posted on 22 October 2014 | 3:29 pm


Ruthenium-Catalyzed Asymmetric [2 + 2] Cycloadditions between Chiral Acyl Camphorsultam-Substituted Alkynes and Bicyclic Alkenes

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The Journal of Organic Chemistry
DOI: 10.1021/jo501594g

Posted on 21 October 2014 | 10:03 pm


Palladium-Catalyzed Annulation of Alkynes with Ortho-Halide-Containing Benzyl Alcohols in Aqueous Medium

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The Journal of Organic Chemistry
DOI: 10.1021/jo501444g

Posted on 21 October 2014 | 10:01 pm


Reactions of Nitrosoalkenes with Dipyrromethanes and Pyrroles: Insight into the Mechanistic Pathway

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The Journal of Organic Chemistry
DOI: 10.1021/jo502095k

Posted on 21 October 2014 | 10:00 pm


Gallium-Catalyzed Reductive Chlorination of Carboxylic Acids with Copper(II) Chloride

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The Journal of Organic Chemistry
DOI: 10.1021/jo501912v

Posted on 21 October 2014 | 7:25 pm


Mechanistic Insights into N?N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides

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The Journal of Organic Chemistry
DOI: 10.1021/jo501865b

Posted on 21 October 2014 | 5:44 pm


A Visible-Light-Promoted Aerobic Metal-Free C-3 Thiocyanation of Indoles

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The Journal of Organic Chemistry
DOI: 10.1021/jo5015799

Posted on 21 October 2014 | 6:58 am


Regioselective (Diacetoxyiodo)benzene-Promoted Halocyclization of Unfunctionalized Olefins

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The Journal of Organic Chemistry
DOI: 10.1021/jo501739j

Posted on 20 October 2014 | 10:12 pm


?-Amino Esters from the Reductive Ring Opening of Aziridine-2-carboxylates

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The Journal of Organic Chemistry
DOI: 10.1021/jo501694h

Posted on 20 October 2014 | 4:29 pm


Donor- and/or Acceptor-Substituted Expanded Radialenes: Theory, Synthesis, and Properties

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The Journal of Organic Chemistry
DOI: 10.1021/jo5016085

Posted on 20 October 2014 | 3:37 pm


Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+

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The Journal of Organic Chemistry
DOI: 10.1021/jo501886w

Posted on 20 October 2014 | 3:37 pm


Investigation of Diastereoselective Acyclic ?-Alkoxydithioacetal Substitutions Involving Thiacarbenium Intermediates

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The Journal of Organic Chemistry
DOI: 10.1021/jo502181a

Posted on 20 October 2014 | 3:36 pm


Deformative Transition of the Menschutkin Reaction and Helical Atropisomers in a Congested Polyheterocyclic System

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The Journal of Organic Chemistry
DOI: 10.1021/jo501815y

Posted on 20 October 2014 | 3:27 pm


Salvadenosine, a 5?-Deoxy-5?-(methylthio) Nucleoside from the Bahamian Tunicate Didemnum sp.

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The Journal of Organic Chemistry
DOI: 10.1021/jo501486p

Posted on 20 October 2014 | 6:41 am


Beyond the Corey Reaction II: Dimethylenation of Sterically Congested Ketones

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The Journal of Organic Chemistry
DOI: 10.1021/jo502021x

Posted on 19 October 2014 | 2:00 pm


No Acid Required: 4? and 6? Electrocyclization Reactions of Dienyl Diketones for the Synthesis of Cyclopentenones and 2H-Pyrans

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The Journal of Organic Chemistry
DOI: 10.1021/jo501914w

Posted on 17 October 2014 | 9:56 pm


Switching of the Triplet Excited State of Styryl 2,6-Diiodo-Bodipy and Its Application in Acid-Activatable Singlet Oxygen Photosensitizing

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The Journal of Organic Chemistry
DOI: 10.1021/jo5019014

Posted on 17 October 2014 | 3:45 pm


Mechanistic Insight into Aerobic Alcohol Oxidation Using NOx–Nitroxide Catalysis Based on Catalyst Structure–Activity Relationships

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The Journal of Organic Chemistry
DOI: 10.1021/jo501862k

Posted on 17 October 2014 | 3:15 pm


Independent Generation and Reactivity of Uridin-2?-yl Radical

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The Journal of Organic Chemistry
DOI: 10.1021/jo501916r

Posted on 17 October 2014 | 3:15 pm


Mechanochemical Preparation of Hydantoins from Amino Esters: Application to the Synthesis of the Antiepileptic Drug Phenytoin

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The Journal of Organic Chemistry
DOI: 10.1021/jo5017629

Posted on 17 October 2014 | 3:14 pm


Copper-Mediated Intramolecular Oxidative C–H/C–H Cross-Coupling of ?-Oxo Ketene N,S-Acetals for Indole Synthesis

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The Journal of Organic Chemistry
DOI: 10.1021/jo5014542

Posted on 16 October 2014 | 10:19 pm


Pyridine-NHC: Effective Ligand in Pd-Catalyzed Cyclopropanation of Esters with Substituted Allyl Carbonates

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018712

Posted on 16 October 2014 | 3:14 pm


Palladium-Catalyzed Direct Regioselective ortho-Phosphonation of Aromatic Azo Compounds with Dialkyl Phosphites

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The Journal of Organic Chemistry
DOI: 10.1021/jo501928x

Posted on 16 October 2014 | 3:11 pm


Electrochemical Cleavage of Aryl Ethers Promoted by Sodium Borohydride

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018537

Posted on 15 October 2014 | 10:36 pm


Protonated Alcohols Are Examples of Complete Charge-Shift Bonds

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The Journal of Organic Chemistry
DOI: 10.1021/jo501549q

Posted on 15 October 2014 | 9:01 pm


Selective Perfluoro- and Polyfluoroarylation of Meldrum’s Acid

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The Journal of Organic Chemistry
DOI: 10.1021/jo502075p

Posted on 15 October 2014 | 8:38 pm


Synthesis of Highly Substituted Adamantanones from Bicyclo[3.3.1]nonanes

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The Journal of Organic Chemistry
DOI: 10.1021/jo501368d

Posted on 15 October 2014 | 3:24 pm


From Amino Acids to Nature-Inspired Molecular Scaffolds: Incorporation of Medium-Sized Bridged Heterocycles into a Peptide Backbone

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The Journal of Organic Chemistry
DOI: 10.1021/jo501983j

Posted on 15 October 2014 | 12:48 pm


Pushing Steric Bias in the Scholl Reaction to Access Liquid Crystalline Crown Ethers

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The Journal of Organic Chemistry
DOI: 10.1021/jo501790d

Posted on 15 October 2014 | 6:00 am


Palladium-Catalyzed Carbonylative Synthesis of Benzoxazinones from N-(o-Bromoaryl)amides Using Paraformaldehyde as the Carbonyl Source

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The Journal of Organic Chemistry
DOI: 10.1021/jo5020118

Posted on 14 October 2014 | 10:33 pm


Mechanism and Selectivity of Methyl and Phenyl Migrations in Hypervalent Silylated Iminoquinones

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The Journal of Organic Chemistry
DOI: 10.1021/jo501888r

Posted on 14 October 2014 | 5:35 pm


Functionalization of 3,5,8-Trichlorinated BODIPY Dyes

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The Journal of Organic Chemistry
DOI: 10.1021/jo501969z

Posted on 14 October 2014 | 4:57 pm


Selective Formation of a Z-Trisubstituted Double Bond Using a 1-(tert-Butyl)tetrazolyl Sulfone

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The Journal of Organic Chemistry
DOI: 10.1021/jo501988e

Posted on 14 October 2014 | 4:57 pm


General Synthesis of Substituted 1,2-Dihydropyridines

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The Journal of Organic Chemistry
DOI: 10.1021/jo501991s

Posted on 14 October 2014 | 12:31 pm


Platinum-Catalyzed Tandem Cycloisomerization Reaction of Benzoendiynyl Esters: Regioselective Long-Range 1,5-Acyl Migration

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The Journal of Organic Chemistry
DOI: 10.1021/jo5020245

Posted on 13 October 2014 | 8:25 pm


Synthesis and Solution Aggregation Studies of a Suite of Mixed Neutral and Zwitterionic Chromophores for Second-Order Nonlinear Optics

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018124

Posted on 13 October 2014 | 7:22 pm


Capricious Selectivity in Electrophilic Deuteration of Methylenedioxy Substituted Aromatic Compounds

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The Journal of Organic Chemistry
DOI: 10.1021/jo5019427

Posted on 13 October 2014 | 5:25 pm


Synthesis and Direct C2 Functionalization of Imidazolium and 1,2,4-Triazolium N-Imides

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The Journal of Organic Chemistry
DOI: 10.1021/jo501746u

Posted on 10 October 2014 | 10:48 pm


I2-Mediated Oxidative Cyclization for Synthesis of Substituted Indolizines

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The Journal of Organic Chemistry
DOI: 10.1021/jo5019574

Posted on 10 October 2014 | 8:47 pm


Zinc-Mediated One-Pot Tandem Reaction of Nitriles with Propargyl Bromides: An Access to 3-Alkynylpyridines

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The Journal of Organic Chemistry
DOI: 10.1021/jo501869d

Posted on 10 October 2014 | 2:05 pm


A Foldable Cyclic Oligomer: Chiroptical Modulation through Molecular Folding upon Complexation and a Change in Temperature

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The Journal of Organic Chemistry
DOI: 10.1021/jo501883m

Posted on 9 October 2014 | 9:20 pm


Carbonylation of cis-Disubstituted Epoxides to trans-?-Lactones: Catalysts Displaying Steric and Contrasteric Regioselectivity

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The Journal of Organic Chemistry
DOI: 10.1021/jo501899e

Posted on 9 October 2014 | 9:20 pm


Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501665e

Posted on 9 October 2014 | 7:48 pm


Synthesis of the Putative Structure of 15-Oxopuupehenoic Acid

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The Journal of Organic Chemistry
DOI: 10.1021/jo502048y

Posted on 9 October 2014 | 6:54 am


Regioselective Cope Rearrangement and Prenyl Transfers on Indole Scaffold Mimicking Fungal and Bacterial Dimethylallyltryptophan Synthases

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The Journal of Organic Chemistry
DOI: 10.1021/jo501651z

Posted on 9 October 2014 | 6:53 am


Computational Characterization of the Mechanism for Coinage-Metal-Catalyzed Carboxylation of Terminal Alkynes

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The Journal of Organic Chemistry
DOI: 10.1021/jo501837p

Posted on 8 October 2014 | 5:15 pm


Mechanism of SmI2/Amine/H2O-Promoted Chemoselective Reductions of Carboxylic Acid Derivatives (Esters, Acids, and Amides) to Alcohols

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018525

Posted on 8 October 2014 | 2:48 pm


Kinetic and Computational Studies on Pd(I) Dimer-Mediated Halogen Exchange of Aryl Iodides

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The Journal of Organic Chemistry
DOI: 10.1021/jo501889j

Posted on 6 October 2014 | 7:11 pm


Iridium(III)-Catalyzed Direct C-7 Amination of Indolines with Organic Azides

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018475

Posted on 26 September 2014 | 4:22 pm


Theoretical Studies on the Regioselectivity of Iridium-Catalyzed 1,3-Dipolar Azide–Alkyne Cycloaddition Reactions

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018348

Posted on 25 September 2014 | 7:24 pm


Palladium-Catalyzed Intermolecular Oxyvinylcyclization of Alkenes with Alkynes: An Approach to 3-Methylene ?-Lactones and Tetrahydrofurans

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The Journal of Organic Chemistry
DOI: 10.1021/jo501606c

Posted on 22 September 2014 | 4:23 pm


Reaction Progress Kinetic Analysis of a Copper-Catalyzed Aerobic Oxidative Coupling Reaction with N-Phenyl Tetrahydroisoquinoline

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The Journal of Organic Chemistry
DOI: 10.1021/jo5018876

Posted on 19 September 2014 | 7:24 pm


Ruthenium-Catalyzed Regioselective Allylic Trifluoromethylthiolation Reaction

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The Journal of Organic Chemistry
DOI: 10.1021/jo5019393

Posted on 18 September 2014 | 3:05 pm


Mechanistic Study of the Selectivity of Olefin versus Cyclobutene Formation by Palladium(0)-Catalyzed Intramolecular C(sp3)–H Activation

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The Journal of Organic Chemistry
DOI: 10.1021/jo501610x

Posted on 11 September 2014 | 4:48 pm


Hydroesterification of Alkenes with Sodium Formate and Alcohols Promoted by Cooperative Catalysis of Ru3(CO)12 and 2-Pyridinemethanol

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The Journal of Organic Chemistry
DOI: 10.1021/jo501828j

Posted on 11 September 2014 | 3:06 pm


Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols

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The Journal of Organic Chemistry
DOI: 10.1021/jo501813d

Posted on 10 September 2014 | 8:20 pm


Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides with Diaryliodonium Salts in the Presence of a Nickel Catalyst

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The Journal of Organic Chemistry
DOI: 10.1021/jo501691f

Posted on 4 September 2014 | 5:52 pm


Synthesis and Biological Evaluation of Kendomycin and Its Analogues

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The Journal of Organic Chemistry
DOI: 10.1021/jo5015273

Posted on 26 August 2014 | 8:47 pm


Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group

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The Journal of Organic Chemistry
DOI: 10.1021/jo501697n

Posted on 21 August 2014 | 2:22 pm


Enantioselective Carbonyl–Ene Reactions Catalyzed by Chiral Cationic Dirhodium(II,III) Carboxamidates

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The Journal of Organic Chemistry
DOI: 10.1021/jo5013674

Posted on 11 August 2014 | 7:47 pm


Palladium-Catalyzed Thiocarbonylation of Aryl, Vinyl, and Benzyl Bromides

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The Journal of Organic Chemistry
DOI: 10.1021/jo5009965

Posted on 17 June 2014 | 2:23 pm


Synthesis of Indolo[2,1-a]isoquinolines via a Triazene-Directed C–H Annulation Cascade

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The Journal of Organic Chemistry
DOI: 10.1021/jo500807d

Posted on 22 May 2014 | 5:20 pm


Medium-Sized Heterocycle Synthesis by the Use of Synergistic Effects of Ni-NHC and ?-Coordination in Cycloisomerization

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The Journal of Organic Chemistry
DOI: 10.1021/jo5008477

Posted on 6 May 2014 | 5:28 pm





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