Chemical Communications - Current Research Articles
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Chemical Communications - Editor: Royal Society of Chemistry, RSC
Urgent high quality communications from across the chemical sciences.
Jung Kwon Oh, Qian Zhang, Na Re Ko (Bio)degradation in response to external stimuli (stimuli-responsive degradation, SRD) is a desired property in constructing novel nanostructured materials. For polymer-based multifunctional drug delivery applications, the degradation enables fast and controlled... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32727A, Communication
Carsten Strohmann, Jonathan O. Bauer A straightforward substitution of silicon-bonded methoxy groups by a lithium amide leading to aminomethoxysilanes is presented. DFT calculations allow thermodynamic insight into the unusual equilibrium conditions. The applicability of N,O-functionalised... The content of this RSS Feed (c) The Royal Society of Chemistry
Shunichi Fukuzumi, Kei Ohkubo, Francis DSouza, Jonathan L. Sessler Anion binding has emerged as an attractive strategy to construct supramolecular electron donor-acceptor complexes. In recent years, the level of sophistication in the design of these systems has advanced to... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33027J, Communication
Ming-Hua Xu, Ting-Shun Zhu A pincer-like chiral auxiliary strategy for synthesizing various optically active [small alpha],[small alpha]-disubstituted amino acids in high yields with excellent enantioselectivities is described. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32497K, Communication
Sathiyamoorthy Murugesan, Fan Jiang, Mathieu Achard, Christian Bruneau, Sylvie Derien New highly functionalized piperidine derivatives are obtained from intermolecular selective coupling of allylic alcohols and propargylic amine derivatives via ruthenium catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32760K, Communication
Yasmin Saima, Saikat Khamarui, Krishnanka S. Gayen, Palash Pandit, Dilip K. Maiti Proline catalyzed cascade cyclization of three imines is established to afford a fused-tetrahydroimidazo[1,5-c]imidazol-7-one with excellent regio- and stereoselectivity. Another dehydrogenative cyclization by union of two imines is developed by the Cu(OTf)2-Ag2O combo catalyst to furnish imidazoles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32581K, Communication
Hosahudya N Gopi, Sachitanand M Mali, Sandip V Jadhav A novel, ultrafast, mild and scalable amide bond formation strategy in methanol using simple thioacids and amines is described. The mechanism suggests that coupling reactions are initially mediated by the... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32279J, Communication
Bishnu Prasad Bastakoti, Masamichi Inuoe, Shin-ichi Yusa, Shih-Hsiang Liao, Kevin C.-W. Wu, Kenichi Nakashima, Yusuke Yamauchi Hollow calcium phosphate (CaP) nanospheres with very high biocompatibility are synthesized by using block copolymer micelles as templates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33021K, Communication
Yong Huang, Shulin Zhao, Zhen-Feng Chen, Ming Shi, Hong Liang We have developed an amplified fluorescence polarization aptasensor that relies on aptamer structure-switching-triggered nanoparticles (NPs) enhancement for biomolecules detection. This new type of assay exhibits high detection sensitivity over traditional... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33211F, Communication
Junyuan Duan, Weidong Shi, Leilei Xu, Guangying Mou, Quanliang Xin, Jianguo Guan The hydrolysis of H2TaF7 when it slowly forms via etching Ta powders with HF and H2O2 under hydrothermal conditions produces hierarchical nanostructures of fluorinated and naked Ta2O5 single-crystalline nanorods, which... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32743K, Communication
Yusuke Ide, Masato Torii, Nao Tsunoji, Masahiro Sadakane, Tsuneji Sano Hiroshima University Silicate-1 (HUS-1), which composed of silicate sheets with halved sodalite cage and the interlayer tetramethylammonium (TMA) cation in the cage, was modified with dimethyldichlorosilane to form the organic... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32711B, Communication
Hao Jiang, Lennart Lykke, Steen Uttrup Pedersen, Wen-Jing Xiao, Karl Anker Jorgensen An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insights into the role of superoxide anions in this reaction have also been... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33118G, Communication
Xi-Sen Wang, Matthew Chrzanowski, Chungsik Kim, Wen-Yang Gao, Lukasz Wojtas, Yu-Sheng Chen, Peter Zhang, Shengqian Ma A porous metal-metalloporphyrin framework, MMPF-2, has been constructed from a custom-designed octatopic porphyrin ligand, tetrakis(3,5-dicarboxyphenyl)porphine, that links a distorted cobalt trigonal prism SBU; MMPF-2 possesses permanent microporosity with the highest... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32271D, Communication
Shun-ichi Matsuura In this work, we successfully constructed a glutaminase-mesoporous silica (TMPS10.6) microreactor and demonstrated the successful encapsulation of the enzyme in TMPS10.6 by direct visualization using a confocal laser microscope system.... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32997B, Communication
Tsutomu Katsuki, Chungsik Kim, Tatsuya Uchida Highly enantioselective and good to high-yielding aziridination of conjugated and non-conjugated terminal olefins and cyclic olefins was achieved using a newly designed Ru(CO)(salen) complex as the catalyst in the presence... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32772D, Communication
Taichi Kano, Sunhwa Song, Keiji Maruoka A diastereo- and enantioselective aldol reaction between aldehydes and a synthetically useful ketomalonate 1c as a hydrated form was developed, and either anti- or syn-aldol adducts having a chiral tetrasubstituted... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC31972A, Communication
Junliang Zhang, Deyun Qian An efficient catalytic C-H arylation by means of gold carbenoids insertion for one-step synthesis of 3-acyloxindole derivatives has been developed. The reaction proceeds efficiently with extremely good substrate scope and... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33438K, Communication
Ming-Cheng Kuo, Hsiao-Fan Chen, Jing-Jong Shyue, Dario Bassani, Ken-Tsung Wong A porphyrin derivative possessing orthogonal self-assembly units displays in-situ reversible transformation of aggregate morphology between nano-rods and hollow spheres upon exposure to different solvents. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33076H, Communication
Atul P. Singh, Dhiraj Murale, Kang Mun Lee, Taehong Jun, Hyunjeong Liew, Yoo-Hun Suh, David George Churchill Novel bis-arylsulfide BODIPY systems were prepared and studied for multiple O-atom sensing (at 522 nm); 2- and 3-atom loading was optimal (50-fold, "turn on,"). Neuronal studies showed greater H2O2 sensitivity... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC31864D, Communication
Jinkui Tang A rare [small mu ]4-O centred square Dy4 aggregate displays field enhanced thermally activated mechanism with 3-fold increase in the single-molecule magnetic relaxation barrier upon application of an optimal field. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32387G, Communication
Wei Yao, Hanqing Qian, Jialiang Zhang, Wei Wu, Xiqun Jiang A polymeric multivesicular system was created by hydrating a film. This system underwent multifusion events and eventually evolved into giant multilamellar vesicles with extremely thick wall. The semi-permeable wall and... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32015K, Communication
Benito Alcaide, Pedro Almendros, Jose M. Alonso, Israel Fernandez An efficient palladium-catalyzed chemo-, regio- and stereoselective carbocyclization-cross-coupling sequence of two different [small alpha]-allenols to afford 3-(E-buta-1,3-dienyl) carbazoles is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33157H, Communication
Xihe Bi Catalytic and highly efficient Wolff's cyclocondensation of [small alpha]-diazoketones with aromatic and aliphatic amines has been realized for the first time by utilizing the strategy of intramolecular hydrogen bonding-activating carbonyl group.... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32382F, Communication
Harriet A. Keane, Wilfried Hess, Jonathan W. Burton Cyclisation of a range of alkynyl aminomalonates in the presence of manganese(III) acetate gives rise to exo-alkylidene pyrrolidines and pyrrolidinones in good yields and with useful levels of (Z)-selectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32305B, Communication
Zhijun Tai, Junying Zhang, Ai-Qin Wang, Mingyuan Zheng, Tao Zhang A temperature-controlled phase-transfer catalyst-tungsten acid, which in combination with a robust heterogeneous catalyst Ru/C shows a high activity and exceptional reusability for the one-pot conversion of cellulose to ethylene glycol.... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC31890C, Communication
Dongdong Li, Jianzhao Liu, Ryan T. K. Kwok, Zhiqiang Liang, Ben Zhong Tang, Jihong Yu This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32373G, Communication
Moses Bio, Gregory Nkepang, Youngjae You Aminoacrylate is prepared via an amine-yne reaction and cleaved by singlet oxygen after irradiation with visible light. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32895J, Communication
Michal Malicki, Kathryn E Knowles, Emily Weiss Photoinduced hole transfer (PHT) from PbS quantum dots (QDs) to aminoferrocene (amFc) occurs in < 1 ns when the QDs are coated with an oleate ligand shell, which allows some... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32412A, Communication
Kathrin Zuberbuhler, Giulio Casi, Goncalo J. L. Bernardes, Dario Neri We describe a method that enables specific and efficient conjugation of hydrazide-moieties to an IgG targeting the tumor neovasculature. The resulting chemically defined, homogeneous hydrazone-linked IgG conjugates remain immunoreactive and... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32184J, Communication
Qing Zhang, Ping Deng, lu liu, Shendong Ren, Hongxiang Li N-Acylation has been studied as a method for reducing the LUMO energy levels of benzodipyrrolidone-based polymers. The N-acylated polymers have displayed significantly reduced the LUMO levels (about 0.3 eV) and... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32435K, Communication
Weimin Xuan, Chen Chen, Yanting Cao, Wenhan He, Wei Jiang, Ke-Jian Liu, Wei Wang A new ratiometric and colorimetric fluorescent probe for highly selective, sensitive and facile detection of Hg2+ has been rationally designed. Notably, significant ratiometric fluorescent response and a large emission red... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32406G, Communication
Meng Liu, huimin zhao, Shuo Chen, Hongtao Yu, Xie Quan A synergistic graphene-based catalyst is engineered by in situ growing "naked" Au-nanoparticles (NPs) on hydrothermally-converted graphene (HCG) sheets, which exhibits excellent switchable peroxidase-like activity in response to specific DNA. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33046F, Communication
Akira Onoda, Tomoki Himiyama, Kei Ohkubo, Shunichi Fukuzumi, Takashi Hayashi A myoglobin-cadmium telluride quantum dot conjugate was constructed using an artificial heme modified with a thiol moiety as a linker. Irradiation of the myoglobin-cadmium telluride conjugate generated the photoreduced ferrous... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33104G, Communication
Manfred Bochmann, Dragos A Rosca, Dan A. Smith The monomeric gold(III) hydroxide, k3-(C^N^C)*Au(OH), undergoes C-H and N-H activation reactions to afford, for example, Au(III) perfluoroaryls, pyrazolato, imidazolato, triazolato and alkynyl compounds, while the reactions with aryl boronic acids... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33103A, Communication
Indresh Kumar, Nisar A. Mir, Vivek Gupta, Rajani Kant A new method for asymmetric synthesis of 2,3-substituted pyrrolidine from N-PMP aldimine and succinaldehyde via formal [3+2] cycloaddition is reported. This reaction involves proline catalyzed direct Mannich reaction and acid... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32147E, Communication
Francesco Manoni, Claudio Cornaggia, James Murray, Sean Tallon, Stephen J. Connon An organocatalyst promotes the enantio- and diastereoselective cycloaddition of aryl succinic anhydrides and aldehydes to generate paraconic acid ([gamma]-butyrolactone) derivatives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC31023F, Communication
Andrew Kellett The di-copper(II) cation [Cu2([small mu ]-terephthalate)(1,10-phen)4]2+ is a powerful, non-sequence-specific, minor-groove oxidizer of duplex DNA which, unlike copper(II) bis-1,10-phenanthroline chloride, operates independently of exogenous reagents. The agent displays excellent in vitro cytoxicity... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32429F, Communication
Wei Wang, Xiangpeng Jiang, Kezheng Chen Peroxidase and superoxide dismutase (SOD) are both enzymes that act as natural antioxidant to defend oxidative stress related to reactive oxygen species (ROS). Iron phosphates (FePOs) nanoflowers were fabricated via... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32258G, Communication
Michael E. Muratore, Lei Shi
, Adam W. Pilling, R. Ian Storer, Darren J. Dixon Size exclusion allows the strong Schwesinger base PS-BEMP to co-exist and function in the presence of bulky BINOL phosphoric acids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33189F, Communication
Mshari Alotaibi, Elena Kozhevnikova, Ivan Kozhevnikov Acidic heteropoly salt Cs2.5H0.5PW12O40 doped with Pt nanoparticles is a highly active and selective catalyst for one-step hydrogenation of methyl isobutyl and diisobutyl ketones to the corresponding alkanes in the... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32462H, Communication
Donna A. Kunkel, Scott Simpson, Justin Nitz, Geoffrey A. Rojas, Lucie Routaboul, Pierre Braunstein, Bernard Doudin, Peter A Dowben, Eva Zurek, Axel Enders The permanent intrinsic charge dipole of quinonoid zwitterions of ca. 10 Debye changes significantly when the molecules adsorb on crystalline Ag(111) and Cu(111) surfaces. Scanning tunnelling microscopy reveals that sub-monolayers... The content of this RSS Feed (c) The Royal Society of Chemistry
Shuho Tanimoto, Daisuke Takahashi, Kazunobu Toshima Molecular design, chemical synthesis, and biological evaluation of several designed organic molecules, which target-selectively degrade proteins upon photo-irradiation, are introduced. The designed molecules for protein photo-degradation include 2-phenylquinoline-steroid hormone hybrids... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33100D, Communication
Zhang-Jie Shi, Hu Li, Jia Liu, Ke-Han He, Ke-Qing Zhao, Ping Hu, Bi-Qin Wang Semi-one-pot synthesis of phenanthrenes from styrenes and arenes was developed through cross dehydrogenative coupling. The sequence of Heck-type coupling and photo-cyclization were involved. A variety of functionalities were tolerated. This... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC33155A, Communication
Biao Yu, Fei Yang, Yugen Zhu A dramatic concentration effect on the stereoselectivity of N-glycosylation, which is attributable to a low-concentration-facilitated remote-participation, has been disclosed, leading to convenient synthesis of the 2'-deoxy-beta-ribonucleosides of biological significance. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Accepted Manuscript DOI: 10.1039/C2CC32790B, Communication
Matthias Westerhausen, Carsten Glock, Helmar Gorls Calcium-mediated intermolecular hydroamination of di¬phe-nyl¬butadiyne with N-phenyl and N-isopropyl-substituted ani-lines yields E- and Z-isomers of the corresponding 1-anilino-1,4-diphenylbut-1-ene-3-yne. Heterobimetallic K2Ca(¬NRPh)4 (R = Ph, iPr) effectively catalyzes this hydroami¬nation reaction in... The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32093B, Communication
Chloe Mauroy, Pauline Castagnos, Marie-Claire Blache, Justin Teissie, Isabelle Rico-Lattes, Marie-Pierre Rols, Muriel Blanzat Spontaneous receptor-free membrane fusion with pure lipid systems, used as a cell membrane model, is demonstrated with easy-to-handle lactose-derived catanionic vesicles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32313C, Communication
Sadia Afrin Khan, Rajashekhar Kanchanapally, Zhen Fan, Lule Beqa, Anant Kumar Singh, Dulal Senapati, Paresh Chandra Ray Design of aptamer conjugated gold nanocage decorated SWCNTs for targeted imaging and photothermal destruction of prostate cancer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32871B, Communication
Angel E. Kaifer, Wei Li, Serena Silvi, Vladimir Sindelar Threading and unthreading of cucurbit[7]uril takes place very slowly when the ends of the linear guest are negatively charged. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31398G, Communication
Peiyu Ge, Micheal D. Scanlon, Pekka Peljo, Xiaojun Bian, Heron Vubrel, Arlene O'Neill, Jonathan N. Coleman, Marco Cantoni, Xile Hu, Kyosti Kontturi, BaoHong Liu, Hubert H. Girault The activities of a series of MoS2-based hydrogen evolution catalysts were studied by biphasic reactions monitored by UV/Vis spectroscopy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC30688C, Communication
B. Puertolas, M. Navlani-Garcia, J. M. Lopez, T. Garcia, R. Murillo, A. M. Mastral, M. V. Navarro, D. Lozano-Castello, A. Bueno-Lopez, D. Cazorla-Amoros CuHZSM-5, a multisite solid with specific adsorption points for the different molecules present in the exhaust gases during the cold start. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32399K, Communication
Yan-Chou Lai, Yu-Chen Tsai Charge injection from excited sensitizer into 3C-SiC/TiO2 nanocomposite photoelectrode. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32011H, Communication
Benjamin C. M. Martindale, Richard G. Compton The novel synthesis of formic acid has been achieved in a room temperature ionic liquid via the reaction of electro-activated carbon dioxide and protons on pre-anodised platinum. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC33032F, Communication
Bing Xu, Baibiao Huang, Hefeng Cheng, Zeyan Wang, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai Novel [small alpha]-Fe2O3 hollow polyhedra structures with single crystalline thin shells were synthesized by a one-pot template-free hydrothermal method. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32866F, Communication
Wenwen Tu, Wenjing Wang, Jianping Lei, Shengyuan Deng, Huangxian Ju A universal photoelectrochemical immunosensing platform based on a reduced graphene oxide-CdS nanocomposite was constructed by using chemiluminescence as the exciting light source. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32442C, Communication
Joseph I. Ambrus, Jill I. Halliday, Nicholas Kanizaj, Nathan Absalom, Kasper Harpsoe, Thomas Balle, Mary Chebib, Malcolm D. McLeod The 3-methylmaleimide congeners of the natural product methyllycaconitine (MLA) and an analogue covalently attach to functional cysteine mutants of the [small alpha]7 nicotinic acetylcholine receptor (nAChR). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32586A, Communication
Sachin G. Modha, Dipak D. Vachhani, Jeroen Jacobs, Luc Van Meervelt, Erik V. Van der Eycken A diversity oriented approach for the synthesis of indoloazocines employing an Ugi reaction followed by a gold-catalyzed intramolecular hydroarylation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32961A, Communication
Andreas Glockner, Constantin G. Daniliuc, Matthias Freytag, Peter G. Jones, Matthias Tamm An antifacial [small mu ]-[small eta]7:[small eta]2-coordination mode of the cycloheptatrienyl ligand was observed for the first time in polymeric [([small eta]7-C7H7)Zr{N(SiMe3)2}][infinity]. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32298F, Communication
Arghya Dutta, Malay Pramanik, Astam K. Patra, Mahasweta Nandi, Hiroshi Uyama, Asim Bhaumik A new organic-inorganic hybrid porous tin phosphonate material has been designed, which shows a very high CO2 uptake of 4.8 mmol g-1 at 273 K and 5 bar pressure and catalyzes one-pot oxidation of cyclohexanone to adipic acid in water as solvent in the presence of air. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32783J, Communication
Min-Qiang Jia, Shu-Li You Enantioselective desymmetrization of cyclohexadienones via a D-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction was realized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32969G, Communication
Victor Sebastian, Seung-Kon Lee, Chao Zhou, Martin F. Kraus, James G. Fujimoto, Klavs F. Jensen A one-step process for synthesizing gold nanorods with tunable absorption spectra and biocompatible surface ligands exemplified with use in optical coherence tomography. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32804F, Communication
Joscha Vollmeyer, Stefan-S. Jester, Friederike Eberhagen, Thomas Prangenberg, Werner Mader, Sigurd Hoger Shape-persistent arylene-ethynylene macrocycles in apolar solvents allow a fine tuning of the gelation temperature by variation of the interior filling. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32519E, Communication
Wen-Ching Chen, Yu-Chen Hsu, Wei-Chun Shih, Ching-Yu Lee, Wen-Han Chuang, Yi-Fang Tsai, Peter Ping-Yu Chen, Tiow-Gan Ong An amino-NHC, 1-tBu, can promote carbon-carbon coupling of benzene and pyridine and EPR spectroscopic evidence supported the single electron transfer mechanism. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32065G, Communication
M. Aguilar-Moncayo, T. Takai, K. Higaki, T. Mena-Barragan, Y. Hirano, K. Yura, L. Li, Y. Yu, H. Ninomiya, M. I. Garcia-Moreno, S. Ishii, Y. Sakakibara, K. Ohno, E. Nanba, C. Ortiz Mellet, J. M. Garcia Fernandez, Y. Suzuki Fine-tuning of aglycone interaction with lysosomal enzymes allows the design of selective pharmacological chaperones for Fabry disease or GM1 gangliosidosis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32396F, Communication
Peng-Yang Xin, Hong-Ying Niu, Gui-Rong Qu, Rui-Fang Ding, Hai-Ming Guo A novel protocol for nickel-catalyzed direct sp2 C-H bond alkylation of N-aromatic heterocycles has been developed. This new reaction proceeded efficiently at room temperature using a Grignard reagent as the coupling partner. This approach provides new access to a variety of alkylated N-aromatic heterocycles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32365F, Communication
Congmin Wang, Yan Guo, Xiang Zhu, Guokai Cui, Haoran Li, Sheng Dai A series of novel alkanolamine-based ionic liquids show a highly efficient and excellent reversible capture of CO2 through multidentate cation coordination between alkanolamine and Li+ ion in a quasi-aza-crown ether fashion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32549G, Communication
Hitomi Sawai, Hiroshi Sugimoto, Yoshitsugu Shiro, Haruto Ishikawa, Yasuhisa Mizutani, Shigetoshi Aono Trp283 is responsible for oxygen sensing and signal transduction in a chemotaxis signal transducer protein, Aer2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31204B, Communication
Jiong-Peng Zhao, Qian Yang, Zhong-Yi Liu, Ran Zhao, Bo-Wen Hu, Miao Du, Ze Chang, Xian-He Bu A chain-based substituted cobalt-formate framework has been synthesized under solvothermal conditions, which remarkably displays the coexistence of spin competition, canting, and slow magnetic relaxation and thus, could be considered as a peculiar example of a weak ferromagnetic single-chain-magnet. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC33036A, Communication
Paul D. Newman, Kingsley J. Cavell, Benson M. Kariuki A tridentate diphosphino-NHC ligand coordinates to CuCl to give the chiral-at-copper complex with the SCu stereochemistry. The same reaction with CuI leads to the diastereomer with the RCu configuration as the major species in solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC33047D, Communication
Michael J. Cowley, Kai Abersfelder, Andrew J. P. White, Moumita Majumdar, David Scheschkewitz The first magnesium, copper and zinc disilenides were prepared via transmetallation reactions of a lithium disilenide and structurally characterised. The copper and zinc derivatives show red-shifted UV/vis absorptions due to admixture of metal d-orbitals to the highest occupied molecular orbital. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32806B, Communication
Rachel C. Klet, David G. VanderVelde, Jay A. Labinger, John E. Bercaw Titanium and zirconium complexes containing an anilide(pyridine)phenoxide ligand and activated with methylaluminoxane (MAO) catalyze the formation of nearly regiorandom polypropylene. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32036C, Communication
Zi-Jian Yao, Xian-Kuan Huo, Guo-Xin Jin Three kinds of zwitterionic complexes containing P,P-o-carborane were synthesized and their reactivity was explored preliminarily, H2 activation of zwitterionic half-sandwich complexes has been also studied. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC33031H, Communication
Fangxing Xiao A facile two-step anodization combined layer-by-layer self-assembly approach has been developed for rapid fabrication of hierarchically ordered metal-TiO2 nanoring/nanotube nanostructures, which exhibit versatile photocatalytic and catalytic reduction capabilities. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32624H, Communication
Gang Qian, Jian Ping Gao, Zhi Yuan Wang Near-infrared chemiluminescence tunable from 900 nm to 1700 nm was realized from the reaction of the narrow-bandgap compounds and polymers with oxalyl chloride and hydrogen peroxide. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32843G, Communication
Ana Petronilho, Helge Muller-Bunz, Martin Albrecht Reaction of CsOH with triazolium salts or the corresponding triazolylidene copper(I) complexes affords mesoionic compounds containing an exocyclic oxygen. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32715E, Communication
Kimihiro Komeyama, Takahiro Yamada, Ryoichi Igawa, Ken Takaki Borderline metal catalysts, Bi(OTf)3 and Fe(OTf)3, were proven to work as dual activators for alkynes and N,O-acetals via [sigma],[small pi]-chelation, which achieved a new carboarylation reaction of alkynylarenes with N,O-acetals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32346J, Communication
Hui Xu, Xingtang Rao, Junkuo Gao, Jiancan Yu, Ziqi Wang, Zhongshang Dou, Yuanjing Cui, Yu Yang, Banglin Chen, Guodong Qian A nanoscale MOF material with controllable morphologies is realized for highly sensitive, selective and instant sensing of bacterial endospores. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32611F, Communication
Manjunath Lamani, Ravikumara Siddappa Guralamata, Kandikere Ramaiah Prabhu An efficient aerobic reduction of olefins is revealed using guanidine as an organocatalyst in the presence of a variety of reducible functional groups. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32521G, Communication
Nicholas J. W. Rattray, Waleed A. Zalloum, David Mansell, Joe Latimer, Carl H. Schwalbe, Alexander J. Blake, Elena V. Bichenkova, Sally Freeman A novel dimer based fluorescence probe has been designed to detect azo-reductase expression by C. perfringens bacteria. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31147J, Communication
Takeshi Uchida, Yukari Sekine, Toshitaka Matsui, Masao Ikeda-Saito, Koichiro Ishimori HutZ from Vibrio cholerae was purified and found as heme oxygenase, which degrades heme to release iron essential for bacterial survival. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC30725A, Communication
Sherif A. El-Safty, Mohamed A. Shenashen, Moahmed Ismael, Mohamed Khairy We designed tunable and giant mesocage alumina monoliths for size-selective, effective encapsulation of large and single proteins from mixtures. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31792C, Communication
Yabing He, Zhangjing Zhang, Shengchang Xiang, Frank R. Fronczek, Rajamani Krishna, Banglin Chen A microporous MOF has been realized for highly selective separation of C1, C2 and C3 hydrocarbons at room temperature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32214E, Communication
Xiao-Jing Yang, Song-Song Bao, Tao Zheng, Li-Min Zheng The enantioenriched compound (VO)3(2-cpp)2(H2O)6[middle dot]H2O (2-cpp3- = 2-OOC-C6H4-PO3) (1) experiences a single-crystal-to-single-crystal transformation upon heating forming achiral compound [(VO)3(2-cpp)2(H2O)4] (1a). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32070C, Communication
Jie He, Peng Zhang, Jinlong Gong, Zhihong Nie This communication describes a one-step strategy for the facile synthesis of polymer-Au patchy particles (PPs) and Au nanocups using the interfacial reactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32232C, Communication
Joseph M. Falkowski, Sophie Liu, Cheng Wang, Wenbin Lin We have synthesized a new pair of porous chiral MOFs that were constructed from the same catalytically active bridging ligand but possessed different open channel sizes as a result of the different catenation modes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31777J, Communication
Yuhao Lu, Long Wang, Jinguang Cheng, John B. Goodenough Prussian blue and its analogues consisting of different transition-metal ions (Fe, Mn, Ni, Cu, Co and Zn) have been synthesized at room temperature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32674D, Communication
Xuewan Wang, Xiaochen Dong, Yanqin Wen, Changming Li, Qihua Xiong, Peng Chen A novel needle-electrode based on a graphene-Co3O4 hybrid was developed for non-enzymatic glucose detection in micro-droplets. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31807E, Communication
Kanniyappan Parthasarathy, Han Han, Chandran Prakash, Chien-Hong Cheng A new method for the synthesis of various isochromen-6-ones and phenanthro[1,10-bc]oxepines via a palladium-catalyzed cascade carbocyclization of 2-iodobenzyl-3-phenylpropiolates and 1-iodo-2-(2-(phenylethynyl)benzyloxy)benzenes with arynes is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32533K, Communication
Lingxiang Jiang, Yun Yan, Markus Drechsler, Jianbin Huang We present here a host-guest approach to construct enzyme-triggered assembly systems on the basis of surfactant-cyclodextrin complexes and [small alpha]-amylase. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32823B, Communication
Benjamin Montaignac, Chandrasekaran Praveen, Maxime R. Vitale, Veronique Michelet, Virginie Ratovelomanana-Vidal The enantioselective metallo-organocatalyzed carbocyclizations of formyl-alkynes granted access to enantio-enriched cyclopentanes through the challenging formation of all-carbon quaternary stereocenters. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32643D, Communication
Bernd M. Schmidt, Berit Topolinski, Philipp Roesch, Dieter Lentz N-Substituted imide-fused corannulenes build supramolecular stacks with large [small pi]-[small pi]-overlap and undergo two reversible reduction steps in THF solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31962D, Communication
Yong Yao, Min Xue, Xiaodong Chi, Yingjie Ma, Jiuming He, Zeper Abliz, Feihe Huang A new water-soluble pillar[5]arene containing ten imidazolium groups was prepared. It can be used as a stabilizer to fabricate gold nanoparticles smaller than 6 nm in water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31990J, Communication
Yanxia Li, Mei Hong, Yanqin Lin, Qiu Bin, Zhenyu Lin, Zongwei Cai, Guonan Chen A highly sensitive electrochemical immunoassay method for detection of H1N1 influenza virus with the signal amplification of CuO NPs has been demonstrated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31377D, Communication
Myeong Seon Jeong, Eunha Kim, Hyo Jin Kang, Eun Joung Choi, Alvin R. Cho, Sang J. Chung, Seung Bum Park We developed a Seoul-Fluor-based bioprobe, SfBP, for selective monitoring of vaccinia H1-related (VHR) phosphatase, a dual-specific protein tyrosine phosphatase (DUSP3). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32805D, Communication
Brandon Djukic, Dmitrii F. Perepichka An unexpected but highly selective formation of a vinylene sulfate moiety in the synthesis of [small pi]-extended diethynylanthracenes opens a possibility of asymmetric functionalization of acene materials. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31753B, Communication
Akio Kamimura, Shingo Ishikawa, Fumiaki Noguchi, Takaaki Moriyama, Masahiro So, Toshihiro Murafuji, Hidemitsu Uno Optically active stannolanes and trigonal bipyramidal pentacoordinated tin complexes were readily prepared by radical cyclization of N-propargylated chiral aza-Morita-Baylis-Hillman adducts induced by Bu3SnH. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32129G, Communication
Meili Yin, Zhenhua Li, Zhen Liu, Jinsong Ren, Xinjian Yang, Xiaogang Qu A versatile system has been designed for targeted magnetic resonance/fluorescence multimodal imaging and subsequent photodynamic therapy of cancer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC18127D, Communication
Jingming Zhang, Ankush V. Biradar, Sanhita Pramanik, Thomas J. Emge, Tewodros Asefa, Jing Li A new layered MOF heterogeneous catalyst [Co(Hoba)2[middle dot]2H2O] leads to both high conversion (96%) and high selectivity (96%) for olefin epoxidation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32542J, Communication
Eszter Takacs, Aude Escande, Nicolas Vanthuyne, Christian Roussel, Christophe Lescop, Elisabeth Guinard, Camille Latouche, Abdou Boucekkine, Jeanne Crassous, Regis Reau, Muriel Hissler The synthesis and chiroptical properties of chiral rhenium complexes bearing mono- or di-topic phosphole ligands are described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC32042H, Communication
Srijit Biswas, Joseph S. M. Samec A novel synthetic route to [small alpha]-thiocarbonyl compounds. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Yongseok Jun, Jong Hyeok Park, Man Gu Kang This article summarizes the preparation methods for various TiO2 nanotubes by anodization and their applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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